Abstract: The present disclosure relates to a process to produce aqueous dispersions of graphene stabilized by cellulose, offering an alternative to the current methods of dispersion of graphene. The present process provides the advantages that it uses biodegradable cellulose compatible with the environment and can be used in industrial processes in alkaline medium or in the absence of alkali; and when graphene is stabilized with cellulose in alkaline medium it becomes unstable when in contact with natural waters, thus precipitating and being easily removed or concentrated. In other embodiments, solids obtained by drying of the dispersions, once dried, can be redispersed in aqueous alkaline solution.

Abstract: The present disclosure relates to a process to produce aqueous dispersions of graphene stabilized by cellulose, offering an alternative to the current methods of dispersion of graphene. The present process provides the advantages that it uses biodegradable cellulose compatible with the environment and can be used in industrial processes in alkaline medium or in the absence of alkali; and when graphene is stabilized with cellulose in alkaline medium it becomes unstable when in contact with natural waters, thus precipitating and being easily removed or concentrated. In other embodiments, solids obtained by drying of the dispersions, once dried, can be redispersed in aqueous alkaline solution.

Abstract: The present patent application relates to a method for producing dispersions and nanodispersions of graphite, graphene and amorphous carbon in aqueous media without using any surfactant and without requiring any chemical modification of the graphene, such as oxidation to produce graphene oxide.

Abstract: An aluminum phosphate composition comprising aluminum phosphate, aluminum polyphosphate, aluminum metaphosphate, or a mixture thereof. The composition may be characterized by, when in powder form, having particles wherein some of the particles have at least one or more voids per particle. In addition, the composition is characterized by exhibiting two endothermic peaks in Differential Scanning calorimetry between about 90 degrees to about 250 degrees Celsius. The composition is also characterized by, when in powder form, having a dispersibility of at least 0.025 grams per 1.0 gram of water. The composition is made by a process comprising contacting phosphoric acid with aluminum sulfate and an alkaline solution to produce an aluminum phosphate based product; and optionally calcining the aluminum phosphate, polyphosphate or metaphosphate based product at an elevated temperature. The composition is useful in paints and as a substitute for titanium dioxide.

Abstract: An aluminum phosphate or polyphosphate-based pigment product is made by a process comprising contacting phosphoric acid with aluminum sulfate and an alkaline solution to produce an aluminum phosphate based product; and optionally calcining the aluminum phosphate based product at an elevated temperature, wherein the process is substantially free of an organic acid. The aluminum phosphate or polyphosphate-based pigment is amorphous. The amorphous aluminum phosphate or polyphosphate characterized by a bulk density of less than 2.30 grams per cubic centimeter and a phosphorus to aluminum mole ratio of greater than 0.8.

Abstract: Slurry composition comprising amorphous aluminum phosphate, polyphosphate orthophosphate, metaphosphate and/or combination thereof and a dispersant are described. In certain embodiments, the polyphosphate orthophosphate and/or metaphosphate concentration is about 40 to about 70 weight % and the dispersant concentration is less than about 3.5 weight % based on the total weight of the slurry. In one embodiment, the composition is useful is paints, varnishes, printing inks, papers and plastics. The compositions can be used as a substitute for titanium dioxide in various applications.

Abstract: An aluminum phosphate composition comprising aluminum phosphate, aluminum polyphosphate, aluminum metaphosphate, or a mixture thereof. The composition may be characterized by, when in powder form, having particles wherein some of the particles have at least one or more voids per particle. In addition, the composition is characterized by exhibiting two endothermic peaks in Differential Scanning Calorimetry between about 90 degrees to about 250 degrees Celsius. The composition is also characterized by, when in powder form, having a dispersibility of at least 0.025 grams per 1.0 gram of water. The composition is made by a process comprising contacting phosphoric acid with aluminum sulfate and an alkaline solution to produce an aluminum phosphate based product; and optionally calcining the aluminum phosphate, polyphosphate or metaphosphate based product at an elevated temperature. The composition is useful in paints and as a substitute for titanium dioxide.

Abstract: An aluminum phosphate or polyphosphate-based pigment product is made by a process comprising contacting phosphoric acid with aluminum sulfate and an alkaline solution to produce an aluminum phosphate based product; and optionally calcining the aluminum phosphate based product at an elevated temperature, wherein the process is substantially free of an organic acid. The aluminum phosphate or polyphosphate-based pigment is amorphous. The amorphous aluminum phosphate or polyphosphate characterized by a bulk density of less than 2.30 grams per cubic centimeter and a phosphorus to aluminum mole ratio of greater than 0.8. The composition is useful in paints and as a substitute for titanium dioxide.

Abstract: Slurry composition comprising amorphous aluminum phosphate, polyphosphate orthophosphate, metaphosphate and/or combination thereof and a dispersant are described. In certain embodiments, the polyphosphate orthophosphate and/or metaphosphate concentration is about 40 to about 70 weight % and the dispersant concentration is less than about 3.5 weight % based on the total weight of the slurry. In one embodiment, the composition is useful in paints, varnishes, printing inks, papers and plastics. The compositions can be used as a substitute for titanium dioxide in various applications.

Abstract: A process for the preparation of amorphous aluminum phosphate or polyphosphate-based pigment by reacting aluminum phosphate and sodium aluminate is provided. The amorphous aluminum phosphate or polyphosphate is characterized by a skeletal density of less than 2.50 grams per cubic centimeter and a phosphorus to aluminum mole ratio of greater than 0.8. In one embodiment, the composition is useful in paints as a substitute for titanium dioxide.

Abstract: Anticorrosive coating compositions comprise a binding polymer and an amorphous aluminum phosphate corrosion inhibiting pigment. The composition comprises from about 1 to 25 percent by weight amorphous aluminum phosphate. The amorphous aluminum phosphate has a water adsorption potential of up to about 25 percent by weight water. The composition provides a controlled phosphate delivery of from about 50 to 500 ppm, and preferably of from about 100 to 200 ppm. The composition has a total solubles content of less than about 1,500 ppm. The amorphous aluminum phosphate is preferably substantially free of alkali metals. The amorphous aluminum phosphate is made by combining aluminum hydroxide with phosphoric acid and sodium aluminate. The amorphous aluminum phosphate is treated to reduce the level of unwanted solubles, and the treated amorphous aluminum phosphate is dried at less than about 300° C. The composition is used as a primer coat, a mid-coat, and/or a top-coat coating.

Abstract: A process for the preparation of amorphous aluminum phosphate or polyphosphate-based pigment by reacting aluminum phosphate and sodium aluminate is provided. The amorphous aluminum phosphate or polyphosphate is characterized by a skeletal density of less than 2.50 grams per cubic centimeter and a phosphorus to aluminum mole ratio of greater than 0.8. In one embodiment, the composition is useful in paints as a substitute for titanium dioxide.

Abstract: A process for the preparation of amorphous aluminum phosphate or polyphosphate-based pigment by reacting aluminum phosphate and sodium aluminate is provided. The amorphous aluminum phosphate or polyphosphate is characterized by a skeletal density of less than 2.50 grams per cubic centimeter and a phosphorus to aluminum mole ratio of greater than 0.8. In one embodiment, the composition is useful in paints as a substitute for titanium dioxide.

Abstract: An aluminum phosphate composition comprising aluminum phosphate, aluminum polyphosphate, aluminum metaphosphate, or a mixture thereof. The composition may be characterized by, when in powder form, having particles wherein some of the particles have at least one or more voids per particle. In addition, the composition is characterized by exhibiting two endothermic peaks in Differential Scanning Calorimetry between about 90 degrees to about 250 degrees Celsius. The composition is also characterized by, when in powder form, having a dispersibility of at least 0.025 grams per 1.0 gram of water. The composition is made by a process comprising contacting phosphoric acid with aluminum sulfate and an alkaline solution to produce an aluminum phosphate based product; and optionally calcining the aluminum phosphate, polyphosphate or metaphosphate based product at an elevated temperature. The composition is useful in paints and as a substitute for titanium dioxide.

Abstract: Provided herein are coating compositions for paper comprising aluminum phosphate, aluminum metaphosphate, aluminum orthophosphate and/or aluminum polyphosphate pigments. Methods of making and using the compositions are described.

Abstract: An aluminum phosphate composition comprising aluminum phosphate, aluminum polyphosphate, aluminum metaphosphate, or a mixture thereof. The composition may be characterized by, when in powder form, having particles wherein some of the particles have at least one or more voids per particle. In addition, the composition is characterized by exhibiting two endothermic peaks in Differential Scanning Calorimetry between about 90 degrees to about 250 degrees Celsius. The composition is also characterized by, when in powder form, having a dispersibility of at least 0.025 grams per 1.0 gram of water. The composition is made by a process comprising contacting phosphoric acid with aluminum sulfate and an alkaline solution to produce an aluminum phosphate based product; and optionally calcining the aluminum phosphate, polyphosphate or metaphosphate based product at an elevated temperature. The composition is useful in paints and as a substitute for titanium dioxide.

Abstract: An aluminum phosphate or polyphosphate-based pigment product is made by a process comprising contacting phosphoric acid with aluminum sulfate and an alkaline solution to produce an aluminum phosphate based product; and optionally calcining the aluminum phosphate based product at an elevated temperature, wherein the process is substantially free of an organic acid. The aluminum phosphate or polyphosphate-based pigment is amorphous. The amorphous aluminum phosphate or polyphosphate characterized by a bulk density of less than 2.30 grams per cubic centimeter and a phosphorus to aluminum mole ratio of greater than 0.8.

Abstract: Slurry composition comprising amorphous aluminum phosphate, polyphosphate orthophosphate, metaphosphate and/or combination thereof and a dispersant are described. In certain embodiments, the polyphosphate orthophosphate and/or metaphosphate concentration is about 40 to about 70 weight % and the dispersant concentration is less than about 3.5 weight % based on the total weight of the slurry. In one embodiment, the composition is useful in paints, varnishes, printing inks, papers and plastics. The compositions can be used as a substitute for titanium dioxide in various applications.

Abstract: A process for the preparation of amorphous aluminum phosphate or polyphosphate-based pigment by reacting aluminum phosphate and sodium aluminate is provided. The amorphous aluminum phosphate or polyphosphate is characterized by a skeletal density of less than 2.50 grams per cubic centimeter and a phosphorus to aluminum mole ratio of greater than 0.8. In one embodiment, the composition is useful in paints as a substitute for titanium dioxide.

Abstract: An aluminum phosphate composition comprising aluminum phosphate, aluminum polyphosphate, aluminum metaphosphate, or a mixture thereof. The composisition may be characterized by, when in powder form, having particles wherein some of the particles have at least one or more voids per particle. In addition, the composition is characterized by exhibiting two endothermic peaks in Differential Scanning Calorimetry between about 90 degrees to about 250 degrees Celsius. The composition is also characterized by, when in powder form, having a dispersibility of at least 0.025 grams per 1.0 gram of water. The composition is made by a process comprising contacting phosphoric acid with aluminum sulfate and an alkaline solution to produce an aluminum phosphate based product; and optionally calcining the aluminum phosphate, polyphosphate or metaphosphate based product at an elevated temperature. The composition is useful in paints and as a substitute for titanium dioxide.