Abstract: Disclosed herein is a membrane-electrode assembly containing: a gastight, selectively proton-conducting membrane which has a retentate side having an anode and a permeate side having a cathode; a voltage source for generating a potential difference between the anode and the cathode; an anode catalyst having a catalytically active material on the retentate side; and a cathode catalyst having a catalytically active material on the permeate side, in which the cathode catalyst has a smaller amount of catalytically active material than the anode catalyst. The present disclosure also includes a reactor containing the membrane-electrode assembly, and a process for separating off hydrogen using the membrane-electrode assembly.

Abstract: Disclosed herein is a membrane-electrode assembly containing: a gastight, selectively proton-conducting membrane which has a retentate side having an anode and a permeate side having a cathode; a voltage source for generating a potential difference between the anode and the cathode; an anode catalyst having a catalytically active material on the retentate side; and a cathode catalyst having a catalytically active material on the permeate side, in which the cathode catalyst has a smaller amount of catalytically active material than the anode catalyst. The present disclosure also includes a reactor containing the membrane-electrode assembly, and a process for separating off hydrogen using the membrane-electrode assembly.

Abstract: The present invention relates to rechargeable electrochemical zinc-oxygen cells comprising A) at least one anode comprising metallic zinc, B) at least one gas diffusion electrode comprising (B1) at least one cathode active material, and (B2) optionally at least one solid medium through which gas can diffuse, and C) an aqueous electrolyte comprising boric acid. The present invention further relates to uses of the inventive rechargeable electrochemical zinc-oxygen cells, to zinc-air batteries comprising the inventive rechargeable electrochemical zinc-oxygen cells, and to the use of an aqueous electrolyte comprising boric acid for production or for operation of rechargeable electrochemical zinc-oxygen cells.