Abstract: A variety of redox catalysts, methods of making, and methods of using thereof are provided. Surface modified redox catalysts are provided having an oxygen carrier core with an outer surface that has been modified to enhance the selectivity of the redox catalyst for oxidative dehydrogenation. The surface modification can include forming a redox catalyst outer layer on the outer surface and/or suppressing sites that form nonselective electrophilic oxygen sites on the outer surface of the oxygen carrier. A variety of methods are provided for making the surface modified redox catalysts, e.g. modified Pechini methods. A variety of methods are provided for using the catalysts for oxidative cracking of light paraffins. Methods are provided for oxidative cracking of light paraffins by contacting the paraffin with a core-shell redox catalyst described herein to convert the paraffins to water and olefins, diolefins, or a combination thereof.

Abstract: Redox catalysts having surface medication, methods of making redox catalysts with surface modification, and uses of the surface modified redox catalysts are provided. In some aspects, the redox catalysts include a core oxygen carrier region such as CaMnO3, BaMnO3-?, SrMnO3-?, Mn2SiO4, Mn2MgO4-?, La0.8Sr0.2O3-?, La0.8Sr0.2FeO3-?, Ca9Ti0.1Mn0.9O3-?, Pr6O11-?, manganese ore, or a combination thereof; and an outer shell having an average thickness of about 1-100 monolayers surrounding the outer surface of the core region. The outer shell can include, for example a salt selected such as Li2WO4, Na2WO4, K2WO4, SrWO4, Li2MoO4, Na2MoO4, K2MoO4, CsMoO4, Li2CO3, Na2CO3, K2CO3, or a combination thereof.

Abstract: Redox catalysts having surface medication, methods of making redox catalysts with surface modification, and uses of the surface modified redox catalysts are provided. In some aspects, the redox catalysts include a core oxygen carrier region such as CaMnO3, BaMnO3??, SrMnO3??, Mn2SiO4, Mn2MgO4??, La0.8Sr0.2O3??, La0.8Sr0.2FeO3??, Ca9Ti0.1Mn0.9O3??, Pr6O11??, manganese ore, or a combination thereof; and an outer shell having an average thickness of about 1-100 monolayers surrounding the outer surface of the core region. The outer shell can include, for example a salt selected such as Li2WO4, Na2WO4, K2WO4, SrWO4, Li2MoO4, Na2MoO4, K2MoO4, CsMoO4, Li2CO3, Na2CO3, K2CO3, or a combination thereof.

Abstract: In one aspect, the disclosure relates to an oxygen-deficient mixed metal perovskite having the formula SrxA1-xFeyB1-yO3-?, wherein A can be Ca, K, Y, Ba, La, Sm, or any combination thereof; wherein B can be Co, Cu, Mn, Mg, Ni, Ti, or any combination thereof; wherein x is from 0 to 1; wherein y is from 0 to 1; and wherein ? is from 0 to 0.7. Also disclosed are redox catalysts comprising the oxygen-deficient mixed metal perovskites and methods for chemical looping air separation, chemical looping CO2 splitting, and chemical looping alkane conversion using the disclosed catalysts.

Abstract: Redox catalysts having surface medication, methods of making redox catalysts with surface modification, and uses of the surface modified redox catalysts are provided. In some aspects, the redox catalysts include a core oxygen carrier region and an outer shell having an average thickness of about 1-100 monolayers surrounding the outer surface of the core region.

Abstract: Redox catalysts are provided for “low-temperature” methane partial oxidation in absence of gaseous oxidants. Methods of converting the methane to syngas using the catalysts are also provided. In some aspects, the conversion takes place at temperatures of about 400° C. to about 950° C. The methods can be used to convert methane to syngas containing carbon monoxide and hydrogen gas. In some aspects, the methods are carried out in a fixed bed reactor with reverse flow.

Abstract: In one aspect, the disclosure relates to a process for dehydrogenating a first dehydrogenation reactant into its unsaturated counterparts. The disclosed process comprises introducing a dehydrogenation reactant to a metal oxide catalyst having dehydrogenation activity, and dehydrogenating the dehydrogenation reactant to provide its unsaturated counterpart and hydrogen; selectively combusting the hydrogen released during dehydrogenation using a lattice oxygen from the metal oxide catalyst, resulting in a reduced metal oxide catalyst and steam; re-oxidizing the reduced metal oxide catalyst by introducing a gaseous oxidant to the reduced metal oxide catalyst; and optionally re-using the re-oxidized metal oxide catalyst for catalytic conversion and combustion. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

Abstract: Novel redox based systems for fuel and chemical production with in-situ CO2 capture are provided. A redox system using one or more chemical intermediates is utilized in conjunction with liquid fuel generation via indirect Fischer-Tropsch synthesis, direct hydrogenation, or pyrolysis. The redox system is used to generate a hydrogen rich stream and/or CO2 and/or heat for liquid fuel and chemical production. A portion of the byproduct fuels and/or steam from liquid fuel and chemical synthesis is used as part of the feedstock for the redox system.

Abstract: Redox catalysts having surface medication, methods of making redox catalysts with surface modification, and uses of the surface modified redox catalysts are provided. In some aspects, the redox catalysts include a core oxygen carrier region such as CaMnO3, BaMnO3-?, SrMnO3-?, Mn2SiO4, Mn2MgO4-?, La0.8Sr0.2O3-?, La0.8Sr0.2FeO3-?, Ca9Ti0.1Mn0.9O3-?, Pr6O11-?, manganese ore, or a combination thereof; and an outer shell having an average thickness of about 1-100 monolayers surrounding the outer surface of the core region. The outer shell can include, for example a salt selected such as Li2WO4, Na2WO4, K2WO4, SrWO4, Li2MoO4, Na2MoO4, K2MoO4, CsMoO4, Li2CO3, Na2CO3, K2CO3, or a combination thereof.

Abstract: Methods and systems are provided for oxidative dehydrogenation of a hydrocarbon feed stream to produce a product stream with improved ethylene yield. The methods can include the steps of (i) combining a recycle stream with the feed stream to form a reactor feed stream, (ii) contacting the reactor feed stream with an oxide-based redox catalyst to produce the product stream comprising ethylene and one or more byproducts selected from the group consisting of methane, ethane, other byproducts, and mixtures thereof, and (iii) removing all or a part of the methane and ethane from the product stream to produce the recycle stream. Systems for the oxidative dehydrogenation (ODH) of a hydrocarbon feed stream are also provided to produce a product stream with improved ethylene yield. The systems and methods can include an oxide-based redox catalyst, such as Mg6MnO8, Cu6PbO8, and Ni6MnO8.

Abstract: In one aspect, the disclosure relates to a process for dehydrogenating a first dehydrogenation reactant into its unsaturated counterparts. The disclosed process comprises introducing a dehydrogenation reactant to a metal oxide catalyst having dehydrogenation activity, and dehydrogenating the dehydrogenation reactant to provide its unsaturated counterpart and hydrogen; selectively combusting the hydrogen released during dehydrogenation using a lattice oxygen from the metal oxide catalyst, resulting in a reduced metal oxide catalyst and steam; re-oxidizing the reduced metal oxide catalyst by introducing a gaseous oxidant to the reduced metal oxide catalyst; and optionally re-using the re-oxidized metal oxide catalyst for catalytic conversion and combustion. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

Abstract: In accordance with one embodiment of the present disclosure, an oxygen carrying material may include a primary active mass, a primary support material, and a secondary support material. The oxygen carrying material may include about 20% to about 70% by weight of the primary active mass, the primary active mass including a composition having a metal or metal oxide selected from the group consisting of Fe, Co, Ni, Cu, Mo, Mn, Sn, Ru, Rh, and combinations thereof. The oxygen carrying material may include about 5% to about 70% by weight of a primary support material. The oxygen carrying material may include about 1% to about 35% by mass of a secondary support material.

Abstract: Compositions and methods for preparing and using ceramic mixed ionic-electronic conductor (MIEC) enhanced transition metals and metal oxides in composite or core-shell forms are disclosed. The presently disclosed compositions are stable at high temperatures and can carry as much as about 20 weight % oxygen.

Abstract: A variety of redox catalysts, methods of making, and methods of using thereof are provided. Surface modified redox catalysts are provided having an oxygen carrier core with an outer surface that has been modified to enhance the selectivity of the redox catalyst for oxidative dehydrogenation. The surface modification can include forming a redox catalyst outer layer on the outer surface and/or suppressing sites that form nonselective electrophilic oxygen sites on the outer surface of the oxygen carrier. A variety of methods are provided for making the surface modified redox catalysts, e.g. modified Pechini methods. A variety of methods are provided for using the catalysts for oxidative cracking of light paraffins. Methods are provided for oxidative cracking of light paraffins by contacting the paraffin with a core-shell redox catalyst described herein to convert the paraffins to water and olefins, diolefins, or a combination thereof.

Abstract: Novel redox based systems for fuel and chemical production with in-situ CO2 capture are provided. A redox system using one or more chemical intermediates is utilized in conjunction with liquid fuel generation via indirect Fischer-Tropsch synthesis, direct hydrogenation, or pyrolysis. The redox system is used to generate a hydrogen rich stream and/or CO2 and/or heat for liquid fuel and chemical production. A portion of the byproduct fuels and/or steam from liquid fuel and chemical synthesis is used as part of the feedstock for the redox system.

Abstract: Novel redox based systems for fuel and chemical production with in-situ CO2 capture are provided. A redox system using one or more chemical intermediates is utilized in conjunction with liquid fuel generation via indirect Fischer-Tropsch synthesis, direct hydro genation, or pyrolysis. The redox system is used to generate a hydrogen rich stream and/or CO2 and/or heat for liquid fuel and chemical production. A portion of the byproduct fuels and/or steam from liquid fuel and chemical synthesis is used as part of the feedstock for the redox system.

Abstract: A oxygen transfer agent useful for the oxidative dehydrogenation of saturated hydrocarbons includes at least one mixed oxide derived from manganese or compounds thereof, as well as a promoter, such as tungsten and/or phosphorus. The oxygen transfer agent may also include an alkali metal or compounds thereof, boron or compounds thereof, an oxide of an alkaline earth metal, and an oxide containing one or more of one or more of manganese, lithium, boron, and magnesium. A reactor is at least partially filled with the oxygen transfer agent in the form of a fixed or circulating bed and provides an unsaturated hydrocarbon product, such as ethylene and/or propylene. The oxygen transfer agent may be regenerated using oxygen.

Abstract: A system for converting fuel is provided and includes a first reactor comprising a plurality of ceramic composite particles, the ceramic composite particles comprising at least one metal oxide disposed on a support, wherein the first reactor is configured to reduce the at least one metal oxide with a fuel to produce a reduced metal or a reduced metal oxide; a second and reactor configured to oxidize at least a portion of the reduced metal or reduced metal oxide from the said first reactor to produce a metal oxide intermediate; a source of air; and a third reactor communicating with said source of air and configured to regenerate the at least one metal oxide from the remaining portion of the solids discharged from the said first reactor and the solids discharged from the said second reactor for by oxidizing the metal oxide intermediate.

Abstract: Systems, devices, and methods for the delivery of gas bubbles to liquids are generally described. The devices can include a primary conduit comprising a plurality of openings fluidically connecting an internal flow pathway of the primary conduit to an environment outside the primary conduit. The devices may also include, in some instances, a secondary conduit located at least partially within the primary conduit, the secondary conduit configured to redistribute the pressure of the gas delivered to the openings of the primary conduit, and comprising a plurality of openings fluidically connecting an internal flow pathway of the secondary conduit to a portion of the internal flow pathway of the primary conduit outside the secondary conduit. Certain of the gas delivery systems and methods described herein are capable of delivering gas at relatively uniform linear flow velocities across multiple gas outlet openings. Certain embodiments are related to inventive configurations (e.g.

Abstract: A system and process for carrying out one or more chemical reactions are provided and include one or more chemical reactors having particulate solids forming a bed therein, and a gas stripping zone forming a non-mechanical seal between said reactors which includes a conduit connecting the reactors. The conduit includes an inlet for a stripping gas which is adapted to prevent process gas from passing between reactors while permitting particulate solids to pass between reactors.