Abstract: A method of forming an interlayer of a solid oxide cell unit on the surface of a substrate may include: providing a base interlayer solution comprising a solution of a soluble salt precursor of a metal oxide (crystalline) ceramic and crystalline nanoparticles, depositing the base interlayer solution onto the surface of the substrate, drying the base interlayer solution to define a nanocomposite sub-layer of the soluble salt precursor and nanoparticles, heating the sub-layer to decompose it and form a film of metal oxide comprising nanoparticles on the surface, and firing the substrate with the film on the metal surface, to form a nanocomposite crystalline layer.

Abstract: A method of coating a substrate includes the steps of: (i) providing a suspension of dye and a binder in a solvent, wherein the ratio of dye to binder is greater than 40 wt % and the dye is uniformly dispersed in the solvent; (ii) spray-coating the suspension onto the substrate with the majority of the solvent evaporating during the spray coating step to result in a coating of dye and binder on the substrate having a density of up to 0.75 gcm-3; and (iii) continuing step (ii) until the coating thickness is at least 30 micrometres; wherein the dye does not include any carbon nanotubes.

Abstract: Exhaust gas catalysts are disclosed. One exhaust gas catalyst comprises a noble metal and a molecular sieve, and has an infrared spectrum having a characteristic absorption peak from 750 cm?1 to 1050 cm?1 in addition to the absorption peaks for the molecular sieve itself. The exhaust gas catalyst also comprises a noble metal and a molecular sieve, having greater than 5 percent of the noble metal amount located inside pores of the molecular sieve. The exhaust gas catalyst also comprises a first and second molecular sieve catalyst. The first molecular sieve catalyst comprises a first noble metal and a first molecular sieve, and the second molecular sieve catalyst comprises a second noble metal and a second molecular sieve. The first and second molecular sieves are different. The invention also includes exhaust systems comprising the exhaust gas catalysts, and a method for treating exhaust gas utilizing the exhaust gas catalysts.

Abstract: A low reflectivity coating (40, 80/82) is provided on a substrate (22). The coating includes a layer of substantially vertically aligned carbon nanotubes (40) on an exposed surface (21) of the substrate. Provided on and extending partially within the carbon nanotube layer (40) is a hydrophobic coating (80, 82), in the preferred embodiment of or containing fluorocarbon. The hydrophobic coating (80, 82) prevents any settling or ingress of water particles onto or into the carbon nanotube layer (40) and as a result increases the stability of the carbon nanotube layer during use (40) while improving the low reflectivity of the film.

Abstract: A low reflectivity coating (40, 80/82) is provided on a substrate (22). The coating includes a layer of substantially vertically aligned carbon nanotubes (40) on an exposed surface (21) of the substrate. Provided on and extending partially within the carbon nanotube layer (40) is a hydrophobic coating (80, 82), in the preferred embodiment of or containing fluorocarbon. The hydrophobic coating (80, 82) prevents any settling or ingress of water particles onto or into the carbon nanotube layer (40) and as a result increases the stability of the carbon nanotube layer during use (40) whilst improving the low reflectivity of the film.

Abstract: A NOx trap composition, and its use in an exhaust system for internal combustion engines, is disclosed. NOx trap composition comprises a platinum group metal, barium, cobalt, and a magnesia-alumina support. The NOx trap composition is less prone to storage deactivation and exhibits reduced N2O formation.

Abstract: A NOx absorber catalyst comprising a substrate monolith coated with one or more washcoat layers and comprising a first component comprising a nitrogen oxide storage component, at least one precious metal and a dispersed rare earth oxide supported on a refractory support material, and a second component comprising a precious metal supported on a bulk reducible oxide that is substantially free of nitrogen oxide storage material, wherein the precious metal present in the second component comprises Pt, Pd or a combination of both Pt and Pd and wherein the bulk reducible oxide is an oxide, a composite oxide or a mixed oxide comprising at least one of manganese, iron, cobalt, copper, tin or cerium.

Abstract: Exhaust gas catalysts are disclosed. One exhaust gas catalyst comprises a noble metal and a molecular sieve, and has an infrared spectrum having a characteristic absorption peak from 750 cm?1 to 1050 cm?1 in addition to the absorption peaks for the molecular sieve itself. The exhaust gas catalyst also comprises a noble metal and a molecular sieve, having greater than 5 percent of the noble metal amount located inside pores of the molecular sieve. The exhaust gas catalyst also comprises a first and second molecular sieve catalyst. The first molecular sieve catalyst comprises a first noble metal and a first molecular sieve, and the second molecular sieve catalyst comprises a second noble metal and a second molecular sieve. The first and second molecular sieves are different. The invention also includes exhaust systems comprising the exhaust gas catalysts, and a method for treating exhaust gas utilizing the exhaust gas catalysts.

Abstract: A method to produce a NOx trap composition, and its use in a NOx trap and in an exhaust system for internal combustion engines, is disclosed. The NOx trap composition is produced by heating an iron-containing zeolite in the presence of an inert gas and an organic compound to produce a reductively calcined iron/zeolite. A palladium compound is then added to the reductively calcined iron/zeolite, and the resulting Pd—Fe/zeolite is then calcined at 400 to 600° C. in the presence of an oxygen-containing gas to produce the NOx trap composition. The NOx trap composition shows low temperature NO capacity below 200° C., as well as an additional NO storage temperature window in the 200 to 250° C. range.

Abstract: A method to produce a NOx trap composition, and its use in a NOx trap and in an exhaust system for internal combustion engines, is disclosed. The NOx trap composition is produced by heating an iron-containing zeolite in the presence of an inert gas and an organic compound to produce a reductively calcined iron/zeolite. A palladium compound is then added to the reductively calcined iron/zeolite, and the resulting Pd—Fe/zeolite is then calcined at 400 to 600° C. in the presence of an oxygen-containing gas to produce the NOx trap composition. The NOx trap composition shows low temperature NO capacity below 200° C., as well as an additional NO storage temperature window in the 200 to 250° C. range.

Abstract: A NOx absorber catalyst comprising a substrate monolith coated with one or more washcoat layers and comprising a first component comprising a nitrogen oxide storage component, at least one precious metal and a dispersed rare earth oxide supported on a refractory support material, and a second component comprising a precious metal supported on a bulk reducible oxide that is substantially free of nitrogen oxide storage material, wherein the precious metal present in the second component comprises Pt, Pd or a combination of both Pt and Pd and wherein the bulk reducible oxide is an oxide, a composite oxide or a mixed oxide comprising at least one of manganese, iron, cobalt, copper, tin or cerium.

Abstract: A NOx trap composition, and its use in an exhaust system for internal combustion engines, is disclosed. NOx trap composition comprises a platinum group metal, barium, cobalt, and a magnesia-alumina support. The NOx trap composition is less prone to storage deactivation and exhibits reduced N2O formation.