Abstract: A method for preparing fluorine/nitrogen co-doped graphitized carbon microspheres with high volumetric specific capacitance, mainly comprises: successively adding a carbon source, a nitrogen source, a fluorine source and a surfactant to a reactor under a nitrogen atmosphere, and stirring for 10-30 minutes before sealing the reactor; placing the reactor into a crucible furnace, heating at 300-600° C., for 6-48 hours, followed by naturally codling the reactor to room temperature and removing the reaction mixture therefrom; successively washing the resulted reaction mixture with absolute ethanol, 0.1 M-5 M diluted hydrochloride acid and distilled water for 3-6 times, filtering, and placing powder thus obtained in a vacuum oven and drying in vacuum at 60-100° C. for 6-12 hours. The present invention provides a simple process with moderate reaction conditions, high reproducibility, and low costs.