Abstract: A liquid-loop compound recuperator is disclosed for high-? heat exchange between a first shell-side fluid stream and a second shell-side fluid stream of similar thermal capacity rates (W/K). The compound recuperator is comprised of at least two fluid-to-liquid (FL) recuperator modules for transfer of heat from a shell-side fluid, usually a gas, to an intermediary tube-side heat transfer liquid (HTL). Each FL module includes a plurality of thermally isolated, serially connected, adjacent exchanger cores inside a pressure vessel. The cores are rows of finned tubes for cross-flow transfer of heat, and they are arranged in series to effectively achieve counterflow exchange between the HTL and the shell-side stream. The HTL may be water, an organic liquid, a molten alloy, or a molten salt. Alumina-dispersion-strengthened-metal fins, superalloy tubes, and a lead-bismuth-tin alloy HTL may be used for high temperatures. Cumene may be used as the HTL in cryogenic applications.

Abstract: A Renewable Fischer Tropsch Synthesis (RFTS) process is disclosed for producing hydrocarbons and alcohol fuels from wind energy, waste CO2 and water. The process includes (A) electrolyzing water to generate hydrogen and oxygen, (B) generating syngas in a reverse water gas shift (RWGS) reactor, (C) driving the RWGS reaction to the right by condensing water from the RWGS products and separating CO using a CuAlCl4-aromatic complexing method, (D) using a compressor with variable stator nozzles, (E) carrying out the FTS reactions in a high-temperature multi-tubular reactor, (F) separating the FTS products using high-pressure fractional condensation, (G) separating CO2 from product streams for recycling through the RWGS reactor, and (H) using control methods to maintain the temperatures of the reactors, electrolyzer, and condensers at optima that are functions of the flow rate. The RFTS process may also include heat engines, a refrigeration cycle utilizing compressed oxygen, and a dual-source organic Rankine cycle.

Abstract: In a dual-source organic Rankine cycle (DORC), the condensed and slightly sub-cooled working fluid at near ambient temperature (˜300 K) and at low-side pressure (0.1 to 0.7 MPa) is (1) pumped to high-side pressure (0.5-5 MPa), (2) pre-heated in a low-temperature (LT) recuperator, (3) boiled using a low-grade heat source, (4) super-heated in a high-temperature (HT) recuperator to a temperature close to the expander turbine exhaust temperature using this exhaust vapor enthalpy, (5) further super-heated to the turbine inlet temperature (TIT) using a mid-grade heat source, (6) expanded through a turbine expander to the low-side pressure, (7) cooled through the HT recuperator, (8) cooled through the LT recuperator, (9) mostly liquefied and slightly subcooled in a condenser, and (10) the condensed portion is returned to the pump to repeat this cycle.

Abstract: A liquid-loop compound recuperator is disclosed for high-? heat exchange between a first shell-side fluid stream and a second shell-side fluid stream of similar thermal capacity rates (W/K). The compound recuperator is comprised of at least two fluid-to-liquid (FL) recuperator modules for transfer of heat from a shell-side fluid, usually a gas, to an intermediary tube-side heat transfer liquid (HTL). Each FL module includes a plurality of thermally isolated, serially connected, adjacent exchanger cores inside a pressure vessel. The cores are rows of finned tubes for cross-flow transfer of heat, and they are arranged in series to effectively achieve counterflow exchange between the HTL and the shell-side stream. The HTL may be water, an organic liquid, a molten alloy, or a molten salt.

Abstract: A Renewable Fischer Tropsch Synthesis (RFTS) process produces hydrocarbons and alcohol fuels from wind energy, waste CO2 and water. The process includes (A) electrolyzing water to generate hydrogen and oxygen, (B) generating syngas in a reverse water gas shift (RWGS) reactor, (C) driving the RWGS reaction to the right by condensing water from the RWGS products and separating CO using a CuAlCl4-aromatic complexing method, (D) using a compressor with variable stator nozzles, (E) carrying out the FTS reactions in a high-temperature multi-tubular reactor, (F) separating the FTS products using high-pressure fractional condensation, (G) separating CO2 from product streams for recycling through the RWGS reactor, and (H) using control methods to maintain temperatures of the reactors, electrolyzer, and condensers at optima that are functions of the flow rate. The RFTS process may also include heat engines, a refrigeration cycle utilizing compressed oxygen, and a dual-source organic Rankine cycle.

Abstract: All critical circuit components, including the sample coils, are located along with the spinner assembly in a region that may be evacuated to high vacuum for thermal insulation and high-voltage operation. A hermetically sealed spinner assembly simultaneously satisfies the requirements of hermeticity, low total emissivity, rf compatibility, spinning performance, magnetic compatibility, and high filling factor by utilizing metal construction except for the central region near the rf sample coils. Hence, it is possible to maintain high vacuum in the region external to the MAS spinner assembly even over a broad range of bearing and drive gas temperatures. A bundle of optical fibers is provided for tachometry for spin rates up to 60 kHz. The use of alumina disc capacitors allows the noise contributions from the most critical capacitors to be reduced to a minor fraction of the total and simplifies high voltage operation.

Abstract: An NMR probe contains a metallic dewar for use in a high field magnet, the dewar characterized as having a major fraction of its inner wall made from an alloy whose weight composition includes at least 70% copper, less than 20% zinc, less than 10% nickel, less than 8% Cr, less than 4% Pb, less than 0.15% iron, less than 0.15% cobalt, and at least 3% from the set comprised of tin, silicon, aluminum, and chromium, and said inner wall further characterized as being plated with a pure metal on at least one surface.

Abstract: An NMR probe contains a metallic dewar for use in a high field magnet, the dewar characterized as having a major fraction of its inner wall made from an alloy whose weight composition includes at least 70% copper, less than 20% zinc, less than 10% nickel, less than 8% Cr, less than 4% Pb, less than 0.15% iron, less than 0.15% cobalt, and at least 3% from the set comprised of tin, silicon, aluminum, and chromium, and said inner wall further characterized as being plated with a pure metal on at least one surface.

Abstract: An improved axial gas bearing for a gas-driven NMR MAS sample rotor is disclosed that utilizes inward flow with a low rotational component over a rotor conical end. A conical flow region is formed between the rotor conical end and a conical stator bearing surface such that the included angle defining the stator surface is not less than the included angle defining the rotor conical end. Gas is injected radially inward with a significant axial rearward component from a number of small holes at high velocity from the periphery into the conical flow region. Compared to the radial velocity components, the tangential flow components of the injected gas are small and preferably opposed to the direction of the rotor rotation.

Abstract: A MAS probe offers a substantial improvement in signal to noise (S/N) in triple-resonance high-resolution (HR) magic-angle-spinning (MAS) NMR of samples near room temperature (RT) in high field magnets, especially where the RT shim bore is less than 55 mm. Critical circuit components other than the sample coils, including both high-power capacitors and inductors for one or more channels are located in a small, thermally insulated, cold zone immediately below the sample spinner assembly. Cooling these components to 100 K allows their thermal noise power to be conveniently reduced by a factor of three or more. Variable capacitors for fine tuning are located in an RT tuning zone below the cold zone. The circuit is designed such that the currents, voltages, and standing wave ratio (SWR) in circuit tuning elements in the RT tuning zone are relatively low, so rf losses and noise contributions below the cold zone may be only a few percent.

Abstract: A flexible, low-loss, low-capacitance, high-voltage, high-current, moderate-impedance, unshielded, balanced, rf-pulse transmission twinline is produced by etching parallel copper traces on opposite sides of a flexible substrate, spaced apart such that the distance between the conductors is greater than four times the substrate thickness and at least one of the conductors has a width greater than half of the separation between the conductors. A second, similar twinline may be etched on the same substrate beside the first twinline and paralleled at both ends with the first twinline to form a lower-impedance quadline such that alternate conductors in the quadline are on alternate sides of the substrate and have opposite current phases. Both surfaces may be coated with a thin, flexible dielectric to increase the voltage rating for a given conductor separation with minimal affect on propagation factor, attenuation constant, or flexibility.

Abstract: The two halves of a conventional RF saddle coil, such as spirals or other related structures for use in high resolution NMR or MRI, are disposed on opposite sides of a cylindrical coilform, and rotated from the conventional orientation 90 degrees about the B1 axis, so that the leads are paralleled near the axial center of the RF coil.

Abstract: An edge-wound NMR solenoidal sample coil is made by winding at least two turns of flattened wire around a cylindrical coilform such that the major cross-sectional axis of the flat wire is perpendicular to the axis of the solenoid. The space between turns near the center is greater than the space between turns at the ends but less than the major cross-sectional dimension of the flat wire. The flattened wire is magnetically compensated by forming copper tubing around paramagnetic wires. The resulting solenoid has considerably higher .eta..sub.F Q and B.sub.1 homogeneity than prior-art solenoids of comparable size and transverse transparency. Similar principles may be used to improve the segmented, transparent, loop-gap resonator for breast and other imaging applications by using segmented planar ring resonators, tightly coupled by means of balanced transmission lines at the magic angle, with outermost conductive surfaces oriented more in the radial than axial direction.

Abstract: A family of NMR coils based on Litz foil conductor groups is disclosed. The simplest embodiment is a two-element Litz foil coil. The foils are joined at node (1) and node (2) and are electrically insulated at crossover (3). When the coil is positioned in a plane perpendicular to a uniform magnetic field, the areas (A) defining two flux sub-windows must be equal.

Abstract: A cylindrical NMR sample cell is made from a first plastic material having Young's modulus Y.sub.1, tensile strength S.sub.1, and density p.sub.1 with precision outside diameter (OD) d.sub.4, wherein the outside diameter fits inside a ceramic NMR MAS rotor having modulus Y.sub.3 and density p.sub.3. The sample cell comprising a sample chamber with a concentric cylindrical opening at one end having inside diameter d.sub.2. A cylindrical plug is made from a second plastic material having modulus Y.sub.2, strength S.sub.2, and density p.sub.2 with plug outside diameter d.sub.1 to fit firmly inside the mouth of the cell, so as to seal the sample of density p.sub.4 inside the cell with inside cell diameter d.sub.3 when stationary and to seal when spinning at a high rate of speed inside the ceramic rotor. More-over, the following materials properties and relationships are satisfied: Y.sub.1> 0.8 GPa, Y.sub.1 <4 GPa, Y.sub.2 <3.4 GPa, S.sub.1 >8 MPa, S.sub.2 >3 MPa, p.sub.2 >880 kg/m.sup.3, p.sub.

Abstract: A single-tuned rf-gradient saddle coil is used for an internal NMR lock in a high-field NMR probe. The non-dipolar lock coil geometry is chosen such that its filling factor and Q are maximized subject to the constraint that its coupling coefficient to two orthogonal saddle coils is zero. Various quadrupolar and octopolar rf coils are disclosed for use in NMR probes having three or four sample coils for multi-nuclear triple resonance or homonuclear decoupling.

Abstract: A high-conductivity ceramic coil form with an internal water jacket is used to simplify water cooling for 3-axis MRI gradient coil configurations on a single cylindrical coilform. Crescent-shaped, axially aligned coils are symmetrically employed on either side of the axial symmetry plane to increase transversely the region of field linearity. These crescent coils may be used in conjunction with Golay-type coils for improved switching efficiency. Lead-filled copper tubing may be used to reduce acoustic noise from pulsed coils in high external magnetic fields.

Abstract: A high-conductivity ceramic coil form with an internal water jacket is used to simplify water cooling for 3-axis MRI gradient coil configurations on a single cylindrical coilform. Crescent-shaped, axially aligned coils are symmetrically employed on either side of the axial symmetry plane to increase transversely the region of field linearity. These crescent coils may be used in conjunction with Golay-type coils for improved switching efficiency. Lead-filled copper tubing may be used to reduce acoustic noise from pulsed coils in high external magnetic fields.

Abstract: A structure provides a gradient field useful in magnetic resonance imaging. Axially aligned, solenoidal-like coils are symmetrically distributed around the perimeter of the bore of a superconducting magnet in an MRI system so as to produce transverse gradients in the X and Y directions with exceptionally high efficiency and exceptionally low acoustic noise. Opposed solenoidal endcoils may be added to reduce axial flux leakage by generating an axial quadrupolar field. Radially aligned coils may be positioned near each end of the axial coils to reduce leakage flux by adding a transverse quadrupolar field to form a resulting octopolar field. Typically, the solenoid-like coils have a mean radius of about 15% of the radius of that of the imaging ellipsoidal region. A thick-walled stainless steel, copper and resin cylinder may be used to simplify gradient shielding problems. Silver plated bronze or stainless steel sheet is used as an rf shield.

Abstract: Whirl forces in a high-speed hydrostatic air bearing are reduced by orienting the gas supply nozzles so that the pressurized gas enters the bearing opposite to the direction of rotation of the shaft. Stiffness also is thereby increased. Stable operation at supersonic surface speeds may thus be achieved. Diffuser chamfers may be added to the bearing surface to enhance performance at very high pressure ratios. This anti-whirl air bearing is effectively used to support a nuclear magnetic resonance cylindrical sample container capable of high-speed spinning for line-narrowing of solid samples. Motive power required to spin the container at supersonic surface speeds is provided by radial-inflow microturbines with tip diameter less than the bearing diameter and supersonic inlet gas velocities. An axial thrust bearing is included between the microturbine and the sample container.