Patents by Inventor Eugene P. Gosselink

Eugene P. Gosselink has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6703523
    Abstract: A zwitterionic polyetherpolyamine comprising a linear or branched polyetherpolyamine backbone having 2 to 10 tertiary amino nitrogen atoms and a molecular weight of from 100 to 800, at least one tertiary amine end group of the polyetherpolyamine backbone contains two groups having the formula wherein A means an ethylene oxide unit, a propylene oxide unit, a unit of butylene oxides and a tetrahydrofuran unit, n is a number of from 1 to 50, X is an anionic group, with the proviso that in formula II one X may also be hydrogen and M is hydrogen, alkali metal or ammonium, or contains one group of formula I or II and one group selected from radicals consisting of C1- to C22-alkyl and C7- to c22-aralkyl, the meaning of A and n is the same as in formula I or II, said zwitterionic polyetherpolyamine having a molecular weight up to 9,000 and optionally containing up to 100% of the nitrogen atoms quaternized, and a process for the production of zwitterionic polyetherpolyamines by
    Type: Grant
    Filed: January 11, 2002
    Date of Patent: March 9, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Dieter Boeckh, Oliver Borzyk, Michael Ehle, Ralf Nörenberg, Eugene P. Gosselink, Jeffrey S. DuPont, Robert H. Rohrbaugh, Kenneth N. Price, Randall S. Deinhammer
  • Patent number: 6673890
    Abstract: A zwitterionic polyamine comprising a linear or branched hydrophobic polyamine backbone having 2 to 10 tertiary amino nitrogen atoms and a spacer between two tertiary nitrogen atoms wherein the spacer is, for example selected from C8-C16-alkylene, C5-C15-cyloalkylene, wherein in formula (IV) R═C1- to C22-alkyl or C7-C22-aralkyl and n=3 to 6, at least one tertiary amine end group of the polyamine backbone contains two groups having formula (V) or (VI), wherein A means an ethylene oxide unit, a propylene oxide unit, a unit of butylene oxides and a tetrahydrofuran unit, n is a number of from 1 to 50, X is an anionic group such as —SO3M, with the proviso that in formula (VI) one X may also be hydrogen and M is hydrogen, alkai metal or ammonium, or contains one group of formula (V) or (VI) and one group selected from radicals consisting of formula (VII), C1- to C22-alkyl and C7-C22-aralkyl the meaning of A and n is the same as in formula (V) or (VI), said zwitterionic polyetherpolyamine having a
    Type: Grant
    Filed: January 16, 2002
    Date of Patent: January 6, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Dieter Boeckh, Oliver Borzyk, Michael Ehle, Ralf Nöerenberg, Eugene P. Gosselink, Jeffrey S. DuPont, Robert H. Rohrbaugh, Kenneth N. Price, Randall S. Deinhammer
  • Publication number: 20030228998
    Abstract: The present invention relates to hydrophobically modified polyamines and laundry detergent compositions which comprise said polyamines, said compositions comprising:
    Type: Application
    Filed: August 30, 2002
    Publication date: December 11, 2003
    Applicant: The Procter & Gamble Company
    Inventors: Jeffrey S. Dupont, Eugene P. Gosselink, Kenneth N. Price, Robert H. Rohrbaugh
  • Patent number: 5635103
    Abstract: Improved cleaning and/or bleaching compositions including fabric laundry and bleaching compositions, automatic dishwashing compositions, hard surface cleaners, bleach additives and the like, suitable for domestic use, comprising improved bleach activators having particular alpha-modified lactam leaving groups leading to improved in-use performance of bleaching agents such as perborate even under wash conditions less alkaline than those typically encountered or when hydrogen peroxide source is at low levels in a cleaning operation. A preferred class of activators are N-acyl-3-morpholinone compounds with benzoyl being a preferred acyl group and N-Benzoyl-3-oxomorpholine being a highly preferred activator.
    Type: Grant
    Filed: January 20, 1995
    Date of Patent: June 3, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Alan D. Willey, Kevin L. Kott, Gregory S. Miracle, Eugene P. Gosselink, James C. T. R. B. St. Laurent
  • Patent number: 5599782
    Abstract: Improved soil release agents for granular laundry detergents, typically used at levels as low as about 1% of a fully-formulated anionic surfactant-containing granular detergent, are reaction products of transesterifying and oligomerizing mixtures of monomers having the functions MO.sub.3 SC.sub.6 H.sub.4 C(O)--, M'O.sub.3 SC.sub.6 H.sub.3 {C(O)O--}.sub.2, --(O)CC.sub.6 H.sub.4 C(O)-- and --OCH.sub.2 CH.sub.2 O-- wherein M and M' are independently selected from lithium, potassium and sodium, more preferably sodium; said mixtures having mole ratio of MO.sub.3 SC.sub.6 H.sub.4 C(O)-- to --(O)CC.sub.6 H.sub.4 C(O)-- of from about 0.2:1 to about 1.4:1, mole ratio of MO.sub.3 SC.sub.6 H.sub.4 C(O)-- to M'O.sub.3 SC.sub.6 H.sub.3 {C(O)O--}.sub.2 of from about 0.67:1 to about 20:1 and mole ratio of MO.sub.3 SC.sub.6 H.sub.4 C(O)-- to --OCH.sub.2 CH.sub.2 O-- of from about 0.007:1 to about 0.51:1 and being substantially free from monomers of formula HOROH wherein R is propylene or higher alkyl.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: February 4, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Robert Y. L. Pan, Eugene P. Gosselink, Eugene J. Pancheri, Stephen W. Morrall
  • Patent number: 5565145
    Abstract: Cleaning and soil dispersing compositions comprising ethoxylated/propoxylated polyalkyleneamine polymers are provided. Thus, detergent compositions which comprise ethoxylated/propoxylated polyalkyleneamine polymers, such as poly(ethyleneimine) with a degree of ethoxylation of 1.0, provide soil dispersing performance in the wash liquor and whitening and/or cleaning benefits to fabrics, hard-surfaces, or dishware.
    Type: Grant
    Filed: January 16, 1996
    Date of Patent: October 15, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Randall A. Watson, Eugene P. Gosselink, Shulin Zhang
  • Patent number: 5561235
    Abstract: Bleaching compositions, laundry and automatic dishwashing detergent compositions comprising multiple-substituted bleach activators which have at least one quaternary nitrogen atom,, are provided. More specifically, the invention relates to compositions which provide enhanced cleaning/bleaching benefits though the selection of multiple-substituted quaternary bleach activators having specific leaving groups with a conjugate acid aqueous pK.sub.a above 13 and with advantageous ratios of rate of perhydrolysis to rate of hydrolysis and of rate of perhydrolysis to rate of diacylperoxide production. Included are preferred activator compounds and methods for washing fabrics, hard surfaces, and tableware using the activators.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: October 1, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Eugene P. Gosselink, Gregory S. Miracle, Alan D. Willey, Michael E. Burns, Kevin L. Kott, Mark R. Sivik, Lucille F. Taylor
  • Patent number: 5560862
    Abstract: Bleaching compositions, laundry and automatic dishwashing detergent compositions comprising multiple-substituted bleach activators which have at least one quaternary nitrogen atom, are provided. More specifically, the invention relates to compositions which provide enhanced cleaning/bleaching benefits though the selection of multiple-substituted quaternary bleach activators having specific leaving groups with a conjugate acid aqueous pK.sub.a above 13 and with advantageous ratios of rate of perhydrolysis to rate of hydrolysis and of rate of perhydrolysis to rate of diacylperoxide production. Included are preferred activator compounds and methods for washing fabrics, hard surfaces, and tableware using the activators.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: October 1, 1996
    Assignee: The Procter & Gamble Company
    Inventors: Eugene P. Gosselink, Gregory S. Miracle, Alan D. Willey, Michael E. Burns, Kevin L. Kott, Mark R. Sivik, Lucille F. Taylor
  • Patent number: 5460747
    Abstract: Bleaching compositions, laundry and automatic dishwashing detergent compositions comprising multiple-substituted bleach activators which have at least one quaternary nitrogen atom, are provided. More specifically, the invention relates to compositions which provide enhanced cleaning/bleaching benefits though the selection of multiple-substituted quaternary bleach activators having specific leaving groups with a conjugate acid aqueous pK.sub.a above 13 and with advantageous ratios of rate of perhydrolysis to rate of hydrolysis and of rate of perhydrolysis to rate of diacylperoxide production. Included are preferred activator compounds and methods for washing fabrics, hard surfaces, and tableware using the activators.
    Type: Grant
    Filed: August 31, 1994
    Date of Patent: October 24, 1995
    Assignee: The Procter & Gamble Co.
    Inventors: Eugene P. Gosselink, Gregory S. Miracle, Alan D. Willey, Michael E. Burns, Kevin L. Kott, Mark R. Sivik, Lucille F. Taylor
  • Patent number: 5415807
    Abstract: Anionic sulfonated poly-ethoxy/propoxy, especially modified isethionate, end-capped esters useful as soil release agents in detergent compositions are presented. The terephthalate esters are homogeneously integrated with one or more crystallization-reducing stabilizers.
    Type: Grant
    Filed: September 17, 1993
    Date of Patent: May 16, 1995
    Assignee: The Procter & Gamble Company
    Inventors: Eugene P. Gosselink, Robert Y. Pan, Patti J. Kellett, Robin G. Hall
  • Patent number: 5405542
    Abstract: Rinse-added fabric conditioning compositions containing cationic soil release polymers are much more effective than similar compositions containing nonionic soil release polymers for soil release. Most of the cationic soil release polymers are new compounds comprising a hydrophobic alkylene oxide/terephthalate portion which has a low molecular weight and at least a single cationic charge under use conditions.
    Type: Grant
    Filed: December 27, 1990
    Date of Patent: April 11, 1995
    Assignee: The Procter & Gamble Company
    Inventors: Toan Trinh, Eugene P. Gosselink, Frederick E. Hardy
  • Patent number: 5332528
    Abstract: Disclosed is a detergent composition containing one or more anionic surfactants and one or more soil release agents characterized by the presence of an anionic surfactant-interactive nonionic hydrophile and/or an anionic surfactant-interactive hydrophobic moiety, or both, and a soil release agent-enhancing amount of a polyhydroxy fatty acid amide surfactant of the formula: ##STR1## wherein R.sup.1 is H, C.sub.1 -C.sub.4 hydrocarbyl, 2-hydroxy ethyl, 2-hydroxy propyl, or a mixture thereof, R.sub.2 is C.sub.5 -C.sub.31 hydrocarbyl, and Z is a polyhydroxylhydrocarbyl having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain, or an alkoxylated derivative thereof.
    Type: Grant
    Filed: June 17, 1993
    Date of Patent: July 26, 1994
    Assignee: The Procter & Gamble Company
    Inventors: Robert Y. Pan, Eugene P. Gosselink
  • Patent number: 5256168
    Abstract: Anionic, sulfobenzoyl end-capped esters useful as soil release agents in granular detergent compositions. The terephthalate esters contain oxyethyleneoxy and oxy-1,2-propyleneoxy units, and are substantially amorphous in form.
    Type: Grant
    Filed: September 22, 1992
    Date of Patent: October 26, 1993
    Assignee: The Procter & Gamble Company
    Inventors: Stephen W. Morrall, Eugene P. Gosselink, Robert Y. Pan, Bala C. Nayar
  • Patent number: 5188769
    Abstract: The synthesis of polyhydroxy fatty acid amide surfactants exemplified by the compound C.sub.11 H.sub.23 C(O)N(CH.sub.3)CH.sub.2 [CHOH].sub.4 CH.sub.2 OH by reacting a fatty acid ester with an N-alkyl sugar amine can result in contamination of the product surfactant by residual sources of fatty acids. These residual fatty acids may be unacceptable in high sudsing detergent compositions, such as dishwashing liquids, especially with Ca or Mg cations. The process of this invention reacts such contaminants with alkyl amines or, especially, ethanolamine, to convert them into fatty alkyl- or alkanolamides, which are quite acceptable in fully-formulated detergent compositions for home or industrial use.
    Type: Grant
    Filed: March 26, 1992
    Date of Patent: February 23, 1993
    Assignee: The Procter & Gamble Company
    Inventors: Daniel S. Connor, Jeffrey J. Scheibel, Bruce P. Murch, Mark H. Mao, Eugene P. Gosselink, Roland G. Severson, Jr.
  • Patent number: 5182043
    Abstract: Anionic, sulfobenzoyl end-capped esters useful as soil release agents in granular detergent compositions. The terephthalate esters contain oxyethyleneoxy and oxy-1,2-propyleneoxy units, and are substantially amorphous in form.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: January 26, 1993
    Assignee: The Procter & Gamble Company
    Inventors: Stephen W. Morrall, Eugene P. Gosselink, Robert Y. Pan, Bala C. Nayar
  • Patent number: 4976879
    Abstract: Anionic, especially sulfoaroyl, NaO.sub.3 S(C.sub.6 H.sub.4) C(O)--preferred, end-capped esters useful as soil release agents in detergent compositions and fabric-conditioner articles. The terephthalate esters contain unsymmetrically substituted oxy-1,2-alkyleneoxy units (oxy-1,2-propyleneoxy units preferred).
    Type: Grant
    Filed: August 28, 1989
    Date of Patent: December 11, 1990
    Assignee: The Procter & Gamble Company
    Inventors: Rene Maldonado, Toan Trinh, Eugene P. Gosselink
  • Patent number: 4968451
    Abstract: The present invention relates to novel soil release agents, which are particular sulfonated linear terephthalate ester oligomers (S.T.E. oligomers). The S.T.E. oligomers are especially suitable for formulation into laundry products such as laundry detergents or fabric conditioners. Thus formulated, they provide effective soil release treatments for fabrics laundered in the home. The S.T.E. oligomers can be made by radical-initiated sulfonation of an allyl end-capped oligomeric ester precursor, and in the preferred embodiments, comprise a high proportion of disulfonate or sulfinate-sulfonate end-capping groups.
    Type: Grant
    Filed: January 29, 1990
    Date of Patent: November 6, 1990
    Assignee: The Procter & Gamble Company
    Inventors: Jeffrey J. Scheibel, Eugene P. Gosselink
  • Patent number: 4956447
    Abstract: Rinse-added fabric conditioning compositions containing cationic soil release polymers are much more effective than similar compositions containing nonionic soil release polymers for soil release. Most of the cationic soil release polymers are new compounds comprising a hydrophobic alkylene oxide/terephthalate portion which has a low molecular weight and at least a single cationic charge under use conditions.
    Type: Grant
    Filed: May 19, 1989
    Date of Patent: September 11, 1990
    Assignee: The Procter & Gamble Company
    Inventors: Eugene P. Gosselink, Frederick E. Hardy, Toan Trinh
  • Patent number: 4877896
    Abstract: Anionic, especially sulfoaroyl, NaO.sub.3 S(C.sub.6 H.sub.4)C(O)- preferred, end-capped esters useful as soil release agents in detergent compositions and fabric-conditioner articles. The terephthalate esters contain unsymmetrically substituted oxy-1,2-alkyleneoxy units (oxy-1,2-propyleneoxy units preferred).
    Type: Grant
    Filed: October 5, 1987
    Date of Patent: October 31, 1989
    Assignee: The Procter & Gamble Company
    Inventors: Rene Maldonado, Toan Trinh, Eugene P. Gosselink
  • Patent number: 4876046
    Abstract: Novel peroxyacids of the formula: ##STR1## wherein X is an alkylene group selected from propylene and butylene, R is alkyl containing from 4 to 12 carbon atoms, benzyl or phenyl and m is 1 or 2. The compounds are useful as disinfectants and fabric bleaches.
    Type: Grant
    Filed: May 11, 1989
    Date of Patent: October 24, 1989
    Assignee: The Procter & Gamble Company
    Inventors: Allen D. Clauss, Eugene P. Gosselink