Abstract: A solid-state lithium battery including a lithium-containing anode and a phosphorus-containing cathode is disclosed. The cathode may include any of a number of electronically conductive allotropes of phosphorus, referred to as a group as black phosphorus. A solid discharge product of the cell acts as an electrolyte for the cell. The cathode may include an auxiliary electronic conductor phase to improve the conductivity of the cathode, improve the cathode utilization during discharge and reduce the overall cell impedance.

Abstract: An apparatus and method are provided for treating pollutants in a gaseous stream. The apparatus comprises tubular inlets for mixing a gas stream with other oxidative and inert gases for mixture within a reaction chamber. The reaction chamber is heated by heating elements and has orifices through which cool or heated air enters into the central reaction chamber. A process is also provided whereby additional gases are added to the gaseous stream preferably within the temperature range of 650 C-950 C which minimizes or alleviates the production of NOx.

Abstract: A method for fabricating an active metal electrode involves depositing lithium or other active metal electrode on a protective layer. The protective layer is a glassy or amorphous material that conducts ions of the active metal. It may be deposited on a releasable web carrier or other substrate such as polymer electrolyte layer. Lithium is then deposited on the protective layer. Finally, a current collector is attached to the lithium.

Abstract: An apparatus and method are provided for treating pollutants in a gaseous stream. The apparatus comprises tubular inlets for mixing a gas stream with other oxidative and inert gases for mixture within a reaction chamber. The reaction chamber is heated by heating elements and has orifices through which cool or heated air enters into the central reaction chamber. A process is also provided whereby additional gases are added to the gaseous stream preferably within the temperature range of 650 C.-950 C. which minimizes or alleviates the production of NOx.

Abstract: An apparatus and method are provided for treating pollutants in a gaseous stream. The apparatus comprises tubular inlets for mixing a gas stream with other oxidative and inert gases for mixture within a reaction chamber. The reaction chamber is heated by heating elements and has orifices through which cool or heated air enters into the central reaction chamber. A process is also provided whereby additional gases are added to the gaseous stream preferably within the temperature range of 650 C.-950° C. which minimizes or alleviates the production of NOx.

Abstract: A method for fabricating an active metal electrode involves depositing lithium or other active metal electrode on a protective layer. The protective layer is a glassy or amorphous material that conducts ions of the active metal. It may be deposited on a releasable web carrier or other substrate such as polymer electrolyte layer. Lithium is then deposited on the protective layer. Finally, a current collector is attached to the lithium.

Abstract: A process for forming an electrode involves mixing or homogenizing one or more electrode components in a "fugitive carrier". This mixture is then frozen by dropping the temperature to a level below which the fugitive carrier freezes. This locks the well-mixed electrode components in place in a solid matrix to form an electrode precursor. Thereafter, the fugitive carrier is sublimated from the electrode precursor to form an electrode in which the components are substantially unsegregated.

Abstract: Several advantages as to ease of cell fabrication, maximum cell size, fiber breakage, tubesheet tightness, resistance to tubesheet deformation in prolonged service, safety, etc., can be realized by using as the tubesheet in a hollow fiber type battery cell one which is elongated in shape, has a substantially smaller diameter than the fiber "bundle" depending from it and in which the fiber ends passing through it are closely packed.

Abstract: Several advantages as to ease of cell fabrication, maximum cell size, fiber breakage, tubesheet tightness, resistance to tubesheet deformation in prolonged service, safety, etc., can be realized by using as the tubesheet in a hollow fiber type battery cell one which is elongated in shape, has a substantially smaller diameter than the fiber "bundle" depending from it and in which the fiber ends passing through it are closely packed.

Abstract: Several advantages as to ease of cell fabrication, maximum cell size, fiber breakage, tubesheet tightness, resistance to tubesheet deformation in prolonged service, safety, etc., can be realized by using as the tubesheet in a hollow fiber type battery cell one which is elongated in shape, has a substantially smaller diameter than the fiber "bundle" depending from it and in which the fiber ends passing through it are closely packed.

Abstract: Alkali metal/sulfur battery cells, in which the cathodic current collector is a shaped article comprising an aluminum substrate coated with molybdenum, have longer service lives if the molybdenum is overcoated with a layer of molybdenum oxides comprising an outer portion consisting of MoO.sub.3.

Abstract: Cracks, in ceramic wall members, on the order of 1 micron or less in width are plugged helium-tight by selectively leaching a component of the wall member with a solvent, letting the resultant leach form a liquid bridge within the crack, removing the solvent and sintering the resultant residue. This method is of particular value for remedying microcracks or channels in a cell member constituting a tubesheet in a hollow fiber type, high temperature battery cell, such as a sodium/sulfur cell, for example.

Abstract: Alkali metal/sulfur battery cells, in which the cathodic current collector is a shaped article comprising an aluminum substrate coated with molybdenum, have longer service lives if the molybdenum is overcoated with a layer of molybdenum oxides comprising an outer portion consisting of MoO.sub.3.

Abstract: A ceramic tubesheet pierced by a plurality of hollow, glass fibers and consisting of sintered particles is rendered essentially impermeable by selectively fusing the portion of the tubesheet subjacent to and defining one of its surfaces. The fiber lengths extending from the opposite surface of the tubesheet are freer to flex and less likely to be broken than if the entire tubesheet were fused.

Abstract: There is disclosed a method of selectively plugging broken fibers included in a bundle of hollow fibers having open ends terminating in or protruding from one face of a tubesheet and closed ends or loops depending from the other face of the tubesheet. The open ends are covered with a curable and flowable sealant and a pressure differential is utilized to draw the sealant into the broken fibers. The resistance to compression of the gases in the unbroken fibers is such that the sealant does not move into them a substantial distance. The sealant is diluted and another pressure differential employed to expel the sealant from the good fibers. The diluted sealant is removed and the plugs in the broken fibers are cured.

Abstract: Alkali metal oxides dissolved in alkali metal melts are reduced with soluble metals which are converted to insoluble oxides. The end points of the reduction is detected as an increase in electrical resistance across an alkali metal ion-conductive membrane interposed between the oxide-containing melt and a material capable of accepting the alkali metal ions from the membrane when a difference in electrical potential, of the appropriate polarity, is established across it. The resistance increase results from blocking of the membrane face by ions of the excess reductant metal, to which the membrane is essentially non-conductive.

Abstract: A ceramic tubesheet pierced by a plurality of hollow, glass fibers and consisting of sintered particles is rendered essentially impermeable by selectively fusing the portion of the tubesheet subjacent to and defining one of its surfaces. The fiber lengths extending from the opposite surface of the tubesheet are freer to flex and less likely to be broken than if the entire tubesheet were fused.

Abstract: There is disclosed a method of selectively plugging broken fibers included in a bundle of hollow fibers having open ends protruding from a tubesheet and closed ends distal from the tubesheet. The protruding open ends are immersed in a curable, fluid sealant and capillary attraction is utilized to draw the sealant into the broken fibers. The resistance to compression of the gases in the unbroken fibers is such that the sealant does not move into the latter fibers so far that they will not be open after the protruding ends are removed. The imbibed sealant is cured in place and the protruding fiber ends are cut off flush with the final surface of the tubesheet. This method is of particular value in preparing tubesheet-fiber assemblies for use in high temperature alkali metal-sulfur battery cells, wherein the hollow fibers function as an electrolyte-separator.