Patents by Inventor François Beguin

François Beguin has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10008334
    Abstract: An electrochemical capacitor includes a first electrode connected to a positive terminal of a power source during the charge of the electrochemical capacitor and a second electrode connected to a negative terminal of a power source during the charge of the electrochemical capacitor. The first and the second electrodes each have a carbon material. The electrochemical capacitor further includes a porous separator to separate the first and second electrodes and to be impregnated with an almost neutral aqueous electrolyte situated between the two electrodes. The neutral aqueous electrolyte has a salt formed by a metallic cation and an anion.
    Type: Grant
    Filed: September 18, 2013
    Date of Patent: June 26, 2018
    Assignees: CNRS, Universite D'Orleans
    Inventors: Francois Beguin, Laurent Demarconnay, Encarnacion Raymundo-Pinero
  • Patent number: 9742003
    Abstract: A method of producing a silicon/carbon composite material which includes the following successive steps: providing a silicon/polymer composite material from silicon particles and a carbonaceous polymer compound, precursor of carbon and able to be cross-linked, performing at least partial cross-linking of the polymer of the silicon/polymer composite material so as to obtain a cross-linked silicon/polymer composite material, the polymer having a cross-linking rate greater than or equal to 50% and, pyrolyzing the cross-linked silicon/polymer composite material until said silicon/carbon composite material is obtained.
    Type: Grant
    Filed: September 13, 2012
    Date of Patent: August 22, 2017
    Assignees: COMMISSARIAT À L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITÉ D'ORLÉANS
    Inventors: Cyril Paireau, Séverine Jouanneau-Si Larbi, François Béguin, Encarnacion Raymundo-Pinero
  • Publication number: 20150291432
    Abstract: The invention relates to a method for manufacturing activated carbon from tobacco leaves by simultaneous carbonization and self-activation in an inert gas environment. The activated carbon produced by this new method has a specific surface area from 600 to 2000 m2 g?1, preferably 1700 m2 g?1, and has an extensive amount of ultramicropores and mesopores, wherein the ratio of the micropore volume to the mesopore volume is at minimum of 3:1, up to 10:1, preferably 4:1. The average pore size (L0) is in the range of 0.55-1.3 nm, preferably 0.8-1.2 nm, with a total pore volume of 0.2 to 1.25 cm3 g?1. The invention also refers to an electrode comprising the activated carbon having the above properties as well as the electrochemical capacitor with such an electrode.
    Type: Application
    Filed: November 16, 2013
    Publication date: October 15, 2015
    Inventors: Francois Béguin, Elzbieta Frackowiak, Piotr Kleszyk
  • Patent number: 9136066
    Abstract: A method is provided for developing a hybrid supercapacitor. The method includes the use of a lithium salt of the electrolyte to carry out the intercalation/insertion of the lithium at the negative electrode but by greatly increasing the concentration of lithium ions of the electrolyte order to subsequently accept a depletion. As the depletion in ions has an impact on the conductivity, the amount and the concentration of the electrolyte are chosen in order to make it possible to accept this depletion white retaining a conductivity of the electrolyte compatible with a powerful system for storage of energy. A portion of the Li+ ions present in the electrolyte is used to form the passivation layer and the compound for intercalation/insertion Li˜0.5C6 at the negative electrode.
    Type: Grant
    Filed: April 17, 2012
    Date of Patent: September 15, 2015
    Assignees: Blue Solutions, Centre National De La Recherche Scientifique
    Inventors: Meriem Anouti, Daniel Lemordant, Grzegorz Lota, Celine Moueza-Decaux, Encarnacion Raymundo-Pinero, Francois Beguin, Philippe Azais
  • Publication number: 20150203366
    Abstract: A cyclic process is provided for reversible adsorption of emerging pollutants or micropollutants for depolluting a contaminated aqueous medium. The process is carried out without oxygen-containing gas, and without the provision of radical initiators, and includes a plurality of cycles, each cycle having the following steps: a. the adsorption of the emerging pollutants and micropollutants contained in the aqueous medium onto an activated carbon felt electrode by bringing the contaminated aqueous medium into contact with the activated carbon felt electrode making it possible to adsorb the emerging pollutants and micropollutants contained in the aqueous medium onto the activated carbon felt electrode; and b.
    Type: Application
    Filed: August 19, 2013
    Publication date: July 23, 2015
    Applicant: CENTRE NATIONAL de la RECHERCHE SCIENTIFIQUE
    Inventors: Sandrine Delpeux-Ouldriane, Francois Beguin
  • Publication number: 20140332717
    Abstract: A method of producing a silicon/carbon composite material which includes the following successive steps: providing a silicon/polymer composite material from silicon particles and a carbonaceous polymer compound, precursor of carbon and able to be cross-linked, performing at least partial cross-linking of the polymer of the silicon/polymer composite material so as to obtain a cross-linked silicon/polymer composite material, the polymer having a cross-linking rate greater than or equal to 50% and, pyrolysing the cross-linked silicon/polymer composite material until said silicon/carbon composite material is obtained.
    Type: Application
    Filed: September 13, 2012
    Publication date: November 13, 2014
    Applicants: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE D'ORLEANS, COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Cyril Paireau, Séverine Jouanneau-Si Larbi, François Béguin, Encarnacion Raymundo-Pinero
  • Publication number: 20140325807
    Abstract: The invention relates to a method for developing a hybrid supercapacitor, said method including: at least a step of assembling together a negative electrode, made of at least one non-porous carbon material, and a positive electrode, made of at least one porous carbon material, said electrodes being separated from each other by means of at least one separator impregnated with a liquid electrolyte containing at least one lithium salt dissolved in at least one solvent; and then at least one first charging step, wherein said method is characterized in that: a) the lithium-ion concentration in the liquid electrolyte, before the first charging step, is greater than or equal to 1.
    Type: Application
    Filed: April 17, 2012
    Publication date: November 6, 2014
    Inventors: Meriem Anouti, Daniel Lemordant, Grzegorz Lota, Celine Moueza-Decaux, Encarnacion Raymundo-Pinero, Francois Beguin, Philippe Azais
  • Publication number: 20140016247
    Abstract: An electrochemical capacitor includes a first electrode connected to a positive terminal of a power source during the charge of the electrochemical capacitor and a second electrode connected to a negative terminal of a power source during the charge of the electrochemical capacitor. The first and the second electrodes each have a carbon material. The electrochemical capacitor further includes a porous separator to separate the first and second electrodes and to be impregnated with an almost neutral aqueous electrolyte situated between the two electrodes. The neutral aqueous electrolyte has a salt formed by a metallic cation and an anion.
    Type: Application
    Filed: September 18, 2013
    Publication date: January 16, 2014
    Applicants: UNIVERSITE D'ORLEANS, CNRS
    Inventors: Francois BEGUIN, Laurent Demarconnay, Encarnacion Raymundo-Pinero
  • Patent number: 8059389
    Abstract: A composite suitable as a charge-storing material for electrochemical capacitors contains carbon nanotubes and a carbonaceous materiel. The carbonaceous material is the carbonization residue of a biopolymer or seaweed rich in heteroatoms. Wherein the carbonization residue of the biopolymer or seaweed is electrically conductive and has a heteroatom content as detected by XPS of at least 6%.
    Type: Grant
    Filed: August 17, 2009
    Date of Patent: November 15, 2011
    Assignees: SGL Carbon SE, Centre National de la Recherche Scientifique, L'Universite d'Orleans
    Inventors: Martin Cadek, Mario Wachtler, Encarnacion Raymundo-Pinero, Francois Beguin
  • Patent number: 7947246
    Abstract: A carbon material suitable for the preparation of electrodes for electrochemical capacitors is obtained by single-stage carbonization of biopolymers with a large content of heteroatoms. Neither addition of an activating agent during carbonization nor subsequent gas phase activation is necessary. Several biopolymers which are available by extraction from seaweed are suitable precursors. Alternatively, the seaweed containing such biopolymers is carbonized directly.
    Type: Grant
    Filed: August 1, 2008
    Date of Patent: May 24, 2011
    Assignees: SGL Carbon SE, Centre National de la Recherche Sientifique, L'Universite d'Orleans
    Inventors: Martin Cadek, Francois Beguin, Encarnacion Raymundo-Pinero
  • Patent number: 7936556
    Abstract: An electrolytic capacitor (1) includes a first electrode (2) and a second electrode (3) each including carbon and an aqueous electrolyte (4) situated at the interface of the two electrodes. The carbon surface of the first electrode (2) has an atomic degree of functionalization which is at least twice that of the carbon surface of the second electrode (3).
    Type: Grant
    Filed: November 30, 2007
    Date of Patent: May 3, 2011
    Assignees: Centre National de la Recherche Scientifique (C.N.R.S.), Universite d'Orleans
    Inventors: Françoïs Beguin, Volodymyr Khomenko, Encarnacion Raymundo-Pinero
  • Publication number: 20100141044
    Abstract: An electrolytic capacitor (1) includes a first electrode (2) and a second electrode (3) each including carbon and an aqueous electrolyte (4) situated at the interface of the two electrodes. The carbon surface of the first electrode (2) has an atomic degree of functionalization which is at least twice that of the carbon surface of the second electrode (3).
    Type: Application
    Filed: November 30, 2007
    Publication date: June 10, 2010
    Applicants: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.), UNIVERSITE D'ORLEANS
    Inventors: Francois Beguin, Volodymyr Khomenko, Encarnacion Raymundo-Pinero
  • Publication number: 20100033902
    Abstract: A composite suitable as a charge-storing material for electrochemical capacitors contains carbon nanotubes and a carbonaceous materiel. The carbonaceous material is the carbonization residue of a biopolymer or seaweed rich in heteroatoms. Wherein the carbonization residue of the biopolymer or seaweed is electrically conductive and has a heteroatom content as detected by XPS of at least 6%.
    Type: Application
    Filed: August 17, 2009
    Publication date: February 11, 2010
    Applicants: SGL CARBON SE, CENTRE NATIONALE DE LA RECHERCHE SCIENTIFIQUE, L'UNIVERSITÉ D'ORLÉANS
    Inventors: Martin Cadek, Mario Wachtler, Encarnacion Raymundo-Pinero, Francois Beguin
  • Publication number: 20090052117
    Abstract: A carbon material suitable for the preparation of electrodes for electrochemical capacitors is obtained by single-stage carbonization of biopolymers with a large content of heteroatoms. Neither addition of an activating agent during carbonization nor subsequent gas phase activation is necessary. Several biopolymers which are available by extraction from seaweed are suitable precursors. Alternatively, the seaweed containing such biopolymers is carbonized directly.
    Type: Application
    Filed: August 1, 2008
    Publication date: February 26, 2009
    Applicants: SGL CARBON AG, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, L'UNIVERSITE D'ORLEANS
    Inventors: Martin Cadek, Francois Beguin, Encarnacion Raymundo-Pinero
  • Publication number: 20080118838
    Abstract: The invention relates to a hydrogen-air secondary cell that finds application for supplying electrical energy to systems of electric cars and portable equipment such as telephones, photographic equipment and laptops. The hydrogen-air secondary cell is characterized in that it contains an electrode made of a material capable of high hydrogen sorption capacity through the electrochemical decomposition of water, connected to the negative pole, disposed between conventional air diffusion electrodes, with at least one auxiliary electrode with lowered oxygen release overpotential being positioned between the air electrodes and the hydrogen sorption electrode, and connected electrically to an auxiliary pole of the cell and charging the cell, the electrodes being kept apart by a separator.
    Type: Application
    Filed: February 7, 2006
    Publication date: May 22, 2008
    Inventors: Krysztof Jurewicz, Elzbieta Frackowiak, Francois Beguin
  • Patent number: 7094385
    Abstract: The present invention concerns a process for the mass production of carbon nanotubes and particularly a process for selectively producing multiwalled carbon nanotubes.
    Type: Grant
    Filed: March 12, 2002
    Date of Patent: August 22, 2006
    Assignee: CNRS
    Inventors: François Beguin, Sandrine Delpeux, Katarzyna Szostak
  • Publication number: 20050163697
    Abstract: The invention relates to an efficient and non-damaging method for opening carbon nanotubes, characterized in that it consists of two oxidation stages, the first in liquid phase in a concentrated acid, the second in gaseous phase.
    Type: Application
    Filed: August 8, 2003
    Publication date: July 28, 2005
    Inventors: Francois Beguin, Sandrine Delpeux, Katarzyna Szostak
  • Publication number: 20040022719
    Abstract: The present invention concerns a process for the mass production of carbon nanotubes and particularly a process for selectively producing multiwalled carbon nanotubes.
    Type: Application
    Filed: March 12, 2002
    Publication date: February 5, 2004
    Inventors: Francois Beguin, Sandrine Delpeux, Katarzyna Szostak
  • Patent number: 6361900
    Abstract: The carbon fibers present a mean lattice surface spacing (d002) not less than 0.36 nm, preferably 0.38 nm, at a crystallite size such that the mean height (Lc) lies in the range 0.7 nm to 0.3 nm and the mean width (La) lies in the range 2 nm to 6 nm, and it presents total porosity lying in the range 10% to 30%. The electrode is preferably a rayon-precursor carbon cloth and it constitutes the anode (10) of a secondary cell having a cathode (20) which includes lithium enabling lithium ions to be inserted and de-inserted, and an electrolyte (30).
    Type: Grant
    Filed: June 1, 2000
    Date of Patent: March 26, 2002
    Assignee: Messier-Bugatti
    Inventors: Philippe Parmentier, Francois Beguin, Elzbieta Frackowiak
  • Patent number: 5411762
    Abstract: A ceramic material based on Sialon, in particular on .beta.'-Sialon is obtained by reducing an aluminosilicate precursor by means of a gas phase comprising a mixture of hydrogen and nitrogen doped with a gaseous carbon compound. The gaseous carbon compound is a gas containing carbon in combined form, e.g. an alkane, and its concentration by volume in the gas is less than 3%. The method is particularly suitable for forming Sialon-based coatings on substrates that are solid or fibrous. For composite materials constituted by a fiber preform densified by means of a matrix, the method can be used to form an interphase coating on the fibers of the preform prior to densifying the preform, or the method can be used to form a matrix that is based on Sialon.
    Type: Grant
    Filed: February 2, 1994
    Date of Patent: May 2, 1995
    Assignee: Societe European De Propulsion
    Inventors: Jacques Thebault, Alain Seron, Francois Beguin