Abstract: A resin-extended modified diene elastomer is based on a plasticizing resin and a diene elastomer having a number-average molar mass before modification Mn1 and a number-average molar mass Mn2 after modification, Mn1 and Mn2 being measured by triple detection size exclusion chromatography, the modified diene elastomer comprising branched chains corresponding to the following general formula (I) the modified diene elastomer having an Mn2 of greater than or equal to 200 000 g/mol and has an Mn2/Mn1 ratio of strictly greater than 1.00.

Abstract: A resin-extended modified diene elastomer is capable of being obtained by a process comprising at least: anionically polymerizing, in an organic solvent, at least one conjugated diene monomer having from 4 to 12 carbon atoms in the presence of a polymerization initiator to form a living diene elastomer having a number-average molar mass Mn1; modifying the living diene elastomer by reaction with a modifying agent to form a modified diene elastomer having a number-average molar mass Mn2 and a glass transition temperature, measured according to the standard ASTM D3418-08, within a range extending from ?95° C. to ?70° C.; adding at least one plasticizing resin to the organic solvent comprising the modified diene elastomer; and removing the organic solvent to obtain the resin-extended modified diene elastomer. The resin-extended modified diene elastomer has an Mn2/Mn1 ratio of strictly greater than 1.00 and an Mn2 of greater than or equal to 200,000 g/mol.

Abstract: A copolymer of ethylene and a 1,3-diene, containing more than 50 mol % of ethylene units and containing 1,2-cyclohexanediyl units is provided. The 1,3-diene is 1,3-butadiene or a mixture of 1,3-dienes containing 1,3-butadiene, and the copolymer consists of a main chain and one or more side chains.

Abstract: A process for preparing a functionalized polybutadiene is provided. The process comprises the following steps: a) homopolymerising butadiene with a catalytic system based on at least one preforming conjugated diene, a salt of one or more rare earth metals of an organic phosphoric acid, an aluminium-containing alkylating agent, an alkylaluminium halide; b) adding a polyfunctional compound to the pseudo-living elastomer formed in step (a); and c) adding a functionalizing agent to the mixture formed in step (b). The total molar amount of aluminium in the polymerization medium is such that the (aluminium/rare earth salt) molar ratio has a value between 1 and 5 and the polymerization is carried out at a temperature between 40° C. and 90° C. A functionalized polybutadiene that can be obtained by the process, and a rubber composition containing the functionalized polybutadiene is also provided.

Abstract: A modified diene elastomer having a good flow resistance, and imparting to a rubber composition containing the same a good compromise of hysteresis and abrasion properties and a satisfactory processing with a view to a tire application is provided. This modified elastomer comprises: a) at least 70% by weight of a linear diene elastomer predominantly functionalized in the middle of the chain by an alkoxysilane group, optionally partly or completely hydrolyzed to silanol, the alkoxysilane group optionally bearing another function capable of interacting with a reinforcing filler, the silicon atom of the alkoxysilane group lying in the main chain of the diene elastomer; b) more than 0 and up to 30% by weight of a star-branched diene elastomer, the Mooney viscosity of said modified diene elastomer varying from 50 to 80 and the glass transition temperature (Tg) thereof varying from ?100° C. to ?80° C.

Abstract: A modified diene elastomer is provided. The elastomer comprises: at least 70% by weight, with respect to the total weight of the modified diene elastomer, of a linear diene elastomer functionalized predominantly in the middle of the chain by an alkoxysilane group, optionally partially or completely hydrolysed to give silanol, the alkoxysilane group optionally bearing another functional group capable of interacting with a reinforcing filler, the alkoxysilane group bonded to the two branches of the diene elastomer via the silicon atom, the functionalized diene elastomer exhibiting a polydispersity index before fractionalization of less than or equal to 1.6; and more than 0 and up to 30% by weight, with respect to the total weight of the modified diene elastomer, of a star-branched diene elastomer exhibiting a polydispersity index before star-branching of less than or equal to 1.6, the Mooney viscosity of the modified diene elastomer varying from 30 to 80.

Abstract: A modified diene elastomer having a good flow resistance, and imparting to a rubber composition containing the same a good compromise of hysteresis and abrasion properties and a satisfactory processing with a view to a tire application is provided. This modified elastomer comprises: a) at least 70% by weight of a linear diene elastomer predominantly functionalized in the middle of the chain by an alkoxysilane group, optionally partly or completely hydrolyzed to silanol, the alkoxysilane group optionally bearing another function capable of interacting with a reinforcing filler, the silicon atom of the alkoxysilane group lying in the main chain of the diene elastomer; b) more than 0 and up to 30% by weight of a star-branched diene elastomer, the Mooney viscosity of said modified diene elastomer varying from 50 to 80 and the glass transition temperature (Tg) thereof varying from ?100° C. to ?80° C.

Abstract: A modified diene elastomer is provided. The elastomer comprises: at least 70% by weight, with respect to the total weight of the modified diene elastomer, of a linear diene elastomer functionalized predominantly in the middle of the chain by an alkoxysilane group, optionally partially or completely hydrolysed to give silanol, the alkoxysilane group optionally bearing another functional group capable of interacting with a reinforcing filler, the alkoxysilane group bonded to the two branches of the diene elastomer via the silicon atom, the functionalized diene elastomer exhibiting a polydispersity index before fractionalization of less than or equal to 1.6; and more than 0 and up to 30% by weight, with respect to the total weight of the modified diene elastomer, of a star-branched diene elastomer exhibiting a polydispersity index before star-branching of less than or equal to 1.6, the Mooney viscosity of the modified diene elastomer varying from 30 to 80.