Patents by Inventor Fabrizio Piemontesi

Fabrizio Piemontesi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20180215845
    Abstract: A gas-phase process for the homopolymerization or copolymerization of propylene with other olefins, including carrying out the polymerization in the presence of a catalyst system made from or containing: (a) a solid catalyst component made from or containing Mg, Ti, halogen, an electron donor selected from 1.3-diethers and an olefin polymer in a specific amount; (b) an aluminum alkyl compound and (c) an external electron donor (ED) compound, wherein components (b) and (c) being employed in amounts such that the Al/(ED) molar ratio ranges from about 2 to about 200.
    Type: Application
    Filed: August 3, 2016
    Publication date: August 2, 2018
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: GIAMPIERO MORINI, MASSIMO COVEZZI, TIZIANO DALL'OCCO, DARIO LIGUORI, FABRIZIO PIEMONTESI, GIANNI VITALE
  • Publication number: 20180201003
    Abstract: A film made from or containing a polyolefin composition made from or containing: A) from about 19 wt % to about 50 wt %, based upon the total weight of the polyolefin composition, of a propylene ethylene copolymer having an ethylene derived units content ranging from about 1.5 wt % to about 6.0 wt %, based upon the total weight of the propylene ethylene copolymer; and B) from about 50 wt % to about 81 wt %, based upon the total weight of the polyolefin composition, of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from about 1.5 wt % to about 6.0 wt %, based upon the total weight of the propylene ethylene 1-butene terpolymer, and 1-butene derived units content of between about 4.8 wt % and about 12.4 wt %, based upon the total weight of the propylene ethylene 1-butene terpolymer; the sum of the amount of component A) and B) being 100.
    Type: Application
    Filed: July 19, 2016
    Publication date: July 19, 2018
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: PAOLA MASSARI, CAROLINE CATHELIN, CLAUDIO CAVALIERI, MARCO CIARAFONI, ANDREA FELISATI, ANGELO FERRARO, GIAMPIERO MORINI, FABRIZIO PIEMONTESI, GIANNI VITALE
  • Patent number: 9683062
    Abstract: The present disclosure relates to a process for the preparation of a porous propylene carried out in the presence of a catalyst system comprising (a) a Ziegler-Natta catalyst containing at least two electron donor compounds, one of which is present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates, and the other being selected from 1,3 diethers, (b) an aluminum alkyl and comprising the following steps: i) contacting the catalyst components (a) and (b) for a period of time ranging from 1 to 60 minutes, at a temperature ranging from 35 to 55° C.; optionally, ii) pre-polymerizing with one or more olefins of formula CH2?CHR, where R is H or a C1-C10 hydrocarbon group, up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); and iii) polymerizing propylene in the optional presence of minor amounts of ethylene and/or C4-C10 alpha olefins for producing the porous propylene (co)polymer.
    Type: Grant
    Filed: October 21, 2014
    Date of Patent: June 20, 2017
    Assignee: Basell Poliolefin Italia S.r.l.
    Inventors: Benedetta Gaddi, Marco Bocchino, Gianni Collina, Ofelia Fusco, Simona Guidotti, Antonio Mazzucco, Roberto Pantaleoni, Fabrizio Piemontesi
  • Patent number: 9676883
    Abstract: The present disclosure relates to propylene-ethylene copolymers comprising an ethylene content of 0.1-10% by weight, a molecular weight distribution (MWD), expressed in terms of Mw/Mn, of greater than 3.0 and a xylene soluble (XS) fraction content defined by values that fall below the line given by the equation XS=1.0296·e0.435C2. The propylene-ethylene copolymers advantageously exhibit high transparency and low melting temperatures.
    Type: Grant
    Filed: May 6, 2015
    Date of Patent: June 13, 2017
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Fabrizio Piemontesi, Caroline Cathelin, Simona Guidotti, Dario Liguori, Giampiero Morini, Davide Tartari, Gianni Vitale
  • Patent number: 9598511
    Abstract: A solid catalyst component for the (co)polymerization of olefins CH2?CHR, in which R is a hydrocarbyl radical with 1-12 carbon atoms, optionally in mixture with ethylene, comprising Ti, Mg, Cu, Cl, and an electron donor compound characterized by the fact that the Cu/Ti weight ratio is lower than 0.5.
    Type: Grant
    Filed: April 2, 2014
    Date of Patent: March 21, 2017
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Simona Guidotti, Dario Liguori, Giampiero Morini, Fabrizio Piemontesi
  • Publication number: 20170073444
    Abstract: The present disclosure relates to propylene-ethylene copolymers comprising an ethylene content of 0.1-10% by weight, a molecular weight distribution (MWD), expressed in terms of Mw/Mn, of greater than 3.0 and a xylene soluble (XS) fraction content defined by values that fall below the line given by the equation XS=1.0296·e0.435C2. The propylene-ethylene copolymers advantageously exhibit high transparency and low melting temperatures.
    Type: Application
    Filed: May 6, 2015
    Publication date: March 16, 2017
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: FABRIZIO PIEMONTESI, CAROLINE CATHELIN, SIMONA GUIDOTTI, DARIO LIGUORI, GIAMPIERO MORINI, DAVIDE TARTARI, GIANNI VITALE
  • Patent number: 9593171
    Abstract: A porous solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor to the succinate donor is higher than, or equal to, 0.60.
    Type: Grant
    Filed: March 29, 2012
    Date of Patent: March 14, 2017
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Simona Guidotti, Giampiero Morini, Simona Esposito, Alessandro Mignogna, Joachim T. M. Pater, Fabrizio Piemontesi, Diego Brita
  • Publication number: 20170066855
    Abstract: The present disclosure relates to a propylene ethylene copolymer comprising: an ethylene content of between 1.8 and 10.0% by weight; a molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; a content of xylene soluble fraction (XS) and ethylene content (C2) that fulfills the following relationship: XS<(C2×2.1)?2.4 where: XS=% by weight of the fraction soluble in xylene at 25° C.; and C2=% by weight of ethylene units in the copolymer as determined via NMR.
    Type: Application
    Filed: April 28, 2015
    Publication date: March 9, 2017
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: PAOLA MASSARI, FABRIZIO PIEMONTESI, GIANNI VITALE, CAROLINE CATHELIN, GIAMPIERO MORINI, MARCO CIARAFONI, CLAUDIO CAVALIERI, TIZIANA CAPUTO
  • Publication number: 20170066851
    Abstract: The present disclosure relates to a solid catalyst component for the (co)polymerization of olefins CH2?CHR, in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Ti, Mg, and Cl, and optionally an electron donor compound selected from the group consisting of ethers, amines, silanes, carbamates ketones, esters of aliphatic acids, alkyl and aryl esters of optionally substituted aromatic polycarboxylic acids, diol derivatives chosen among monoesters monocarbamates and monoesters monocarbonates or mixtures thereof, comprising from 0.1 to 50% wt of Bi with respect to the total weight of the solid catalyst component.
    Type: Application
    Filed: March 10, 2015
    Publication date: March 9, 2017
    Applicant: BASELL POLIOLEFIINE ITALIA S.R.L.
    Inventors: SIMONA GUIDOTTI, TIZANO DALL'OCCO, DARIO LIGUORI, GIAMPIERO MORINI, FABRIZIO PIEMONTESI, GIANNI VITALE
  • Publication number: 20170066856
    Abstract: The present disclosure relates to a multilayer film characterized by one or more skin layers comprising propylene/ethylene copolymers characterized by the following features: an ethylene derived units content of between 1.0 wt % and 15.0% wt %; and a molecular weight distribution (MWD), expressed in terms of Mw/Mn, of greater than 4.0; a content of xylene soluble fraction (XS) and an ethylene derived units content (C2) that fulfills the following relationship: XS<1.0296·e0.435C2 where XS is the percentage by weight of the fraction soluble in xylene at 25° C., and C2 is the percentage by weight of ethylene units in the copolymers as determined via NMR.
    Type: Application
    Filed: April 28, 2015
    Publication date: March 9, 2017
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: PAOLA MASSARI, FABRIZIO PIEMONTESI, GIANNI VITALE, CAROLINE CATHELIN, GIAMPIERO MORINI, MARCO CIARAFONI, CLAUDIO CAVALIERI, ANDREA ISATI
  • Publication number: 20160304642
    Abstract: The present disclosure relates to a process for the preparation of a porous propylene carried out in the presence of a catalyst system comprising (a) a Ziegler-Natta catalyst containing at least two electron donor compounds, one of which is present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates, and the other being selected from 1,3 diethers, (b) an aluminum alkyl and comprising the following steps: i) contacting the catalyst components (a) and (b) for a period of time ranging from 1 to 60 minutes, at a temperature ranging from 35 to 55° C.; optionally, ii) pre-polymerizing with one or more olefins of formula CH2?CHR, where R is H or a C1-C10 hydrocarbon group, up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); and iii) polymerizing propylene in the optional presence of minor amounts of ethylene and/or C4-C10 alpha olefins for producing the porous propylene (co)polymer.
    Type: Application
    Filed: October 21, 2014
    Publication date: October 20, 2016
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: BENEDETTA GADDI, MARCO BOCCHINO, GIANNI COLLINA, OFELIA FUSCO, SIMONA GUIDOTTI, ANTONIO MAZZUCCO, ROBERTO PANTALEONI, FABRIZIO PIEMONTESI
  • Publication number: 20160032026
    Abstract: A solid catalyst component for the (co)polymerization of olefins CH2?CHR, in which R is a hydrocarbyl radical with 1-12 carbon atoms, optionally in mixture with ethylene, comprising Ti, Mg, Cu, Cl, and an electron donor compound characterized by the fact that the Cu/Ti weight ratio is lower than 0.5.
    Type: Application
    Filed: April 2, 2014
    Publication date: February 4, 2016
    Applicant: BASEBALL POLYOLEFINE ITALIA S.R.L.
    Inventors: Simona Guidotti, Dario Liguori, Giampiero Morini, Fabrizio Piemontesi
  • Publication number: 20150353653
    Abstract: A liquid phase process for the polymerization of butene-1 carried out in the presence of a catalyst comprising (a) a solid catalyst component comprising Mg, Ti and an electron donor compound of the following formula (I) in which the R groups, equal to or different from each other, are C1-C10 hydrocarbon groups; (b) an aluminium alkyl cocatalyst and (c) an external electron donor.
    Type: Application
    Filed: January 14, 2014
    Publication date: December 10, 2015
    Inventors: Gianni Vitale, Simona Esposito, Simona Guidotti, Alessandro Mignogna, Giampiero Morini, Fabrizio Piemontesi
  • Publication number: 20150259443
    Abstract: Catalyst components component for the (co)polymerization of olefins CH2?CHR, in which R is a hydrocarbyl radical with 1-12 carbon atoms, optionally in mixture with ethylene, comprising Ti, Mg, Zn, Cl, and an electron donor compound characterized by the fact that more than 50% of the titanium atoms are in the +4 valence state, and that the amount of Zn ranges from 0.1 to 4% by weight based on then total weight of said solid catalyst component.
    Type: Application
    Filed: September 25, 2013
    Publication date: September 17, 2015
    Applicant: Basell Poliolefine Italia S.r.l.
    Inventors: Simona Guidotti, Simona Esposito, Dario Liguori, Giampiero Morini, Fabrizio Piemontesi, Gianni Vitale
  • Patent number: 9068029
    Abstract: A process for the preparation of propylene polymer compositions comprising from 50 to 90% by weight of a propylene polymer fraction insoluble in xylene at 25° C., and from 10 to 50% by weight of an ethylene copolymer fraction soluble in xylene at 25° C., said process being carried out in the presence of a specific catalyst system, is also characterized by the following step: (i) contacting the catalyst components (a), (b) and optionally (c) for a period of time ranging from 0.1 to 120 minutes, at a temperature ranging from 0 to 90° C.; (ii) polymerizing propylene in the optional presence of ethylene and/or C4-C10 alpha olefins producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25° C. and (iii) in a successive step, carried out in gas-phase, in the presence of the product coming from (ii), polymerizing mixtures of ethylene with ?-olefins CH2?CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce an ethylene copolymer.
    Type: Grant
    Filed: November 15, 2010
    Date of Patent: June 30, 2015
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Gianni Collina, Marco Ciarafoni, Ofelia Fusco, Benedetta Gaddi, Monica Galvan, Giampiero Morini, Roberto Pantaleoni, Joachim T. M. Pater, Fabrizio Piemontesi, Francesca Verrocchio
  • Publication number: 20150141595
    Abstract: Process for the polymerization of butene-1 carried out in the presence of a catalyst comprising (a) a solid catalyst component comprising Mg, Ti and an electron donor compound of the following formula (I) In which the R groups equal to or different from each other, are C1-C15 hydrocarbon groups, the R1-R2 groups, equal to or different from each other, are hydrogen, halogen or C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0; (b) An aluminium alkyl cocatalyst and (c) an external electron donor
    Type: Application
    Filed: May 13, 2013
    Publication date: May 21, 2015
    Applicant: Basell Poliolefine Italia S.r.l
    Inventors: Alessandro Mignogan, Simona Esposito, Simona Guidotti, Giampiero Morini, Joachim T.M. Pater, Fabrizio Piemontesi, Gianni Vitale
  • Patent number: 8835578
    Abstract: Catalyst component for the polymerization of olefins CH2?CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and two electron donor compounds one of which selected from alkoxybenzenes and the other being selected from those of formula (II) where RI and RII are the same or different and are hydrogen or linear or branched C1-C18 hydrocarbon groups which can also form one or more cyclic structures; RIII groups, equal or different from each other, are hydrogen or C1-C18 hydrocarbon groups; RIV groups equal or different from each other, have the same meaning of RIII except that they cannot be hydrogen; each of RI to RIV groups can contain heteroatoms selected from halogens, N, O, S and Si.
    Type: Grant
    Filed: February 22, 2011
    Date of Patent: September 16, 2014
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Simona Guidotti, Fabrizio Piemontesi, Joachim T. M. Pater, Giampiero Morini
  • Patent number: 8829126
    Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti, halogen and two electron donor compounds one of which selected those of formula (I) and the other being selected from succinates of formula (II):
    Type: Grant
    Filed: February 22, 2011
    Date of Patent: September 9, 2014
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Simona Guidotti, Fabrizio Piemontesi, Joachim T. M. Pater, Giampiero Morini
  • Publication number: 20140243489
    Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R to R12 groups, equal to or different from each other, are hydrogen, halogen or C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, with the proviso that R groups cannot be hydrogen and that the carboxylate groups are in trans configuration with respect to each other.
    Type: Application
    Filed: October 11, 2012
    Publication date: August 28, 2014
    Applicant: Basell Poliolefine Italia S.r.l.
    Inventors: Ilya Nifant'ev, Alessandro Mignogna, Vladimir Bagrov, Simona Esposito, Simona Guidotti, Giampiero Morini, Joachim T.M. Pater, Fabrizio Piemontesi, Sophia A. Toloraya
  • Publication number: 20140046010
    Abstract: A porous solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor to the succinate donor is higher than, or equal to, 0.60.
    Type: Application
    Filed: March 29, 2012
    Publication date: February 13, 2014
    Applicant: Basell Poliolefine Italia S.r.I.
    Inventors: Simona Guidotti, Giampiero Morini, Simona Esposito, Alessandro Mignogna, Joachim T.M. Pater, Fabrizio Piemontesi, Diego Brita