Abstract: The present invention relates to a method for preparing an aqueous dispersion of acrylate-siloxane copolymer particles as described herein. The polymer particles comprise structural units of an acrylate monomer; an acid monomer; and a siloxane acrylate monomer of formula I: where R, R1, R2, Y and x are as defined herein. The method provides an efficient way to prepare a high solids content aqueous dispersion of siloxane-acrylate hybrid copolymers with efficient incorporation of siloxane acrylate monomers, low residual monomer, and low generation of unwanted coagulum. The dispersion is useful for forming coatings with improved hydrophobicity, stain resistance, and aesthetic/haptic properties compared with conventional all-acrylic compositions.

Abstract: A polymer blend is provided comprising: a single stage polymer and a silicone-grafted vinyl copolymer; wherein the single stage polymer comprises: structural units of a monoethylenically unsaturated non-ionic monomer; structural units of a monoethylenically unsaturated carboxylic acid monomer; and structural units of a multiethylenically unsaturated monomer having at least two ethylenically unsaturated groups per molecule; and wherein the silicone-grafted vinyl copolymer, comprises: structural units of a vinyl monomer; and structural units of a carbosiloxane dendrimer of formula (I). Also provided is a suncare formulation comprising the polymer blend in a dermatologically acceptable carrier with a suncare active.

Abstract: A hydrophilic silica/polymer blend is provided comprising (a) a hydrophilic silica powder; and (b) a thickening polymer powder, comprising (i) structural units of C4-8 alkyl (meth)acrylate monomer; (ii) structural units of (meth)acrylic acid monomer; (iii) structural units of (methoxy) poly(ethylene glycol) (meth)acrylate monomer; and (iv) structural units of multiethylenically unsaturated monomer; wherein the weight ratio of hydrophilic silica powder to thickening polymer powder in the hydrophilic silica/polymer blend is 1:9 to 9:1. Also provided are personal care compositions containing same and methods of using same.

Abstract: A color cosmetic formulation is provided comprising: a color ingredient and a polymer blend, comprising: a single stage polymer and a silicone-grafted vinyl copolymer; wherein the single stage polymer comprises: structural units of a monoethylenically unsaturated non-ionic monomer; structural units of a monoethylenically unsaturated carboxylic acid monomer; and structural units of a multiethylenically unsaturated monomer having at least two ethylenically unsaturated groups per molecule; and wherein the silicone-grafted vinyl copolymer, comprises: structural units of a vinyl monomer; and structural units of a carbosiloxane dendrimer of formula (I).

Abstract: A personal care formulation is provided comprising: multistage polymer, comprising: acrylate rich stage comprising: (a) structural units of monoethylenically unsaturated non-ionic, acrylate rich stage monomer selected from C1-22 alkyl (meth)acrylates and mixtures thereof; and (b) carbosiloxane rich stage, comprising: structural units of carbosiloxane monomer of formula (I), wherein a is 0 to 3; wherein d is 0 or 1; wherein R1 is selected from hydrogen, C1-10 alkyl group and aryl group; wherein R2 is selected from hydrogen and C1-10 alkyl group; wherein R8 is —O—Si(CH3)2—O—Si(CH3)3 group; wherein Y is selected from formula (II), (III) and (IV); wherein R4 and R6 are selected from hydrogen and methyl group; wherein R3 and R5 are a C1-10 alkylene group; wherein R7 is C1-10 alkyl group; wherein b is 0 to 4 and wherein c is 0 or 1.

Abstract: A polymer blend is provided comprising: (A) multistage polymer, comprising: acrylate rich stage comprising: structural units of monoethylenically unsaturated non-ionic, acrylate rich stage monomer selected from C1-22 alkyl (meth)acrylates and mixtures thereof; and carbosiloxane rich stage, comprising: structural units of carbosiloxane monomer of formula (I); and (B) silicone-grafted vinyl copolymer, wherein the silicone-grafted vinyl copolymer, comprises: structural units of a vinyl (B) monomer; and structural units of a carbosiloxane dendrimer of formula (V). Also provided are personal care formulations comprising the polymer blend.

Abstract: A personal care composition is provided, comprising: a vehicle; a cosmetically acceptable oil; and a cationic polymer comprising structural units of acrylamide monomer; structural units of N,N-dimethyl acrylamide monomer; and structural units of monoethylenically unsaturated monocationic monomer; wherein the cationic polymer comprises <10 mol % structural units of multiethylenically unsaturated cationic monomer; wherein the cationic polymer comprises <30 wt % structural units of ester containing monomers; wherein the cationic polymer comprises <1 mol % structural units of ethylenically unsaturated monomers containing a moiety selected from the group consisting of epoxy, anhydride, imide, lactone, carboxylic acid, sulfonic acid and isocyanate; wherein the cationic polymer comprises <0.1 mol % structural units of a reactive siloxane; and wherein the personal care composition comprises <0.05 wt % water soluble, organic, ampholytic polymer conditioning agent.

Abstract: A multistage polymer is provided, comprising: acrylate rich stage comprising: (a) structural units of monoethylenically unsaturated non-ionic, acrylate rich stage monomer selected from C1-22 alkyl (meth)acrylates and mixtures thereof; and (b) carbosiloxane rich stage, comprising: structural units of carbosiloxane monomer of formula (I), wherein a is 0 to 3; wherein d is 0 or 1; wherein R1 is selected from hydrogen, C1-10 alkyl group and aryl group; wherein R2 is selected from hydrogen and C1-10 alkyl group; wherein R8 is —O—Si(CH3)2—O—Si(CH3)3 group; wherein Y is selected from formula (II), (III) and (IV); wherein R4 and R6 are selected from hydrogen and methyl group; wherein R3 and R5 are a C1-10 alkylene group; wherein R7 is C1-10 alkyl group; wherein b is 0 to 4 and wherein c is 0 or 1.

Abstract: A multistage polymer is provided, having: acrylate rich stage comprising: (a) structural units of monomer selected from C1-22 alkyl (meth)acrylates and structural units of first carbosiloxane monomer of formula (I); and (b) carbosiloxane rich stage, comprising: structural units of second carbosiloxane monomer of formula (I); wherein a is 0 to 3; wherein d is 0 or 1; wherein R1 is selected from hydrogen, C1-10 alkyl group and aryl group; wherein R2 is selected from hydrogen and C1-10 alkyl group; wherein R8 is —O—Si(CH3)3 group; wherein Y is selected from formula (II), (III) and (IV); wherein R4 and R6 are selected from hydrogen and methyl group; wherein R3 and R5 are a C1-10 alkylene group; wherein R7 is C1-10 alkyl group; wherein b is 0 to 4 and wherein c is 0 or 1; and wherein the first and second carbosiloxane monomer of formula (I) are same or different.

Abstract: Personal care formulation is provided having multistage polymer, comprising: acrylate rich stage comprising: (a) structural units of monomer selected from C1-22 alkyl (meth)acrylates and structural units of first carbosiloxane monomer of formula (I); and (b) carbosiloxane rich stage, comprising: structural units of second carbosiloxane monomer of formula (I); wherein a is 0 to 3; wherein d is 0 or 1; wherein R1 is selected from hydrogen, C1-10 alkyl group and aryl group; wherein R2 is selected from hydrogen and C1-10 alkyl group; wherein R8 is —O—Si(CH3)3 group; wherein Y is selected from formula (II), (III) and (IV); wherein R4 and R6 are selected from hydrogen and methyl group; wherein R3 and R5 are C1-10 alkylene group; wherein R7 is C1-10 alkyl group; wherein b is 0 to 4 and wherein c is 0 or 1; and wherein the first and second carbosiloxane monomer of formula (I) are same or different.

Abstract: A polymer/hydrophilic silica blend is provided comprising (a) a thickening polymer powder, comprising (i) structural units of C4-8 alkyl (meth)acrylate monomer; (ii) structural units of (meth)acrylic acid monomer, and (iii) structural units of a specialized associative monomer of formula (I) wherein R1 is a linear saturated C10-20 alkyl group; and n is an average of 20 to 28; and (b) a hydrophilic silica powder; wherein the weight ratio of hydrophilic silica powder to thickening polymer powder in the polymer/hydrophilic silica blend is 1:9 to 9:1. Also provided are personal care compositions containing same and methods of using same.

Abstract: A fabric care formulation is provided, comprising: a liquid carrier; and a plurality of composite opacifier particles, wherein the composite opacifier particles comprise metal oxide particles that are partially or completely encapsulated by a wax; wherein the metal oxide particles are selected from the group consisting of zinc oxide, titanium oxide and mixtures thereof; wherein the metal oxide particles have a z average particle size of >100 nm as measured by dynamic light scattering; wherein the wax has a melting point temperature of 45 to 110° C.; and wherein the composite opacifier particles have a z average particle size of >100 nm to 2,000 nm as measured by dynamic light scattering.

Abstract: An aqueous personal care rinse off composition is provided, comprising: a dermatologically acceptable aqueous vehicle; a dermatologically acceptable cleaning surfactant; and a plurality of composite opacifier particles, wherein the composite opacifier particles comprise metal oxide particles that are partially or completely encapsulated by a wax; wherein the metal oxide particles are selected from the group consisting of zinc oxide, titanium oxide and mixtures thereof; wherein the metal oxide particles have a z average particle size of >100 nm as measured by dynamic light scattering; wherein the wax has a melting point temperature of 50 to 110° C.; and wherein the composite opacifier particles have a z average particle size of >100 nm to 2,000 nm as measured by dynamic light scattering.

Abstract: Described herein are aspherical hollow silica particles, processes for making aspherical hollow silica particles, and uses of aspherical hollow silica particles in sun care compositions. To form the aspherical hollow silica particles, deposition of a silica shell on a calcium carbonate template using a sol-gel chemistry is employed. Subsequent dissolution of the calcium carbonate template forms voids (e.g., a hollow interior) in the aspherical hollow silica particles.

Abstract: A fixative polymer is provided, comprising: structural units of monoethylenically unsaturated C1-12 alkyl (meth)acrylate monomer; structural units of monoethylenically unsaturated carboxylic acid containing monomer; structural units of monoethylenically unsaturated hydroxy functionalized C1-16 alkyl (meth)acrylate monomer; and structural units of carbosiloxane monomer of formula (I) wherein a is 0 to 3; wherein d is 0 or 1; wherein R1 is hydrogen, C1-10 alkyl, aryl, —OSi(R9)3 or —X—SiOSi(R9)3; wherein R2 and R9 are hydrogen or C1-10 alkyl; wherein R8 is —OSi(CH3)2OSi(CH3)3; wherein Y is formula (II), (III), (IV) or (V) wherein R4, R6 and R10 are hydrogen or C1-4 alkyl; wherein X, R3 and R5 are a divalent linking group; wherein R7 is a C1-10 alkyl group; wherein b is 0 to 4 and wherein c is 0 or 1.

Abstract: An aqueous antiperspirant composition is provided, comprising: (A) water; (B) a sweat repellent polymer, comprising a multistage polymer comprising: an acrylate rich stage comprising: structural units of a monoethylenically unsaturated nonionic acrylate rich stage monomer; and structural units of a first carbosiloxane monomer of formula (I); and a carbosiloxane rich stage, comprising: structural units of a vinyl monomer; and structural units of a second carbosiloxane monomer of formula (I); wherein the first carbosiloxane monomer of formula (I) and the second carbosiloxane monomer of formula (I) are the same or different; and (C) an antiperspirant aluminum salt; wherein the aqueous antiperspirant composition is an emulsion. Also provided are methods of using the same.

Abstract: A silicone-(meth) acrylate copolymer and methods for the preparation and use of the copolymer are provided. The copolymer is soluble in ethanol under ambient conditions. The copolymer, or homogeneous ethanol solution thereof, may be used as a film forming agent in a personal care composition, such as a foundation.

Abstract: The present invention is a method for preparing a aqueous dispersion of copolymer particles comprising structural units of a) an acrylate monomer; b) an acid monomer; and c) a siloxane acrylate monomer of formula I: where R, R1, R2, Y and x are defined herein. The method also requires the use of special classes on anionic and nonionic surfactants as described herein. The aqueous dispersion prepared by the method of the present invention is useful in a variety of applications ranging from architectural coatings to personal care products.

Abstract: The present invention is a composition comprising an aqueous dispersion of copolymer particles comprising structural units of a) an acrylate monomer; b) an acid monomer; and c) a siloxane-acrylate monomer of formula I: where R, R1, R2, Y and x are defined herein. The composition, which also comprises a nonionic and anionic surfactant as described herein, is useful in a variety of applications ranging from architectural coatings to personal care products.

Abstract: A method for styling hair comprises placing the hair in a desired configuration and applying a hair styling composition to the hair. The hair styling composition comprises a powder of a multistage polymer of a soft polymer of Tg<40° C.; and a hard polymer having a Tg>40° C., and at least 10° C. higher than the Tg of the soft polymer wherein the hard polymer forms a complete or partial shell around the soft polymer the weight ratio of hard polymer to soft polymer being 1.01:1 to 2:1. After exposure to liquid water and drying at temperatures below 100° C., a maximum thermal transition temperature of the multistage polymer in an atmosphere of 0% relative humidity that differs by 20° C. or less from the maximum thermal transition temperature in an atmosphere of 75% relative humidity.