Patents by Inventor Fernando Rey García

Fernando Rey García has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10427140
    Abstract: The present invention refers to a microporous crystalline material, to the method for the production thereof and to the use of same, the material having a composition: xX2O3:zZO2:yYO2 in which: X is a trivalent element such as Al, B, Fe, In, Ga, Cr, or mixtures thereof, where (y+z)/x can have values of between 9 and infinity; Z corresponds to a tetravalent element selected from Si, Ge or mixtures thereof; and Y corresponds to a tetravalent element such as Ti, Sn, Zr, V or mixtures thereof, where z/y can have values of between 10 and infinity.
    Type: Grant
    Filed: August 16, 2017
    Date of Patent: October 1, 2019
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Avelino Corma Canos, Fernando Rey Garcia, Manuel Hernandez Rodriguez, Jose Luis Jorda Moret
  • Patent number: 9856145
    Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1-g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, a method for its preparation and its use.
    Type: Grant
    Filed: June 19, 2015
    Date of Patent: January 2, 2018
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia, Angel Cantin Sanz, Jose Luis Jordá Moret
  • Publication number: 20170368537
    Abstract: The present invention refers to a microporous crystalline material, to the method for the production thereof and to the use of same, the material having a composition: xX2O3:zZO2:yYO2 in which: X is a trivalent element such as Al, B, Fe, In, Ga, Cr, or mixtures thereof, where (y+z)/x can have values of between 9 and infinity; Z corresponds to a tetravalent element selected from Si, Ge or mixtures thereof; and Y corresponds to a tetravalent element such as Ti, Sn, Zr, V or mixtures thereof, where z/y can have values of between 10 and infinity.
    Type: Application
    Filed: August 16, 2017
    Publication date: December 28, 2017
    Inventors: Avelino COMA CANOS, Fernando REY GARCIA, Manuel HERNANDEZ RODRIGUEZ, Jose Luis JORDA MORET
  • Patent number: 9764311
    Abstract: The present invention refers to a microporous crystalline material, to the method for the production thereof and to the use of same, the material having a composition: xX2O3:zZO2:yYO2 in which: X is a trivalent element such as Al, B, Fe, In, Ga, Cr, or mixtures thereof, where (y+z)/x can have values of between 9 and infinity; Z corresponds to a tetravalent element selected from Si, Ge or mixtures thereof; and Y corresponds to a tetravalent element such as Ti, Sn, Zr, V or mixtures thereof, where z/y can have values of between 10 and infinity.
    Type: Grant
    Filed: October 17, 2014
    Date of Patent: September 19, 2017
    Assignees: Universitat Politecnica De Valencia, Consejo Superior de Investigaciones Cientificas (CSIC)
    Inventors: Avelino Corma Canós, Fernando Rey García, Manuel Hernández Rodríguez, José Luis Jordá Moret
  • Patent number: 9738539
    Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1?g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
    Type: Grant
    Filed: June 19, 2015
    Date of Patent: August 22, 2017
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Edward W. Corcoran, Jr., Pavel Kortunov, Charanjit S. Paur, Peter I. Ravikovitch, Yu Wang, Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia, Angel Cantín Sanz, Miguel Palomino Roca
  • Patent number: 9695056
    Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1?g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
    Type: Grant
    Filed: June 19, 2015
    Date of Patent: July 4, 2017
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Edward W. Corcoran, Jr., Pavel Kortunov, Charanjit S. Paur, Peter I. Ravikovitch, Yu Wang, Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia, Angel Cantin Sanz, Miguel Palomino Roca
  • Patent number: 9688542
    Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1?g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
    Type: Grant
    Filed: June 19, 2015
    Date of Patent: June 27, 2017
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Edward W. Corcoran, Jr., Pavel Kortunov, Charanjit S. Paur, Peter I. Ravikovitch, Yu Wang, Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia, Angel Cantin Sanz, Miguel Palomino Roca
  • Patent number: 9617164
    Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1?g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
    Type: Grant
    Filed: June 19, 2015
    Date of Patent: April 11, 2017
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Edward W. Corcoran, Jr., Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia, Angel Cantin Sanz, Miguel Palomino Roca
  • Publication number: 20160009618
    Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1?g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
    Type: Application
    Filed: June 19, 2015
    Publication date: January 14, 2016
    Applicant: ExxonMobil Research and Engineering Company
    Inventors: Edward W. Corcoran, JR., Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia, Angel Cantín Sanz, Miguel Palomino Roca
  • Publication number: 20160009563
    Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1-g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, a method for its preparation and its use.
    Type: Application
    Filed: June 19, 2015
    Publication date: January 14, 2016
    Applicants: Higher Council of Scientific Research (CSIC), Polytechnic University of Valencia
    Inventors: Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia, Angel Cantín Sanz, Jose Luis Jordá Moret
  • Publication number: 20160008753
    Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1?g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
    Type: Application
    Filed: June 19, 2015
    Publication date: January 14, 2016
    Applicant: ExxonMobil Research and Engineering Company
    Inventors: Edward W. Corcoran, JR., Pavel Kortunov, Charanjit S. Paur, Peter I. Ravikovitch, Jade Yu Wang, Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia, Angel Cantín Sanz, Miguel Palomino Roca
  • Publication number: 20160008756
    Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1?g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
    Type: Application
    Filed: June 19, 2015
    Publication date: January 14, 2016
    Applicant: ExxonMobil Research and Engineering Company
    Inventors: Edward W. Corcoran, JR., Pavel Kortunov, Charanjit S. Paur, Peter I. Ravikovitch, Yu Wang, Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia, Angel Cantín Sanz, Miguel Palomino Roca
  • Publication number: 20160008754
    Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1?g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
    Type: Application
    Filed: June 19, 2015
    Publication date: January 14, 2016
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Edward W. Corcoran, JR., Pavel Kortunov, Charanjit S. Paur, Peter I. Ravikovitch, Yu Wang, Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia, Angel Cantín Sanz, Miguel Palomino Roca
  • Publication number: 20150038756
    Abstract: The present invention refers to a microporous crystalline material, to the method for the production thereof and to the use of same, the material having a composition: x X2O3:z ZO2:y YO2 in which: X is a trivalent element such as Al, B, Fe, In, Ga, Cr, or mixtures thereof, where (y+z)/x can have values of between 9 and infinity; Z corresponds to a tetravalent element selected from Si, Ge or mixtures thereof; and Y corresponds to a tetravalent element such as Ti, Sn, Zr, V or mixtures thereof, where z/y can have values of between 10 and infinity.
    Type: Application
    Filed: October 17, 2014
    Publication date: February 5, 2015
    Inventors: Avelino CORMA CANÓS, Fernando REY GARCÍA, Manuel HERNÁNDEZ RODRIGUEZ, José Luis JORDÁ MORET
  • Publication number: 20130046123
    Abstract: The present invention relates to a micro-porous crystalline material that is isostructural with the mineral known as boggsite and to a method for preparing same, said material having composition x X2O3: z ZO2: y YO2, wherein: X is a trivalent element such as Al, B, Fe, In, Ga, Cr or mixtures thereof; where (y+z)/x may have values between 9 and infinity; Z corresponds to a tetravalent element selected from Si and Ge or mixtures thereof; Y corresponds to a tetravalent element such as Ti, Sn, Zr, V or mixtures thereof; and z/y may have values between 10 and infinity.
    Type: Application
    Filed: September 5, 2012
    Publication date: February 21, 2013
    Inventors: Avelino CORMA CANÓS, Fernando REY GARCÍA, Maria Teresa NAVARRO VILLALBA, Raquel SIMANCAS COLOMA, Noemi VELAMAZÁN CIRUJEDA, Ángel CANTIN SANZ, José Luis JORDÁ MORET
  • Patent number: 8337594
    Abstract: The present invention describes the use of isostructural zeolites with rho zeolitic structure in processes of adsorption and separation of the various components of natural gas.
    Type: Grant
    Filed: October 13, 2011
    Date of Patent: December 25, 2012
    Assignees: Consejo Superior de Investigaciones Cientficas (CSIC), Universidad Politecnica de Valencia (UPV)
    Inventors: Avelino Corma Canos, Miguel Palomino Roca, Fernando Rey Garcia, Susana Valencia Valencia
  • Patent number: 8226925
    Abstract: Described herein are zeolite microporous crystalline materials comprising, in the heated state and in the absence of defects in its crystalline framework manifested by the presence of silanols, the empirical formula: x(M1/nXO2):yYO2:SiO2, wherein M is selected from H+, an inorganic cation of charge +n, and mixtures thereof, X is at least one chemical element having an oxidation state of +3, Y is at least one second chemical element other than Si having an oxidation state +4, x has a value between 0 and about 0.3, y has a value between 0 and about 0.1, and wherein the synthesized material has an X-ray diffraction pattern having at least values of angle 2? (degrees) and relative intensities (I/I0) described. Process of making the microporous crystalline materials are also disclosed.
    Type: Grant
    Filed: January 31, 2008
    Date of Patent: July 24, 2012
    Assignee: Consejo Superior de Investigaciones Cientificas
    Inventors: Avelino Corma Canos, Manuel Moliner Marin, Fernando Rey Garcia, Jorge Gonzalez Gonzalez
  • Patent number: 8187469
    Abstract: The invention relates to a method of separating fluids from mixtures using a zeolite known as ITQ-32 consisting of a two-dimensional pore system comprising channels with openings formed by 8 tetrahedra which are interconnected by channels with openings formed by 12 tetrahedra. The inventive method comprises at least the following steps: a) the zeolite ITQ-32 material is brought into contact with the mixture of fluids, b) one or more of the components are adsorbed in the zeolite ITQ-32 material, c) the non-adsorbed components are extracted, and d) one or more of the components adsorbed in the zeolite ITQ-32 material are recovered.
    Type: Grant
    Filed: July 24, 2006
    Date of Patent: May 29, 2012
    Assignees: Consejo Superior de Investigaciones Cientificas, Universidad Politecnica de Valencia
    Inventors: Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia
  • Publication number: 20120067216
    Abstract: The present invention describes the use of isostructural zeolites with rho zeolitic structure in processes of adsorption and separation of the various components of natural gas.
    Type: Application
    Filed: October 13, 2011
    Publication date: March 22, 2012
    Inventors: Avelino CORMA CANOS, Miguel Palomino Roca, Fernando Rey Garcia, Susana Valencia Valencia
  • Patent number: 7854834
    Abstract: The invention relates to a catalyst consisting of at least: one matrix comprising at least one oxide which is selected from an amorphous oxide, an oxide with low crystallinity and a mixture of both; at least one solid microporous crystalline material which, in the calcined and anhydrous state, has the molar compositions X2O3:nYO2:mZO2, in which X is a trivalent element such as, for example, Al, B, Fe, In, Ga, Cr, Y is at least one trivalent element that is different from Ge and Z is Ge, the value (n+m) is at least equal to 5 and can be between 5 and ?, and the value of n/m is at least equal to 1; and at least one hydrogenating compound, preferably Pt, Pd, Ir, Ru, Rh, and Re or a combination of same. The invention also relates to the use of said catalyst in a process in order to improve the quality of diesel fractions.
    Type: Grant
    Filed: August 25, 2009
    Date of Patent: December 21, 2010
    Assignees: Consejo Superior de Invetigaciones Cientificas, Universidad Politenica de Valencia
    Inventors: Avelino Corma Canos, Agustin Martinez Feliu, Fernando Rey García, María José Díaz Cabañas, Maria de los Desamparados Arribas Viana