Patents by Inventor François-Genes Tournilhac
François-Genes Tournilhac has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20110166293Abstract: The present invention relates to a composition containing at least one (meth)acrylic polymer and at least one copolymer containing motifs from at least one first monomer (A), enabling compatibility with said (meth)acrylic polymer, and at least one second motif (B) carrying an associative group. The invention also relates to the use of such a copolymer having associative groups to improve the properties of a (meth)acrylic polymer. The invention also relates to uses of the abovementioned composition.Type: ApplicationFiled: June 12, 2009Publication date: July 7, 2011Applicants: Arkema France, CNRSInventors: Nicolas Dufaure, François-Genes Tournilhac, Manuel Hidalgo, Ludwik Leibler
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Publication number: 20110135859Abstract: The invention concerns a polymer material consisting of macromolecular chains bound by hydrogen bonds, wherein: the macromolecular chains consist of a polymer skeleton whereon is fixed by at least one covalent bond a modifying agent, the modifying agent comprising, assembled in a common molecule, one or more associative groups capable of being bound by hydrogen bonds and one or more reactive groups capable of forming covalent bonds with the polymer skeleton, at least one of the associative groups of the modifying agent is an imidazolidone heterocycle, the macromolecular chains bear on average, 1 to 10 imidazolidone groups per chain. The average number of imidazolidone groups to be introduced into the macromolecular chains depends both on the average mass of said chains and the final properties desired for the material.Type: ApplicationFiled: September 9, 2010Publication date: June 9, 2011Applicants: Arkema France, Centre National De La Recherche Scientifique (CNRS)Inventors: Francois-Genes TOURNILHAC, Ludwik Leibler, Philippe Cordier, Corinne Soulie-Ziakovic, Annett Linemann, Manuel Hidalgo
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Publication number: 20110065866Abstract: The present invention relates to a composition comprising: (a) at least one halogenated vinyl polymer and (b) at least one copolymer containing (i) units derived from a first monomer (A) rendering said copolymer compatible with said halogenated vinyl polymer and (ii) units derived from a second monomer (B) bearing at least one given associative group. The present invention also relates to the use of such a copolymer bearing associative groups, for improving certain properties of a halogenated vinyl polymer. The invention finally relates to the uses of the aforementioned composition.Type: ApplicationFiled: May 5, 2009Publication date: March 17, 2011Applicants: ARKEMA FRANCE, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE-CNRSInventors: Ludwik Leibler, Francois Genes Tournilhac, Nicolas Dufaure, Manuel Hidalgo
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Publication number: 20110059280Abstract: The present invention relates to a method for synthesizing a supramolecular material comprising: 1—the reaction of at least one carboxylic diacid, or ester or chloride of such a diacid, with, on the one hand, at least one modifier compound bearing both reactive functional groups capable of reacting with the carboxylic acid, ester or acid chloride functional groups and associative groups capable of associating with one another by hydrogen bonds, in a molar ratio of the reactive functional groups to the carboxylic acid, ester or acid chloride functional groups of between 0.10 and 0.50, and, on the other hand, at least one polyamine, said reactions being carried out successively or simultaneously, and 2—the reaction of the polyamide obtained at the end of step 1 with urea. The present invention also relates to the resulting material, and also to the uses thereof.Type: ApplicationFiled: May 5, 2009Publication date: March 10, 2011Inventors: Damien Montarnal, Ludwick Leibler, Francois-Genes Tournilhac, Manuel Hidalgo
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Publication number: 20110003872Abstract: The present invention relates to a material comprising dendritic molecules each constituted of fragments that are at least bifunctional and of fragments that are at least trifunctional joined together by ester or thioester bridges, alone or in combination with amide or urea bridges, said bridges being formed from two functions carried by different fragments, said molecules containing, on the fragments located at the ends of the dendritic branches, associative end groups capable of forming associations with one another by hydrogen bonds and joined covalently to the functions that are not involved in said bridges. It also relates to the method of production thereof, as well as to its uses and to compositions, notably cosmetic, containing this material.Type: ApplicationFiled: December 2, 2008Publication date: January 6, 2011Applicants: Arkema France, Centre National De La Recherche Scientifique CNRSInventors: François-Genes Tournilhac, Manuel Hidalgo, Ludwik Leibler
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Publication number: 20100305334Abstract: The present invention relates to a method of preparing a material formed from arborescent-branched molecules comprising associative groups that includes the following successive steps: (a) the reaction of at least one at least trifunctional compound (A) bearing first and second functional groups with at least one bifunctional compound (B), the functional groups of which are capable of, reacting with the first functional groups of the compound (A); and (b) the reaction of the compound(s) obtained in step (a) with at least one compound (C) bearing, on the one hand, at least one reactive group capable of reacting with the second functional groups of (A) and; on the other hand, at least one given associative groupType: ApplicationFiled: December 19, 2008Publication date: December 2, 2010Applicant: Arkema FranceInventor: Francois-Genes Tournilhac
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Patent number: 7750113Abstract: The invention relates to a supramolecular polymer containing units which are linked by hydrogen bonds, said units being monomers of prepolymers comprising at least one functional group selected from the functional groups (1) and (3) and a second functional group (5) wherein A denotes oxygen, sulphur or NH and X is any unit; the hydrogen bonds in the supramolecular polymer being formed between two identical or different functional groups chosen from the functional groups (1) to (5). The inventive polymers can be used alone, i.e. in the form of a composition which is essentially made from said polymers and, optionally, stabilizers, antioxidants, etc. or in the form of a mixture with other polymers or other products.Type: GrantFiled: March 19, 2008Date of Patent: July 6, 2010Assignee: Arkema FranceInventors: Francois-Genes Tournilhac, Corinne Soulie-Ziakovic, Ludwik Leibler, Laurent Lachaize
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Publication number: 20100135940Abstract: The invention relates to a supramolecular polymer derived from the reaction between (i) an amine bearing a nitrogen-containing heterocyclic group: imidazolidone, trimethyleneurea or triazine, capable of joining together via hydrogen bonds with (ii) at least one fatty acid monomer comprising at least one reactive functional group, a dimer of identical or different fatty acids and/or a trimer of identical or different fatty acids, or a derivative of said fatty acid(s) chosen from a fatty acid ester, and a fatty acid chloride.Type: ApplicationFiled: September 7, 2007Publication date: June 3, 2010Applicant: Arkema FranceInventors: Sandra Grimaldi, Jean-Philippe Gillet, Manuel Hidalgo, Francois-Genes Tournilhac, Philippe Cordier, Ludwik Leibler
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Publication number: 20100120983Abstract: A polymeric material from the styrene family, consisting of macromolecular chains grafted by nitrogen-containing heterocyclic groups; wherein the macromolecular chains consist of a polymeric backbone to which a grafted agent is attached by at least one covalent bond, the grafting agent comprises, in a single molecule, one or more associative groups capable of being bound by hydrogen bonds, and one or more reactive groups capable of forming covalent bonds with the polymeric backbone, at least one of the associative groups of the modifier is an imidazolidone heterocyclic ring. The mean number of imidazolidone groups to be inserted into the macromolecular chains is dependent both on the mean mass of said chains and on the final properties to be imparted to the material. The polymeric material of the invention can be extruded, coextruded, injected, blow-moulded, moulded, overmoulded, calendered or thermoformed. Objects such as tubes, films, plates, stiffenerss, bottles and containers can be made.Type: ApplicationFiled: February 1, 2008Publication date: May 13, 2010Applicants: Arkema France, Centre National De La Recherche Scientifique (CNRSInventors: Nicolas Dufaure, Sandra Grimaldi, Manuel Hidalgo, Ludwik Leibler, Francois-Genes Tournilhac
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Publication number: 20090062551Abstract: The present invention relates to materials exhibiting the property of rubbery elasticity, consisting of molecules with a mass of between 9 and 9000 g/mol, all or some of the molecules having at least three groups (also referred to as “associative groups”) capable of associating via non-covalent interactions. Although consisting of small non-polymerized molecules that are not chemically crosslinked, this material exhibits properties of rubbery elasticity. According to an embodiment of the invention, this material exhibits rubbery elasticity at ambient temperature. Above a certain temperature, the material flows like a simple liquid. The material is thermoreversible, i.e. after cooling, the material again exhibits the property of rubbery elasticity. This material is self-repairing and potentially recyclable, which is never the case with a chemically crosslinked elastomer.Type: ApplicationFiled: February 14, 2006Publication date: March 5, 2009Applicant: ARKEMA FRANCEInventors: Francois-Genes Tournilhac, Ludwik Leibler, Philippe Cordier, Corinne Soulie-Ziakovic
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Publication number: 20080221272Abstract: The invention concerns a polymer material consisting of macromolecular chains bound by hydrogen bonds wherein: the macromolecular chains consist of a polymer skeleton whereon is fixed by at least one covalent bond a modifying agent, the modifying agent comprising, assembled in a common molecule, one or more associative groups capable of being bound by hydrogen bonds and one or more reactive groups capable of forming covalent bonds with the polymer skeleton, at least one of the associative groups of the modifying agent is an imidazolidone heterocycle, the macromolecular chains bear on average 1 to 10 imidazolidone groups per chain. The average number of imidazolidone groups to be introduced into the macromolecular chains depends both on the average mass of said chains and the final properties desired for the material. The inventive polymer material can be extruded, co-extruded, injected, blown, moulded, overmoulded, calandered, thermoformed.Type: ApplicationFiled: July 6, 2005Publication date: September 11, 2008Inventors: Francois-Genes Tournilhac, Ludwik Leibler, Philippe Cordier, Corinne Soulie-Ziakovic, Annett Linemann, Manuel Hidalgo
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Publication number: 20080167442Abstract: The invention relates to a supramolecular polymer containing units which are linked by hydrogen bonds, said units being monomers of prepolymers comprising at least one functional group selected from the functional groups (1) and (3) and a second functional group (5) wherein A denotes oxygen, sulphur or NH and X is any unit; the hydrogen bonds in the supramolecular polymer being formed between two identical or different functional groups chosen from the functional groups (1) to (5). The inventive polymers can be used alone, i.e. in the form of a composition which is essentially made from said polymers and, optionally, stabilizers, antioxidants, etc. or in the form of a mixture with other polymers or other products.Type: ApplicationFiled: March 19, 2008Publication date: July 10, 2008Applicant: Arkema FranceInventors: Francois-Genes Tournilhac, Corinne Soulie-Ziakovic, Ludwik Leibler, Laurent Lachaize
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Patent number: 7348397Abstract: The invention relates to a supramolecular polymer containing units which are linked by hydrogen bonds, said units being monomers of prepolymers comprising at least one functional group selected from the functional groups (1) and (3) and a second functional group (5) wherein A denotes oxygen, sulphur or NH and X is any unit; the hydrogen bonds in the supramolecular polymer being formed between two identical or different functional groups chosen from the functional groups (1) to (5). The inventive polymers can be used alone, i.e. in the form of a composition which is essentially made from said polymers and, optionally, stabilizers, antioxidants, etc. or in the form of a mixture with other polymers or other products.Type: GrantFiled: November 14, 2006Date of Patent: March 25, 2008Assignee: Arkema FranceInventors: Francois-Genes Tournilhac, Corinne Soulie-Ziakovic, Ludwik Leibler, Laurent Lachaize
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Patent number: 7250487Abstract: The invention relates to a supramolecular polymer containing units which are linked by hydrogen bonds, said units being monomers of prepolymers comprising at least one functional group selected from the functional groups (1) and (3) and a second functional group chosen from functional groups (1) to (5) wherein A denotes oxygen, sulphur or NH and X is any unit; the hydrogen bonds in the supramolecular polymer being formed between two identical or different functional groups chosen from the functional groups (1) to (5). The inventive polymers can be used alone, i.e. in the form of a composition which is essentially made from said polymers and, optionally, stabilizers, antioxidants, etc. or in the form of a mixture with other polymers or other products.Type: GrantFiled: January 15, 2003Date of Patent: July 31, 2007Assignee: Arkema FranceInventors: Francois-Genes Tournilhac, Corinne Soulie-Ziakovic, Ludwik Leibler, Laurent Lachaize
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Publication number: 20070123694Abstract: The invention relates to a supramolecular polymer containing units which are linked by hydrogen bonds, said units being monomers of prepolymers comprising at least one functional group selected from the functional groups (1) and (3) and a second functional group (5) wherein A denotes oxygen, sulphur or NH and X is any unit; the hydrogen bonds in the supramolecular polymer being formed between two identical or different functional groups chosen from the functional groups (1) to (5). The inventive polymers can be used alone, i.e. in the form of a composition which is essentially made from said polymers and, optionally, stabilizers, antioxidants, etc. or in the form of a mixture with other polymers or other products.Type: ApplicationFiled: November 14, 2006Publication date: May 31, 2007Inventors: Francois-Genes Tournilhac, Corinne Soulie-Ziakovic, Ludwik Leibler, Laurent Lachaize
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Publication number: 20060116475Abstract: The invention relates to a shock-reinforced thermoplastic composition comprising at least one polyamide and at least one block copolymer having a block that is entirely or mainly comprised of sydiotactic methyl polymethacrylate at a rate of more than 60%. The inventive composition has excellent mechanical properties and can be used in various applications.Type: ApplicationFiled: January 13, 2004Publication date: June 1, 2006Inventors: Ludwik Leibler, Francois Court, Valery Rebizant, Volker Abertz, Francois-Genes Tournilhac, Christophe Navarro
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Publication number: 20050148760Abstract: The invention relates to a supramolecular polymer containing units which are linked by hydrogen bonds, said units being monomers of prepolymers comprising at least one functional group selected from the functional groups (1) and (3) and a second functional group chosen from functional groups (1) to (5) wherein A denotes oxygen, sulphur or NH and X is any unit; the hydrogen bonds in the supramolecular polymer being formed between two identical or different functional groups chosen from the functional groups (1) to (5). The inventive polymers can be used alone, i.e. in the form of a composiiotn which is essentially made from said polymers and, optionally, stabilizers, antioxidants, etc. or in the form of a mixture with other polymers or other products.Type: ApplicationFiled: January 15, 2003Publication date: July 7, 2005Inventors: Francois-Genes Tournilhac, Corinne Soulie-Ziakovic, Ludwik Leibler, Laurent Lachaize