Abstract: Described are starch-based materials, and formulations including such, which can be spun in spunbond, melt blown, yarn, or similar processes. Even with high viscosity resulting from inclusion of the starch-based materials, the formulations can be processed at commercial line speeds, with spinneret shear viscosities of 1000 sec?1, or even up to 4000 sec?1, without onset of melt flow instability. Viscosity and other processing characteristics can be improved by addition of an acid or acid anhydride, and/or by use of sorbitol as the plasticizer, when forming the starch-based material. The starch-based material can be blended with one or more thermoplastic materials, e.g., having higher melt flow index value(s), allowing the blend to be spun. The particular melt flow index characteristics of the thermoplastic diluent material can be selected based on what type of process is being used (e.g., spunbond, melt blown, yarn, etc.).

Abstract: An absorbent article having a liquid-handling system includes a liquid permeable bodyside liner; a liquid impermeable outer cover; and an absorbent core disposed between the liner and the outer cover, wherein the absorbent core has a longitudinal direction, wherein the absorbent core includes a layer of a three-dimensionally patterned, wetlaid, cellulosic tissue nonwoven material, and wherein the layer includes longitudinal ridges and grooves. The absorbent core can include multiple layers of a three-dimensionally patterned, wetlaid, cellulosic tissue nonwoven material, wherein each layer of the multiple layers includes longitudinal ridges and grooves, and wherein the multiple layers are joined by lines of embossing, such lines of embossing extending in the longitudinal direction. Each layer of the multiple layers can include embossed longitudinal ridges and grooves.

Abstract: Thermoplastic starch-based materials formed as a reactive extrusion product from one or more starches, plasticizers, with the addition of a diacid, diglycidyl ether, silicone and/or a glyceride additive added during gelatinization of the starch and plasticizer, before blending of such starch-based polymeric material with any other polymer (e.g., polyester biopolymers, polyolefins, polyamides, etc.). Silicones, where added, may alternatively be added after formation of the thermoplastic starch, e.g., as part of a masterbatch, when blending with another polymer. Addition of silicone reduces glycerin migration and smoke generation, particularly when processing such compositions to form nonwovens. Addition of glycerides (e.g., triglycerides) can increase hydrophobicity of the resulting starch-based polymeric material.

Abstract: Thermoplastic starch-based materials formed as a reactive extrusion product from one or more starches, one or more plasticizers, and micro or nano particles or fibers, with such particles or fibers being added before gelatinization of the starch. A diacid or acid anhydride may also be included. Such components are added and then gelatinized together, before blending of a resulting starch-based polymeric material with any other polymer (e.g., polyester biopolymers, polyolefins, or the like). Addition of such nano or micro particles during synthesis of the thermoplastic starch advantageously results in a far more homogenous distribution of such particles or fibers throughout the starch-based material matrix than occurs where addition of similar particles or fibers is attempted after formation of the thermoplastic starch, e.g., when mixing with a partner resin material. Addition of a diacid during synthesis can reduce molecular weight and viscosity, further aiding in achieving substantially uniform distribution.

Abstract: Described are very high molecular weight (e.g., over 2 million, such as 3-20 million g/mol) starch-based materials, and formulations including such, which can be spun in spunbond, melt blown, yarn, or similar processes. Even with such very high molecular weights, the formulations can be processed at commercial line speeds, with spinneret shear viscosities of 1000 sec?1, without onset of melt flow instability. The starch-based material can be blended with one or more thermoplastic materials having higher melt flow index value(s), which serve as a diluent and plasticizer, allowing the very viscous starch-based component to be spun under such conditions. The particular melt flow index characteristics of the thermoplastic diluent material can be selected based on what type of process is being used (e.g., spunbond, melt blown, yarn, etc.). The starch-based material may exhibit high shear sensitivity, strain hardening behavior, and/or very high critical shear stress (e.g., at least 125 kPa).

Abstract: Described are very high molecular weight (e.g., over 2 million, such as 3-20 million g/mol) starch-based materials, and formulations including such, which can be spun in spunbond, melt blown, yarn, or similar processes. Even with such very high molecular weights, the formulations can be processed at commercial line speeds, with spinneret shear viscosities of 1000 sec?1, without onset of melt flow instability. The starch-based material can be blended with one or more thermoplastic materials having higher melt flow index value(s), which serve as a diluent and plasticizer, allowing the very viscous starch-based component to be spun under such conditions. The particular melt flow index characteristics of the thermoplastic diluent material can be selected based on what type of process is being used (e.g., spunbond, melt blown, yarn, etc.). The starch-based material may exhibit high shear sensitivity, strain hardening behavior, and/or very high critical shear stress (e.g., at least 125 kPa).

Abstract: Described are very high molecular weight (e.g., over 2 million, such as 3-20 million g/mol) starch-based materials, and formulations including such, which can be spun in spunbond, melt blown, yarn, or similar processes. Even with such very high molecular weights, the formulations can be processed at commercial line speeds, with spinneret shear viscosities of 1000 sec?1, without onset of melt flow instability. The starch-based material can be blended with one or more thermoplastic materials having higher melt flow index value(s), which serve as a diluent and plasticizer, allowing the very viscous starch-based component to be spun under such conditions. The particular melt flow index characteristics of the thermoplastic diluent material can be selected based on what type of process is being used (e.g., spunbond, melt blown, yarn, etc.). The starch-based material may exhibit high shear sensitivity, strain hardening behavior, and/or very high critical shear stress (e.g., at least 125 kPa).

Abstract: Described herein are starch-based materials, and formulations including such for use in directional alignment extrusion processes. The present compositions exhibit critical shear stress characteristics that allow extrusion at high shear rates and line speeds, without onset of melt flow instability. The present compositions provide sufficient melt strength to allow such compositions to be directionally oriented by stretching the heated polymer (e.g., the polymer melt) following initial extrusion, directionally aligning the molecular chains of the heated polymer blend in the machine-direction, the cross-direction, or both. In an embodiment, the starch-based material is blended with one or more thermoplastic materials having desired melt flow index value(s), which serves as a diluent, allowing the very viscous starch-based component to be processed under such conditions.

Abstract: Described are very high molecular weight (e.g., over 2 million, such as 3-20 million g/mol) starch-based materials, and formulations including such, which can be spun in spunbond, melt blown, yarn, or similar processes. Even with such very high molecular weights, the formulations can be processed at commercial line speeds, with spinneret shear viscosities of 1000 sec?1, without onset of melt flow instability. The starch-based material can be blended with one or more thermoplastic materials having higher melt flow index value(s), which serve as a diluent and plasticizer, allowing the very viscous starch-based component to be spun under such conditions. The particular melt flow index characteristics of the thermoplastic diluent material can be selected based on what type of process is being used (e.g., spunbond, melt blown, yarn, etc.). The starch-based material may exhibit high shear sensitivity, strain hardening behavior, and/or very high critical shear stress (e.g., at least 125 kPa).

Abstract: Described are very high molecular weight (e.g., over 2 million, such as 3-20 million g/mol) starch-based materials, and formulations including such, which can be spun in spunbond, melt blown, yarn, or similar processes. Even with such very high molecular weights, the formulations can be processed at commercial line speeds, with spinneret shear viscosities of 1000 sec?1, without onset of melt flow instability. The starch-based material can be blended with one or more thermoplastic materials having higher melt flow index value(s), which serve as a diluent and plasticizer, allowing the very viscous starch-based component to be spun under such conditions. The particular melt flow index characteristics of the thermoplastic diluent material can be selected based on what type of process is being used (e.g., spunbond, melt blown, yarn, etc.). The starch-based material may exhibit high shear sensitivity, strain hardening behavior, and/or very high critical shear stress (e.g., at least 125 kPa).

Abstract: Described are very high molecular weight (e.g., over 2 million, such as 3-20 million g/mol) starch-based materials, and formulations including such, which can be spun in spunbond, melt blown, yarn, or similar processes. Even with such very high molecular weights, the formulations can be processed at commercial line speeds, with spinneret shear viscosities of 1000 sec?1, without onset of melt flow instability. The starch-based material can be blended with one or more thermoplastic materials having higher melt flow index value(s), which serve as a diluent and plasticizer, allowing the very viscous starch-based component to be spun under such conditions. The particular melt flow index characteristics of the thermoplastic diluent material can be selected based on what type of process is being used (e.g., spunbond, melt blown, yarn, etc.). The starch-based material may exhibit high shear sensitivity, strain hardening behavior, and/or very high critical shear stress (e.g., at least 125 kPa).

Abstract: An absorbent article having a liquid-handling system includes a liquid permeable bodyside liner; a liquid impermeable outer cover; and an absorbent core disposed between the liner and the outer cover, wherein the absorbent core has a longitudinal direction, wherein the absorbent core includes a layer of a three-dimensionally patterned, wetlaid, cellulosic tissue nonwoven material, and wherein the layer includes longitudinal ridges and grooves. The absorbent core can include multiple layers of a three-dimensionally patterned, wetlaid, cellulosic tissue nonwoven material, wherein each layer of the multiple layers includes longitudinal ridges and grooves, and wherein the multiple layers are joined by lines of embossing, such lines of embossing extending in the longitudinal direction. Each layer of the multiple layers can include embossed longitudinal ridges and grooves.

Abstract: A method for making a permanently wettable material is disclosed. The method includes selecting a plurality of non-polar polymer fibers (12) wherein each fiber has a surface (16), depositing a hydrophilic polymer mixture (14) on the non-polar polymer fiber surface to form a shell. The hydrophilic polymer mixture (14) includes a cross-linkable and graftable epoxy-containing polymer, such as, poly(glycidyl methacrylate-co-ethylene glycol methacrylate) copolymer (PGMA-co-POEGMA), a high weight average molecular weight polyethylene glycol (PEG), and a surfactant. A permanently wettable material is also disclosed that includes a non-polar polymer-based web (10) having fibers (12) with a surface (16). A hydrophilic polymer mixture (14) forms a shell on the non-polar polymer fiber surface (16). The hydrophilic polymer mixture (14) includes a poly(glycidyl methacrylate-co-ethylene glycol methacrylate) copolymer (PGMA-co-POEGMA), a high weight average molecular weight polyethylene glycol (PEG), and a surfactant.