Abstract: Systems and methods for separating a mixture of olefinic and paraffinic C4 components are disclosed. The systems and methods include adsorptive equipment and adsorptive processes for separating components from the mixture.

Abstract: A mechanism for generating optimized native code for a program having dynamic behavior uses a static analysis of the program to predict the likelihood that different elements of the program are likely to be used when the program executes. The static analysis is performed prior to execution of the program and marks certain elements of the program with confidence indicators that classify the elements with either a high level of confidence or a low level of confidence. The confidence indicators are then used by an ahead-of-time native compiler to generate native code and to optimize the code for faster execution and/or a smaller-sized native code.

Abstract: A desalination cell which works with flat membranes for water purification purposes. A feed fluid is stirred on a feed side of the membrane to minimize cake formation. A purified liquid is formed on the permeate side of the membrane, and a reject fluid formed on the feed side of the membrane. When thick ceramic membranes are used, the desalination cell can be adapted to have a sealing gasket around the circumference of the membrane to prevent the feed fluid from by-passing the membrane and contaminating the purified fluid.

Abstract: A mechanism for generating optimized native code for a program having dynamic behavior uses a static analysis of the program to predict the likelihood that different elements of the program are likely to be used when the program executes. The static analysis is performed prior to execution of the program and marks certain elements of the program with confidence indicators that classify the elements with either a high level of confidence or a low level of confidence. The confidence indicators are then used by an ahead-of-time native compiler to generate native code and to optimize the code for faster execution and/or a smaller-sized native code.

Abstract: A desalination cell which works with flat membranes for water purification purposes. A feed fluid is stirred on a feed side of the membrane to minimize cake formation. A purified liquid is formed on the permeate side of the membrane, and a reject fluid formed on the feed side of the membrane. When thick ceramic membranes are used, the desalination cell can be adapted to have a sealing gasket around the circumference of the membrane to prevent the feed fluid from by-passing the membrane and contaminating the purified fluid.

Abstract: The antiscalant compound is a dianionic polyelectrolyte (DAPE), namely, poly[disodium 3-(N,N-diallylamino)propanephosphonate]. The cationic polyelectrolyte (CPE) polydiallyl(diethylphosphonato)propylammonium chloride is synthesized by cyclopolymerization of the monomer. The CPE contains a pendant having a three-carbon spacer separating the diethylphosphonate and NH+. Upon acidic hydrolysis of the phosphonate esters, the CPE was converted into a pH-responsive polyzwitterionic acid (PZA), poly[3-(N,N-diallylammonio)propanephosphonic acid], which was converted to DAPE poly[disodium 3-(N,N-diallylamino)propanephosphonate] and to a zwitterionic/anionic polyelectrolyte (ZAPE) poly[sodium 3-(N,N-diallylammonio)propanephosphonate]. The solution properties of the polymers were correlated to the structurally similar polyzwitterion (PZ) having monoethylphosphonate and NH+ groups.

Abstract: The oxidative dehydrogenation of propane provides a highly selective catalyst for the oxidative dehydrogenation of propane to propylene, and a process for preparing the catalyst. The catalyst is a mixed metal oxides catalyst of the general formula MoaVbOx, where the molar ratio of molybdenum to vanadium is between 1:1 and 9:1 (a:b is between 0.5:0.5 and 0.9:0.1) and x is determined according to the oxidation state of the cations present. The catalyst is prepared by mixing the metals by sol-gel technique, heating the gel to dry the mixed oxides, further heating the dried product to induce auto-combustion, washing the product with isopropyl alcohol, and drying with a supercritical CO2 dryer. Oxidative dehydrogenation is carried out by contacting a stream of propane gas with the bulk mixed metal oxides catalyst at a temperature between 350° C. and 550° C. Propylene selectivity of 100% is reached at conversion rates between 1.9% and 4.8%.

Abstract: The catalyst for oxidative dehydrogenation of propane to propylene includes vanadium and aluminum incorporated into the framework of a mesoporous support, viz., MCM-41, to form V—Al-MCM-41, and nickel impregnated onto the walls of the mesoporous support. Nickel loading is preferably in the range of 5 to 15% by weight of the catalyst. A process for the production of propylene from propane includes steps of placing the catalyst in a fixed bed reactor, introducing a flow of feedstock in a propane:oxygen:nitrogen ratio of about 6:6:88 by volume, maintaining the reactor at atmospheric pressure and in a temperature range of about 400 to 550° C., collecting the product, and separating propylene from the product. The process achieves propane conversion between about 6 to 22%, and a selectivity for propylene between about 22 and 70%, depending upon percent nickel content and temperature of the reaction.

Abstract: The device for testing reverse osmosis membranes provides for the quick and efficient testing of the transport properties of reverse osmosis membranes at a fixed pressure over a fixed period of time. The device includes a first chamber adapted for receiving a volume of de-ionized water and a second chamber adapted for receiving a volume of brine. In use, a reverse osmosis membrane to be tested is clamped between the first and second chambers and a pressurized inert gas, such as gaseous nitrogen, is injected into the second chamber at known pressure to initiate reverse osmosis transport. The transport is carried out at the known pressure for a fixed period of time, after which the concentration of brine volume of water in the first chamber is measured.

Abstract: The oxidative dehydrogenation of propane provides a highly selective catalyst for the oxidative dehydrogenation of propane to propylene, and a process for preparing the catalyst. The catalyst is a mixed metal oxides catalyst of the general formula MoaVbOx, where the molar ratio of molybdenum to vanadium is between 1:1 and 9:1 (a:b is between 0.5:0.5 and 0.9:0.1) and x is determined according to the oxidation state of the cations present. The catalyst is prepared by mixing the metals by sol-gel technique, heating the gel to dry the mixed oxides, further heating the dried product to induce auto-combustion, washing the product with isopropyl alcohol, and drying with a supercritical CO2 dryer. Oxidative dehydrogenation is carried out by contacting a stream of propane gas with the bulk mixed metal oxides catalyst at a temperature between 350° C. and 550° C. Propylene selectivity of 100% is reached at conversion rates between 1.9% and 4.8%.

Abstract: The device for testing reverse osmosis membranes provides for the quick and efficient testing of the transport properties of reverse osmosis membranes at a fixed pressure over a fixed period of time. The device includes a first chamber adapted for receiving a volume of de-ionized water and a second chamber adapted for receiving a volume of brine. In use, a reverse osmosis membrane to be tested is clamped between the first and second chambers and a pressurized inert gas, such as gaseous nitrogen, is injected into the second chamber at known pressure to initiate reverse osmosis transport. The transport is carried out at the known pressure for a fixed period of time, after which the concentration of brine volume of water in the first chamber is measured.

Abstract: The catalyst for oxidative dehydrogenation of propane to propylene includes vanadium and aluminum incorporated into the framework of a mesoporous support, viz., MCM-41, to form V—Al-MCM-41, and nickel impregnated onto the walls of the mesoporous support. Nickel loading is preferably in the range of 5 to 15% by weight of the catalyst. A process for the production of propylene from propane includes steps of placing the catalyst in a fixed bed reactor, introducing a flow of feedstock in a propane:oxygen:nitrogen ratio of about 6:6:88 by volume, maintaining the reactor at atmospheric pressure and in a temperature range of about 400 to 550° C., collecting the product, and separating propylene from the product. The process achieves propane conversion between about 6 to 22%, and a selectivity for propylene between about 22 and 70%, depending upon percent nickel content and temperature of the reaction.

Abstract: The present invention relates to a supported catalyst system for olefin polymerization which comprises at least one metallocene component and a support of an inorganic oxide of silica, aluminum or a polymer containing hydroxyl groups. The support is modified with an organogermane and/or organotin compound. The inventive catalyst system produces minimal reactor fouling, has excellent productivity and good hydrogen responsiveness. The present invention also relates to a process for preparing the catalyst system and to the slurry/suspension or gas-phase polymerization of olefins using the catalytic system, optionally with a small amount of aluminoxane cocatalyst.

Abstract: The present invention relates to a supported catalyst system for olefin polymerization which comprises at least one metallocene component and a support of an inorganic oxide of silica, aluminum or a polymer containing hydroxyl groups. The support is modified with an organogermane and/or organotin compound. The inventive catalyst system produces minimal reactor fouling, has excellent productivity and good hydrogen responsiveness. The present invention also relates to a process for preparing the catalyst system and to the slurry/suspension or gas-phase polymerization of olefins using the catalytic system, optionally with a small amount of aluminoxane cocatalyst.