Abstract: The present disclosure provides a fixed-position defect doping method for a micro-nanostructure based on a self-alignment process, including: S1, sequentially forming a sacrificial layer and a photoresist layer on a surface of a crystal substrate; S2, performing a lithography on the photoresist layer to form a mask hole according to a micro-nano pattern; S3, performing an isotropic etching on the sacrificial layer through the mask hole, and amplifying the micro-nano pattern to the sacrificial layer; S4, performing an ion implantation doping on an exposed crystal surface below the mask hole; S5, removing the photoresist layer, and depositing a mask material; S6, removing the sacrificial layer, and transferring a micro-nano amplified pattern in the sacrificial layer to a mask material pattern; and S7, etching an exposed crystal surface, and removing the mask material on the surface and forming a specific defect by annealing.

Abstract: A method for implementing an atomic clock based on NV-14N coupling spin system in diamond and a device are provided. The method is to lock a RF frequency using a 14N zero-field splitting and output the RF frequency as a frequency standard. The method includes: applying a pulse sequence to jointly initialize NV electron spins and 14N nuclear spins; performing a Ramsey interferometry to compare a RF frequency and a 14N zero-field splitting; entangling the NV electron spin and the nuclear spin, reading out a state of nuclear spins by collecting a fluorescence signal; calculating a frequency difference between the RF frequency and the 14N zero-field splitting according to the fluorescence signal, thereby locking the RF frequency to the 14N zero-field splitting; and outputting the RF frequency as a frequency standard.

Abstract: A method for implementing an atomic clock based on NV-15N coupling spin system in diamond and a device are provided. The method includes: applying a pulse sequence to jointly initialize NV electron spins and 15N nuclear spins; performing a Ramsey interferometry to compare a RF frequency and a 15N hyperfine coupling; entangling the NV electron spin and the nuclear spin, reading out a state of nuclear spins by collecting a fluorescence signal; calculating a frequency difference between the RF frequency and the 15N hyperfine coupling according to the fluorescence signal, thereby locking the RF frequency to the 15N hyperfine coupling; and outputting the RF frequency as a frequency standard. This system is located in a stable solid environment and is not affected by environmental conditions such as an external magnetic field, electric field, and temperature, and therefore it has an excellent robustness. Various components of the device may be integrated into several chips to miniaturize a diamond atomic clock.