Abstract: This disclosure relates to a process for producing titanium dioxide, comprising: a) reacting an alloy comprising a metal selected from the group consisting of aluminum, titanium and mixtures thereof, wherein either aluminum or titanium is a major component of the alloy, and an element selected from the group consisting of Li, Be, B, Na, Mg, Al, P, S, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Rb, Sr, Y, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, In, Sn, Sb, Te, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Tl, Pb, and Bi, with chlorine gas to form chlorides of aluminum, titanium or mixtures thereof and chlorides of the element selected from the group consisting of Li, Be, B, Na, Mg, Al, P, S, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Rb, Sr, Y, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, In, Sn, Sb, Te, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Tl, Pb, and Bi, at or above the boiling p

Abstract: Powders such as pigmentary titanium dioxide (TiO2) often demonstrate poor bulk handling properties. It is very cohesive, often dusty, and many grades have loose bulk densities that are lower than desired by customers for their processes. The present invention relates to a process for manufacturing low-dusting, smoothly-discharging, easily dispersible, powders such as pigmentary titanium dioxide that resist compaction, aging, lumping, and/or caking. Particularly, the present invention relates to a process for treating powders such as pigmentary titanium dioxide with ammonia or a similarly basic substance prior to or during agglomeration to produce a powder with improved bulk handling properties. The present invention also relates to powders treated as such, including titanium dioxide.

Abstract: The present invention relates to a process for manufacturing low-dusting, smoothly-discharging, easily dispersible, powders such as pigmentary titanium dioxide that resist compaction, aging, lumping, and/or caking. Particularly, the present invention relates to a process for treating powders such as pigmentary titanium dioxide with ammonia or a similarly basic substance prior to or during agglomeration to produce a powder with improved bulk handling properties.

Abstract: This disclosure relates to a process for producing titanium dioxide, comprising: a) reacting an alloy comprising a metal selected from the group consisting of aluminum, titanium and mixtures thereof, wherein either aluminum or titanium is a major component of the alloy, and an element selected from the group consisting of Li, Be, B, Na, Mg, Al, P, S, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Rb, Sr, Y, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, In, Sn, Sb, Te, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Tl, Pb, and Bi, with chlorine gas to form chlorides of aluminum, titanium or mixtures thereof and chlorides of the element selected from the group consisting of Li, Be, B, Na, Mg, Al, P, S, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Rb, Sr, Y, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, In, Sn, Sb, Te, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, TI, Pb, and Bi, at or above the boiling p

Abstract: A process for producing titanium dioxide, comprising: a) reacting an alloy comprising a metal selected from the group consisting of aluminum, titanium and mixtures thereof, wherein one metal is a major component of the alloy, and an element, with chlorine gas to form chlorides of aluminum, titanium or mixtures thereof and chlorides of the element, at or above the boiling point of the chloride of the major component of the alloy; with the proviso that the element does not comprise Ti when the metal is Ti and does not comprise Al when the metal is Al; (b) adding titanium tetrachloride to the chlorides formed in step (a); (c) oxidizing the chlorides formed in step (a), and titanium tetrachloride of step (b); and (d) forming titanium dioxide.

Abstract: This disclosure relates to inorganic particles, typically inorganic metal oxide or mixed metal oxide particles, and more typically titanium dioxide (TiO2) particles, comprising at least about 0.002% of tungsten, based on the total weight of the inorganic particles, wherein inorganic particles have a photostability ratio (PSR) of at least about 2, as measured by the Ag+ photoreduction rate, and color as depicted by an L* of at least about 97.0, and b* of less than about 4. These titanium dioxide particles comprising tungsten may further comprise alumina.

Abstract: This disclosure relates to a polymer composition comprising an inorganic particle, wherein the inorganic particle comprises at least about 0.002% of tungsten, based on the total weight of the inorganic particle, and has a photostability ratio (PSR) of at least about 2, as measured by the Ag+ photoreduction rate, and color as depicted by an L* of at least about 97.0, and b* of less than about 4. The disclosure also relates to plastic parts prepared from these compositions.

Abstract: This disclosure relates to a resin-impregnated, opaque, cellulose pulp-based sheet comprising an inorganic particle, wherein the inorganic particle comprises at least about 0.002% of tungsten, based on the total weight of the inorganic particle, and has a photostability ratio (PSR) of at least about 2, as measured by the Ag+ photoreduction rate, and color as depicted by an L* of at least about 97.0, and b* of less than about 4. The disclosure also relates to paper laminates prepared from these resin-impregnated, opaque, cellulose pulp-based sheets.

Abstract: This disclosure relates to a process for producing titanium dioxide, comprising: a) reacting an alloy comprising a metal selected from the group consisting of aluminum, titanium and mixtures thereof, wherein one metal is a major component of the alloy, and an element selected from the group consisting of Li, Be, B, Na, Mg, Al, P, S, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Rb, Sr, Y, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, In, Sn, Sb, Te, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Tl, Pb, and Bi, with chlorine gas to form chlorides of aluminum, titanium or mixtures thereof and chlorides of the element selected from the group consisting of Li, Be, B, Na, Mg, Al, P, S, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Rb, Sr, Y, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, In, Sn, Sb, Te, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Tl, Pb, and Bi, at or above the boiling point of the chlori

Abstract: This disclosure relates to a coating composition comprising an inorganic particle, wherein the inorganic particle comprises at least about 0.002% of tungsten, based on the total weight of the inorganic particle, and has a photostability ratio (PSR) of at least about 2, as measured by the Ag+ photoreduction rate, and color as depicted by an L* of at least about 97.0, and b* of less than about 4. The disclosure also relates to dried films prepared from these coating compositions.

Abstract: The present invention relates to processes for making anodes suitable for use in the production of titanium metals. The processes use a kneaded mixture of TiO2 particles, carbon particles, a binder, and a solvent. The mixture is extruded and the solvent is allowed to evaporate to form a green body which is subsequently fired. During firing of the green body, the carbon particles aid in reducing the titanium dioxide to a lower oxide or oxycarbide which can be electrochemically processed into titanium metal.

Abstract: The present invention relates to processes for making anodes suitable for use in the production of titanium metals. The processes use a kneaded mixture of TiO2 particles, carbon particles, a binder, and a solvent. The mixture is extruded and the solvent is allowed to evaporate to form a green body which is subsequently fired. During firing of the green body, the carbon particles aid in reducing the titanium dioxide to a lower oxide or oxycarbide which can be electrochemically processed into titanium metal.

Abstract: The present invention provides hydrothermal processes for the production of titanium dioxide from titanyl hydroxide. The use of specific crystallization directors, or additives, can promote the formation of rutile, anatase, or brookite. Variation of process operating parameters can lead to either pigmentary-sized or nano-sized rutile.

Abstract: Disclosed herein is a method of improving a chemo/electro-active material by increasing the sensitivity of the material; increasing the stability of an electrical response characteristic of the chemo/electro-active material; or increasing the speed with which a change in an electrical response characteristic of the chemo/electro-active material is detected.

Abstract: An infrared thermographic technique for rapid parallel screening of compositional arrays of potential chemical sensor materials has been developed. The technique involves applying a voltage bias and the associated current to the sample array during screening. The thermographic response is amplified by the resistance change that occurs with gas adsorption, and is directly monitored as the temperature change associated with I2R heating. This technique can also be used to determine n- or p-type character for the semiconductor in question.

Abstract: An infrared thermographic technique for rapid parallel screening of compositional arrays of potential chemical sensor materials has been developed. The technique involves applying a voltage bias and the associated current to the sample array during screening. The thermographic response is amplified by the resistance change that occurs with gas adsorption, and is directly monitored as the temperature change associated with I2R heating. This technique can also be used to determine n- or p-type character for the semiconductor in question.

Abstract: A ceramic matrix composite article comprised of inorganic fibers having a mullite-containing coating disposed within a matrix phase. The invention also provides a method for mating such an article, as well as for preparing a fiber having a mullite-containing coating. The mullite-containing coating on inorganic fibers within a matrix acts as a debonding coating, and the ceramic matrix composite article exhibits high strength and fracture toughness, even at elevated temperatures.

Abstract: Vanadyl pyrophosphate oxidation catalyst precursors comprise vanadium phosphate esters of the formula(VO)(((R.sub.1-x /H.sub.x)OPO.sub.3).multidot.((ROH).sub.y /(H.sub.2 O).sub.z)wherein, R is an alkyl group capable of bonding, through oxygen, to phosphorus to form a phosphate ester; x is 0 to about 0.5; y is 0-1.0; z is 0-1.25; and y+z is 0-1.25 are particularly useful for the selective oxidation of butane to maleic anhydride and readily thermally decompose to form the vanadyl pyrophosphate oxidation catalysts.