Patents by Inventor Francis H. Walker
Francis H. Walker has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6291400Abstract: A compound of formula (I): or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X1 and X2 are independently oxygen or sulphur, R1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C2-C4 alkylene group which is optionally interposed by an oxygen atom, a group a group or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and Rb is alkyl or alkoxy; provided that when X, X1 and X2 are oxygen, R1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.Type: GrantFiled: May 27, 1999Date of Patent: September 18, 2001Assignee: Zeneca LimitedInventors: John E D Barton, David Cartwright, John M Cox, Glynn Mitchell, Charles G Carter, David L Lee, Francis H Walker, Frank X Woolard
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Patent number: 5958839Abstract: A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group ##STR2## a group ##STR3## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.Type: GrantFiled: February 11, 1998Date of Patent: September 28, 1999Assignee: Zeneca LitmitedInventors: John E. D. Barton, David Cartwright, John M Cox, Glynn Mitchell, Charles G. Carter, David L Lee, Francis H Walker, Frank X. Woolard
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Patent number: 5744610Abstract: A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed, by an oxygen atom, a group ##STR2## a group ##STR3## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.Type: GrantFiled: July 18, 1996Date of Patent: April 28, 1998Assignee: Zeneca LimitedInventors: John E. D. Barton, David Cartwright, John M. Cox, Glynn Mitchell, Charles G. Carter, David L. Lee, Francis H. Walker, Frank X. Woolard
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Patent number: 5563115Abstract: A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group ##STR2## a group ##STR3## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.Type: GrantFiled: May 30, 1995Date of Patent: October 8, 1996Assignee: Zeneca LimitedInventors: John E. D. Barton, David Cartwright, John M. Cox, Glynn Mitchell, Charles G. Carter, David L. Lee, Francis H. Walker, Frank X. Woolard
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Patent number: 5426091Abstract: A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group ##STR2## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.Type: GrantFiled: August 4, 1993Date of Patent: June 20, 1995Assignee: Zeneca LimitedInventors: John E. D. Barton, David Cartwright, John M. Cox, Glynn Mitchell, Charles G. Carter, David L. Lee, Francis H. Walker, Frank X. Woolard
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Patent number: 5314865Abstract: Compounds having the formula ##STR1## wherein R is C.sub.1 -C.sub.6 lower alkoxy; C.sub.1 -C.sub.6 lower alkylthio; 3- to 6-membered heterocycle or substituted heterocycle; phenyl or substituted phenyl; R.sub.1 is hydrogen or C.sub.1 -C.sub.3 lower alkyl; R.sub.2 is selected from the group consisting of hydrogen, C.sub.1 -C.sub.3 lower alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.1 -C.sub.3 lower alkylalkoxy or combinations thereof; R.sub.3 and R.sub.4 are independently selected from the group consisting of hydrogen; C.sub.1 -C.sub.6 lower alkyl; C.sub.2 -C.sub.6 lower alkenyl; C.sub.2 -C.sub.6 lower alkenyl; 3- to 6-membered heterocycle or substituted heterocycle; alkyl heterocycle or substituted alkyl heterocycle; phenyl or substituted phenyl; and where R.sub.3 or R.sub.4 is a basic heterocycle, herbicidally acceptable organic or inorganic salts thereof are herbicidally active.Type: GrantFiled: April 10, 1992Date of Patent: May 24, 1994Assignee: ICI Americas Inc.Inventors: Francis H. Walker, Don R. Baker
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Patent number: 5250501Abstract: A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group ##STR2## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.Type: GrantFiled: January 10, 1992Date of Patent: October 5, 1993Assignees: Imperial Chemical Industries PLC, ICI Americas, Inc.Inventors: John E. D. Barton, David Cartwright, John M. Cox, Glynn Mitchell, Charles G. Carter, David L. Lee, Francis H. Walker, Frank X. Woolard
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Patent number: 5157043Abstract: Novel fungicidal pyridyl carboximides having the general structural formula ##STR1## wherein R is C.sub.1 -C.sub.6 alkyl, preferably methyl;R.sub.1 is selected from the group consisting of halogen such as chlorine, fluorine and bromine, C.sub.1 -C.sub.3 alkoxy such as propoxyethoxy and methoxy, preferably methoxy, and C.sub.2 -C.sub.4 alkenyloxy;R.sub.2 is selected from the group consisting of hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.4 -C.sub.6 cycloalkyl, heterocyclic moieties, aryl, preferably phenyl, substituted aryl, preferably substituted phenyl wherein the substitutions are chlorine, fluorine, bromine, trifluoromethyl and --NO.sub.3 ;X is --O or --S; andY is --O or --S;and fungicidally acceptable organic and inorganic salts thereof which are highly effective fungicides for use both as preventive and curative fungicides are disclosed herein.Type: GrantFiled: November 1, 1990Date of Patent: October 20, 1992Assignee: Imperial Chemical Industries PLCInventors: Don R. Baker, Charles Kezerian, Francis H. Walker, Keith H. Brownell
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Patent number: 5098464Abstract: A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group>S(O).sub.pa group ##STR2## or an optionally mono-substituted nitrogen atom, wherein p is O, 1 or 2, s is 0.sub.1 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.Type: GrantFiled: October 9, 1990Date of Patent: March 24, 1992Assignees: Imperial Chemical Industries PLC, ICI Americas, Inc.Inventors: John E. D. Barton, David Cartwright, John M. Cox, Glynn Mitchell, Charles G. Carter, Davie L. Lee, Francis H. Walker, Frank X. Woolard
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Patent number: 5002605Abstract: Compounds having the formula ##STR1## wherein R is C.sub.1 -C.sub.6 lower alkoxy; C.sub.1 -C.sub.6 lower alkylthio; 3- to 6-membered heterocycle or substituted heterocycle; phenyl or substituted phenyl; R.sub.1 is hydrogen or C.sub.1 -C.sub.3 lower alkyl; R.sub.2 is selected from the group consisting of hydrogen, C.sub.1 -C.sub.3 lower alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.1 -C.sub.3 lower alkylalkoxy or combinations thereof; R.sub.3 and R.sub.4 are independently selected from the group consisting of hydrogen; C.sub.1 -C.sub.6 lower alkyl; C.sub.2 -C.sub.6 lower alkenyl; C.sub.2 -C.sub.6 lower alkynyl; 3- to 6-membered heterocyle or substituted heterocycle; alkyl heterocycle or substituted alkyl heterocycle; phenyl or substituted phenyl; and where R.sub.3 l or R.sub.4 is a basic heterocyle, herbicidally acceptable organic or inorganic salts thereof are herbicidally active.Type: GrantFiled: December 21, 1988Date of Patent: March 26, 1991Assignee: ICI Americas Inc.Inventors: Francis H. Walker, Don R. Baker
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Patent number: 4931451Abstract: Novel fungicidal pyridyl sulfenyl carbamates having the formula ##STR1## wherein R is selected from the group consisting of haloalkyl, C.sub.1 -C.sub.8 alkyl, aryl, substituted aryl, arylalkyl, substituted arylalkyl, alkanoyl, alkylamino, arylamino, arylalkylamino and substituted pyridylcarbamoyl;R.sub.1 is C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy or halomethoxy; alkenyloxy; and halogen;R.sub.2 is C.sub.1 -C.sub.3 alkyl;X is oxygen or sulfur; andY is oxygen or sulfurand fungicidally acceptable organic and inorganic salts thereof which are highly effective fungicides for use both as preventive and curative fungicides are disclosed herein.Type: GrantFiled: October 17, 1988Date of Patent: June 5, 1990Assignee: ICI Americas Inc.Inventors: Don R. Baker, Francis H. Walker, Keith H. Brownell
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Patent number: 4800205Abstract: Novel fungicidal pyridyl sulfenyl carbamates having the formula ##STR1## wherein R is selected from the group consisting of haloalkyl, C.sub.1 -C.sub.8 alkyl, aryl, substituted aryl, arylalkyl, substituted arylalkyl, alkanoyl, alkylamino, arylamino, arylalkylamino and substituted pyridylcarbamoyl;R.sub.1 is C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy or halomethoxy; alkenyloxy; and halogen;R.sub.2 is C.sub.1 -C.sub.3 alkyl;X is oxygen or sulfur; andY is oxygen or sulfurand fungicidally acceptable organic and inorganic salts thereof which are highly effective fungicides for use both as preventive and curative fungicides are disclosed herein.Type: GrantFiled: October 29, 1987Date of Patent: January 24, 1989Inventors: Don R. Baker, Francis H. Walker, Keith H. Brownell
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Patent number: 4695314Abstract: Novel S-benzyl thiolcarbamates are disclosed, having the formula ##STR1## in which R.sup.1 is selected from the group consisting of hydrogen and methoxy,R.sup.2 is selected from the group consisting of methyl, ethyl, and allyl, andR.sup.3 is selected from the group consisting of straight-chain C.sub.3 -C.sub.6 alkyl optionally substituted with one or two methyl groups, and allyl.The compounds are particularly effective in the control of weeds associated with rice crops.Type: GrantFiled: April 28, 1986Date of Patent: September 22, 1987Assignee: Stauffer Chemical CompanyInventors: Lawrence L. Buren, Donald R. James, Barney J. Randolph, Eugene G. Teach, Harry Tilles, Francis H. Walker
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Patent number: 4650516Abstract: .alpha.-Halo-.OMEGA.-haloalkylamide compounds have the following formula ##STR1## in which R is selected from the group consisting of chlorine and bromine;R.sub.1 is selected from the group consisting of chlorine and bromine, provided that it is different from R;R.sub.2 is selected from the group consisting of hydrogen and methyl; andR.sub.3 is selected from the group consisting of alkyl having 1 to 10 carbon atoms, alkynyl having 2 to 10 carbon atoms, cyanoalkyl having 2 to 10 carbon atoms, methoxy substituted cyanoalkyl having 2 to 10 carbon atoms, cyanocycloalkyl having 5 to 14 carbon atoms. The compounds are useful as antidotes for the protection of crops from herbicidal injury.Type: GrantFiled: April 28, 1980Date of Patent: March 17, 1987Assignee: Stauffer Chemical Co.Inventor: Francis H. Walker
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Patent number: 4561876Abstract: Herbicide antidote compounds having the formula: ##STR1## in which R is haloalkyl wherein halo is chlorine, bromine or iodine and the alkyl group has 1-4 carbon atoms, inclusive;R.sub.1 is selected from the group consisting of hydrogen; lower alkyl having 1-4 carbon atoms, inclusive; alkenyl having 2-4 carbon atoms, inclusive; and phenyl;R.sub.2 is selected from the group consisting of hydrogen and lower alkyl having 1-4 carbon atoms, inclusive;R.sub.3 is selected from the group consisting of hydrogen and lower alkyl having 1-4 carbon atoms, inclusive;R.sub.4 is selected from the group consisting of hydrogen and a nitro group; andeither R.sub.3 is hydrogen or R.sub.4 is hydrogen.Type: GrantFiled: June 16, 1981Date of Patent: December 31, 1985Assignee: Stauffer Chemical Co.Inventor: Francis H. Walker
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Patent number: 4548641Abstract: Compounds having the formula ##STR1## in which R is chloro, fluoro, bromo, methyl, methoxy or methylthio, and R.sub.1 and R.sub.2 are each C.sub.1 -C.sub.4 alkyl are hebicides. In one embodiment the compound is an optical isomer.Type: GrantFiled: May 25, 1983Date of Patent: October 22, 1985Assignee: Stauffer Chemical CompanyInventors: Francis H. Walker, Don R. Baker
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Patent number: 4512796Abstract: Herbicide antidote compounds having the formula: ##STR1## in which X is halomethyl, wherein halo is selected from the group consisting of chlorine, bromine, and iodine and the methyl group is mono-, di-, or tri-substituted; andR.sub.1 is selected from the group consisting of lower alkyl having 1-4 carbon atoms, inclusive, and alkenyloxy having from 2-6 carbon atoms, inclusive, provided that, if R.sub.1 is alkyl the haloacetylaminomethyl moiety is attached to the ring at the 2-position.Type: GrantFiled: May 25, 1983Date of Patent: April 23, 1985Assignee: Stauffer Chemical CompanyInventor: Francis H. Walker
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Patent number: 4415351Abstract: A method of increasing the yield of legumes (soybeans) utilizing a compound of the formula ##STR1## wherein R.sub.1 is selected from the group consisting of --CH.sub.3, --C.sub.2 H.sub.5, --C.sub.3 H.sub.7 and --C.sub.4 H.sub.9, and R.sub.2 and R.sub.3 are independently selected from the group consisting of --OCH.sub.3, --OC.sub.2 H.sub.5 and --OC.sub.3 H.sub.7.Type: GrantFiled: August 26, 1981Date of Patent: November 15, 1983Assignee: Stauffer Chemical CompanyInventors: Llewellyn W. Fancher, Francis H. Walker, Lawrence L. Buren
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Patent number: 4406686Abstract: Herbicide antidote compounds having the formula: ##STR1## in which X is halomethyl, wherein halo is selected from the group consisting of chlorine, bromine, and iodine and the methyl group is mono-, di-, or tri-substituted; andR.sub.1 is selected from the group consisting of lower alkyl having 1-4 carbon atoms, inclusive, and alkenyloxy having from 2-6 carbon atoms, inclusive, provided that, if R.sub.1 is alkyl the haloacetylaminomethyl moiety is attached to the ring at the 2-position.Type: GrantFiled: July 24, 1981Date of Patent: September 27, 1983Assignee: Stauffer Chemical CompanyInventor: Francis H. Walker
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Patent number: 4385926Abstract: A method of increasing the yield of legumes (soybeans) utilizing a compound of the formula ##STR1## wherein R is selected from the group consisting of --CH.sub.3, --C.sub.2 H.sub.5 and --C.sub.3 H.sub.7.Type: GrantFiled: August 26, 1981Date of Patent: May 31, 1983Assignee: Stauffer Chemical CompanyInventor: Francis H. Walker