Abstract: A method for styling hair comprises placing the hair in a desired configuration and applying a hair styling composition to the hair. The hair styling composition comprises a powder of a multistage polymer of a soft polymer of Tg<40° C.; and a hard polymer having a Tg>40° C., and at least 10° C. higher than the Tg of the soft polymer wherein the hard polymer forms a complete or partial shell around the soft polymer the weight ratio of hard polymer to soft polymer being 1.01:1 to 2:1. After exposure to liquid water and drying at temperatures below 100° C., a maximum thermal transition temperature of the multistage polymer in an atmosphere of 0% relative humidity that differs by 20° C. or less from the maximum thermal transition temperature in an atmosphere of 75% relative humidity.

Abstract: Described herein are sun care compositions comprising at least one sunscreen active and hollow mesoporous silica nanospheres, and methods of making and using the sun care compositions. The presently described sun care compositions further comprise at least one of a cosmetically acceptable emollient, humectant, vitamin, moisturizer, conditioner, oil, silicone, suspending agent, surfactant, emulsifier, preservative, rheology modifier, pH adjustor, reducing agent, anti-oxidant, and/or foaming or de-foaming agent.

Abstract: The present invention relates to a composition comprising an aqueous dispersion of acrylate-siloxane copolymer particles comprising structural units of an acrylate monomer; an acid monomer; and a siloxane acrylate monomer of formula I: where R, R1, R2, Y and x are as defined herein. The composition has a high solids content, a low concentration of siloxane acrylate monomer and low coagulum levels. The composition is useful for forming coatings with improved hydrophobicity, stain resistance, and aesthetic/haptic properties compared with conventional all-acrylic compositions.

Abstract: The present invention relates to a method for preparing an aqueous dispersion of acrylate-siloxane copolymer particles as described herein. The polymer particles comprise structural units of an acrylate monomer; an acid monomer; and a siloxane acrylate monomer of formula I: where R, R1, R2, Y and x are as defined herein. The method provides an efficient way to prepare a high solids content aqueous dispersion of siloxane-acrylate hybrid copolymers with efficient incorporation of siloxane acrylate monomers, low residual monomer, and low generation of unwanted coagulum. The dispersion is useful for forming coatings with improved hydrophobicity, stain resistance, and aesthetic/haptic properties compared with conventional all-acrylic compositions.

Abstract: An acidic aqueous shampoo composition, which comprises: (I) a cleansing surfactant selected from the group consisting of anionic surfactant, zwitterionic or amphoteric surfactant and nonionic surfactant; (II) an emulsified silicone, (III) an anti-settling, thickening polymer, wherein the anti-settling, thickening polymer, comprises: (a) 40 to 74.5 wt % of structural units of C1-4 alkyl acrylate; (b) 20 to 50 wt % of structural units of methacrylic acid; (c) 0.

Abstract: An aqueous anti-dandruff shampoo composition which comprises: (I) a cleansing surfactant selected from the group consisting of anionic surfactant, zwitterionic or amphoteric surfactant and nonionic surfactant; (II) suspended particles of an anti-dandruff agent, (III) an anti-settling, thickening polymer, wherein the anti-settling, thickening polymer, comprises: (a) 40 to 74.5 wt % of structural units of C1-4 alkyl acrylate; (b) 20 to 50 wt % of structural units of methacrylic acid; (c) 0.

Abstract: A hydrophilic silica/polymer blend is provided comprising (a) a hydrophilic silica powder; and (b) a thickening polymer powder, comprising (i) structural units of C4-8 alkyl (meth)acrylate monomer; (ii) structural units of (meth)acrylic acid monomer; (iii) structural units of (methoxy) poly(ethylene glycol) (meth)acrylate monomer; and (iv) structural units of multiethylenically unsaturated monomer; wherein the weight ratio of hydrophilic silica powder to thickening polymer powder in the hydrophilic silica/polymer blend is 1:9 to 9:1. Also provided are personal care compositions containing same and methods of using same.

Abstract: A polymer oil blend is provided comprising (a) a cosmetically acceptable long chain hydrophobic ester oil, wherein the cosmetically acceptable long chain hydrophobic ester oil comprises aliphatic C>12-24 alkyl triglycerides; (b) a thickening polymer powder, wherein the thickening polymer powder comprises: (i) 96 to 99.9 wt %, based on weight of the thickening polymer powder, of structural units of C4-8 alkyl (meth)acrylate monomer; (ii) 0.1 to 2 wt %, based on weight of the thickening polymer powder, of structural units of (meth)acrylic acid monomer; (iii) 0 to 2 wt %, based on weight of the thickening polymer powder, of structural units of multi-ethylenically unsaturated crosslinking monomer; and (c) a silica powder; and wherein the weight ratio of silica powder/thickening polymer powder is ?0.25. Also provided are personal care compositions containing same and methods of using same.

Abstract: A polymer/hydrophilic silica blend is provided comprising (a) a thickening polymer powder, comprising (i) structural units of C4-8 alkyl (meth)acrylate monomer; (ii) structural units of (meth)acrylic acid monomer, and (iii) structural units of a specialized associative monomer of formula (I) wherein R1 is a linear saturated C10-20 alkyl group; and n is an average of 20 to 28; and (b) a hydrophilic silica powder; wherein the weight ratio of hydrophilic silica powder to thickening polymer powder in the polymer/hydrophilic silica blend is 1:9 to 9:1. Also provided are personal care compositions containing same and methods of using same.

Abstract: A hydrophobically modified rheology modifier comprising: (a) from 1 to 20 wt % polymerized units of H2C?C(R)C(O)O(CH2CH2O)n(CH(R?)CH2O)mR?; (b) from 35 to 75 wt % polymerized units of C1-C4 alkyl (meth)acrylates; and (c) from 20 to 60 wt % polymerized units of C3-C6 carboxylic acid monomers; wherein R is H or CH3, R? is methyl or ethyl; R? is C29-C60 alkyl; n is an average number from 20 to 100 and m is an average number from 0 to 50, provided that n?m.

Abstract: A multistage polymer is provided, comprising: acrylate rich stage comprising: (a) structural units of monoethylenically unsaturated non-ionic, acrylate rich stage monomer selected from C1-22 alkyl (meth)acrylates and mixtures thereof; and (b) carbosiloxane rich stage, comprising: structural units of carbosiloxane monomer of formula (I), wherein a is 0 to 3; wherein d is 0 or 1; wherein R1 is selected from hydrogen, C1-10 alkyl group and aryl group; wherein R2 is selected from hydrogen and C1-10 alkyl group; wherein R8 is —O—Si(CH3)2—O—Si(CH3)3 group; wherein Y is selected from formula (II), (III) and (IV); wherein R4 and R6 are selected from hydrogen and methyl group; wherein R3 and R5 are a C1-10 alkylene group; wherein R7 is C1-10 alkyl group; wherein b is 0 to 4 and wherein c is 0 or 1.

Abstract: A polymer blend is provided comprising: (A) multistage polymer, comprising: acrylate rich stage comprising: structural units of monoethylenically unsaturated non-ionic, acrylate rich stage monomer selected from C1-22 alkyl (meth)acrylates and mixtures thereof; and carbosiloxane rich stage, comprising: structural units of carbosiloxane monomer of formula (I); and (B) silicone-grafted vinyl copolymer, wherein the silicone-grafted vinyl copolymer, comprises: structural units of a vinyl (B) monomer; and structural units of a carbosiloxane dendrimer of formula (V). Also provided are personal care formulations comprising the polymer blend.

Abstract: An SPF booster is provided, comprising: a multistage polymeric particle having a core comprising polymerized units of a monoethylenically unsaturated carboxylic acid core monomer and a non-ionic ethylenically unsaturated core monomer; an inner shell comprising polymerized units of a non-ionic ethylenically unsaturated inner shell monomer; a monoethylenically unsaturated carboxylic acid inner shell monomer and an aliphatic inner shell monomer; an outer shell comprising polymerized units of a non-ionic ethylenically unsaturated outer shell monomer; an aliphatic outer shell monomer; a monoethylenically unsaturated non-carboxylic acid outer shell monomer and an ethylenically unsaturated surfactant outer shell monomer; wherein the core, when dry, contains a void; and wherein the multistage polymeric particle has an average particle size, when dry, of 50 to 1,000 nm.

Abstract: A personal care formulation is provided comprising: multistage polymer, comprising: acrylate rich stage comprising: (a) structural units of monoethylenically unsaturated non-ionic, acrylate rich stage monomer selected from C1-22 alkyl (meth)acrylates and mixtures thereof; and (b) carbosiloxane rich stage, comprising: structural units of carbosiloxane monomer of formula (I), wherein a is 0 to 3; wherein d is 0 or 1; wherein R1 is selected from hydrogen, C1-10 alkyl group and aryl group; wherein R2 is selected from hydrogen and C1-10 alkyl group; wherein R8 is —O—Si(CH3)2—O—Si(CH3)3 group; wherein Y is selected from formula (II), (III) and (IV); wherein R4 and R6 are selected from hydrogen and methyl group; wherein R3 and R5 are a C1-10 alkylene group; wherein R7 is C1-10 alkyl group; wherein b is 0 to 4 and wherein c is 0 or 1.

Abstract: A color cosmetic formulation is provided comprising: a color ingredient and a polymer blend, comprising: a single stage polymer and a silicone-grafted vinyl copolymer; wherein the single stage polymer comprises: structural units of a monoethylenically unsaturated non-ionic monomer; structural units of a monoethylenically unsaturated carboxylic acid monomer; and structural units of a multiethylenically unsaturated monomer having at least two ethylenically unsaturated groups per molecule; and wherein the silicone-grafted vinyl copolymer, comprises: structural units of a vinyl monomer; and structural units of a carbosiloxane dendrimer of formula (I).

Abstract: A polymer blend is provided comprising: a single stage polymer and a silicone-grafted vinyl copolymer; wherein the single stage polymer comprises: structural units of a monoethylenically unsaturated non-ionic monomer; structural units of a monoethylenically unsaturated carboxylic acid monomer; and structural units of a multiethylenically unsaturated monomer having at least two ethylenically unsaturated groups per molecule; and wherein the silicone-grafted vinyl copolymer, comprises: structural units of a vinyl monomer; and structural units of a carbosiloxane dendrimer of formula (I). Also provided is a suncare formulation comprising the polymer blend in a dermatologically acceptable carrier with a suncare active.

Abstract: A personal care composition is provided, comprising: a vehicle; a cosmetically acceptable oil; and a cationic polymer comprising structural units of acrylamide monomer; structural units of N,N-dimethyl acrylamide monomer; and structural units of monoethylenically unsaturated monocationic monomer; wherein the cationic polymer comprises <10 mol % structural units of multiethylenically unsaturated cationic monomer; wherein the cationic polymer comprises <30 wt % structural units of ester containing monomers; wherein the cationic polymer comprises <1 mol % structural units of ethylenically unsaturated monomers containing a moiety selected from the group consisting of epoxy, anhydride, imide, lactone, carboxylic acid, sulfonic acid and isocyanate; wherein the cationic polymer comprises <0.1 mol % structural units of a reactive siloxane; and wherein the personal care composition comprises <0.05 wt % water soluble, organic, ampholytic polymer conditioning agent.

Abstract: A multistage colored polymer particle is provided, having a core comprising polymerized units of a monoethylenically unsaturated carboxylic acid core monomer and a non-ionic ethylenically unsaturated core monomer; an inner shell comprising polymerized units of a non-ionic ethylenically unsaturated inner shell monomer; a monoethylenically unsaturated carboxylic acid inner shell monomer; optionally, an aliphatic inner shell monomer; and, optionally, a first polymerizable dye monomer; an outer shell comprising polymerized units of a non-ionic ethylenically unsaturated outer shell monomer; a monoethylenically unsaturated non-carboxylic acid outer shell monomer; optionally, a second polymerizable dye monomer; and, optionally, an aliphatic outer shell monomer; wherein the core, when dry, contains at least one void; and wherein the multistage colored polymer particle comprises polymerized units of polymerizable dye monomer.

Abstract: A suncare formulation comprising: a dermatologically acceptable organic carrier; a UV radiation absorbing agent; and an SPF booster; wherein the SPF booster comprises a multistage polymeric particle having a core comprising polymerized units of a monoethylenically unsaturated carboxylic acid core monomer and a non-ionic ethylenically unsaturated core monomer; an inner shell comprising polymerized units of a non-ionic ethylenically unsaturated inner shell monomer; a monoethylenically unsaturated carboxylic acid inner shell monomer and an aliphatic inner shell monomer; an outer shell comprising polymerized units of a non-ionic ethylenically unsaturated outer shell monomer; an aliphatic outer shell monomer; a monoethylenically unsaturated non-carboxylic acid outer shell monomer and an ethylenically unsaturated surfactant outer shell monomer; wherein the core, when dry, contains a void; wherein the multistage polymeric particle has an average particle size, when dry, of 50 to 1,000 nm.

Abstract: Provided are personal care compositions comprising a polyacrylate oil gel composition comprising (a) hydrophobic ester oil, and (b) one or more polymers comprising polymerized units derived from (i) 85 to 100 weight % of C4-C8 (meth)acrylate monomers, and (ii) 0 to 15 weight % of high Tg monoethylenically unsaturated monomers having a Tg of more than 90° C. after polymer formation.