Patents by Inventor Francis H. Walker

Francis H. Walker has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6291400
    Abstract: A compound of formula (I): or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X1 and X2 are independently oxygen or sulphur, R1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C2-C4 alkylene group which is optionally interposed by an oxygen atom, a group a group or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and Rb is alkyl or alkoxy; provided that when X, X1 and X2 are oxygen, R1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.
    Type: Grant
    Filed: May 27, 1999
    Date of Patent: September 18, 2001
    Assignee: Zeneca Limited
    Inventors: John E D Barton, David Cartwright, John M Cox, Glynn Mitchell, Charles G Carter, David L Lee, Francis H Walker, Frank X Woolard
  • Patent number: 5958839
    Abstract: A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group ##STR2## a group ##STR3## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.
    Type: Grant
    Filed: February 11, 1998
    Date of Patent: September 28, 1999
    Assignee: Zeneca Litmited
    Inventors: John E. D. Barton, David Cartwright, John M Cox, Glynn Mitchell, Charles G. Carter, David L Lee, Francis H Walker, Frank X. Woolard
  • Patent number: 5744610
    Abstract: A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed, by an oxygen atom, a group ##STR2## a group ##STR3## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.
    Type: Grant
    Filed: July 18, 1996
    Date of Patent: April 28, 1998
    Assignee: Zeneca Limited
    Inventors: John E. D. Barton, David Cartwright, John M. Cox, Glynn Mitchell, Charles G. Carter, David L. Lee, Francis H. Walker, Frank X. Woolard
  • Patent number: 5563115
    Abstract: A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group ##STR2## a group ##STR3## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: October 8, 1996
    Assignee: Zeneca Limited
    Inventors: John E. D. Barton, David Cartwright, John M. Cox, Glynn Mitchell, Charles G. Carter, David L. Lee, Francis H. Walker, Frank X. Woolard
  • Patent number: 5426091
    Abstract: A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group ##STR2## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.
    Type: Grant
    Filed: August 4, 1993
    Date of Patent: June 20, 1995
    Assignee: Zeneca Limited
    Inventors: John E. D. Barton, David Cartwright, John M. Cox, Glynn Mitchell, Charles G. Carter, David L. Lee, Francis H. Walker, Frank X. Woolard
  • Patent number: 5314865
    Abstract: Compounds having the formula ##STR1## wherein R is C.sub.1 -C.sub.6 lower alkoxy; C.sub.1 -C.sub.6 lower alkylthio; 3- to 6-membered heterocycle or substituted heterocycle; phenyl or substituted phenyl; R.sub.1 is hydrogen or C.sub.1 -C.sub.3 lower alkyl; R.sub.2 is selected from the group consisting of hydrogen, C.sub.1 -C.sub.3 lower alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.1 -C.sub.3 lower alkylalkoxy or combinations thereof; R.sub.3 and R.sub.4 are independently selected from the group consisting of hydrogen; C.sub.1 -C.sub.6 lower alkyl; C.sub.2 -C.sub.6 lower alkenyl; C.sub.2 -C.sub.6 lower alkenyl; 3- to 6-membered heterocycle or substituted heterocycle; alkyl heterocycle or substituted alkyl heterocycle; phenyl or substituted phenyl; and where R.sub.3 or R.sub.4 is a basic heterocycle, herbicidally acceptable organic or inorganic salts thereof are herbicidally active.
    Type: Grant
    Filed: April 10, 1992
    Date of Patent: May 24, 1994
    Assignee: ICI Americas Inc.
    Inventors: Francis H. Walker, Don R. Baker
  • Patent number: 5250501
    Abstract: A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group ##STR2## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.
    Type: Grant
    Filed: January 10, 1992
    Date of Patent: October 5, 1993
    Assignees: Imperial Chemical Industries PLC, ICI Americas, Inc.
    Inventors: John E. D. Barton, David Cartwright, John M. Cox, Glynn Mitchell, Charles G. Carter, David L. Lee, Francis H. Walker, Frank X. Woolard
  • Patent number: 5157043
    Abstract: Novel fungicidal pyridyl carboximides having the general structural formula ##STR1## wherein R is C.sub.1 -C.sub.6 alkyl, preferably methyl;R.sub.1 is selected from the group consisting of halogen such as chlorine, fluorine and bromine, C.sub.1 -C.sub.3 alkoxy such as propoxyethoxy and methoxy, preferably methoxy, and C.sub.2 -C.sub.4 alkenyloxy;R.sub.2 is selected from the group consisting of hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.4 -C.sub.6 cycloalkyl, heterocyclic moieties, aryl, preferably phenyl, substituted aryl, preferably substituted phenyl wherein the substitutions are chlorine, fluorine, bromine, trifluoromethyl and --NO.sub.3 ;X is --O or --S; andY is --O or --S;and fungicidally acceptable organic and inorganic salts thereof which are highly effective fungicides for use both as preventive and curative fungicides are disclosed herein.
    Type: Grant
    Filed: November 1, 1990
    Date of Patent: October 20, 1992
    Assignee: Imperial Chemical Industries PLC
    Inventors: Don R. Baker, Charles Kezerian, Francis H. Walker, Keith H. Brownell
  • Patent number: 5098464
    Abstract: A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group>S(O).sub.pa group ##STR2## or an optionally mono-substituted nitrogen atom, wherein p is O, 1 or 2, s is 0.sub.1 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.
    Type: Grant
    Filed: October 9, 1990
    Date of Patent: March 24, 1992
    Assignees: Imperial Chemical Industries PLC, ICI Americas, Inc.
    Inventors: John E. D. Barton, David Cartwright, John M. Cox, Glynn Mitchell, Charles G. Carter, Davie L. Lee, Francis H. Walker, Frank X. Woolard
  • Patent number: 5002605
    Abstract: Compounds having the formula ##STR1## wherein R is C.sub.1 -C.sub.6 lower alkoxy; C.sub.1 -C.sub.6 lower alkylthio; 3- to 6-membered heterocycle or substituted heterocycle; phenyl or substituted phenyl; R.sub.1 is hydrogen or C.sub.1 -C.sub.3 lower alkyl; R.sub.2 is selected from the group consisting of hydrogen, C.sub.1 -C.sub.3 lower alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.1 -C.sub.3 lower alkylalkoxy or combinations thereof; R.sub.3 and R.sub.4 are independently selected from the group consisting of hydrogen; C.sub.1 -C.sub.6 lower alkyl; C.sub.2 -C.sub.6 lower alkenyl; C.sub.2 -C.sub.6 lower alkynyl; 3- to 6-membered heterocyle or substituted heterocycle; alkyl heterocycle or substituted alkyl heterocycle; phenyl or substituted phenyl; and where R.sub.3 l or R.sub.4 is a basic heterocyle, herbicidally acceptable organic or inorganic salts thereof are herbicidally active.
    Type: Grant
    Filed: December 21, 1988
    Date of Patent: March 26, 1991
    Assignee: ICI Americas Inc.
    Inventors: Francis H. Walker, Don R. Baker
  • Patent number: 4931451
    Abstract: Novel fungicidal pyridyl sulfenyl carbamates having the formula ##STR1## wherein R is selected from the group consisting of haloalkyl, C.sub.1 -C.sub.8 alkyl, aryl, substituted aryl, arylalkyl, substituted arylalkyl, alkanoyl, alkylamino, arylamino, arylalkylamino and substituted pyridylcarbamoyl;R.sub.1 is C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy or halomethoxy; alkenyloxy; and halogen;R.sub.2 is C.sub.1 -C.sub.3 alkyl;X is oxygen or sulfur; andY is oxygen or sulfurand fungicidally acceptable organic and inorganic salts thereof which are highly effective fungicides for use both as preventive and curative fungicides are disclosed herein.
    Type: Grant
    Filed: October 17, 1988
    Date of Patent: June 5, 1990
    Assignee: ICI Americas Inc.
    Inventors: Don R. Baker, Francis H. Walker, Keith H. Brownell
  • Patent number: 4800205
    Abstract: Novel fungicidal pyridyl sulfenyl carbamates having the formula ##STR1## wherein R is selected from the group consisting of haloalkyl, C.sub.1 -C.sub.8 alkyl, aryl, substituted aryl, arylalkyl, substituted arylalkyl, alkanoyl, alkylamino, arylamino, arylalkylamino and substituted pyridylcarbamoyl;R.sub.1 is C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy or halomethoxy; alkenyloxy; and halogen;R.sub.2 is C.sub.1 -C.sub.3 alkyl;X is oxygen or sulfur; andY is oxygen or sulfurand fungicidally acceptable organic and inorganic salts thereof which are highly effective fungicides for use both as preventive and curative fungicides are disclosed herein.
    Type: Grant
    Filed: October 29, 1987
    Date of Patent: January 24, 1989
    Inventors: Don R. Baker, Francis H. Walker, Keith H. Brownell
  • Patent number: 4695314
    Abstract: Novel S-benzyl thiolcarbamates are disclosed, having the formula ##STR1## in which R.sup.1 is selected from the group consisting of hydrogen and methoxy,R.sup.2 is selected from the group consisting of methyl, ethyl, and allyl, andR.sup.3 is selected from the group consisting of straight-chain C.sub.3 -C.sub.6 alkyl optionally substituted with one or two methyl groups, and allyl.The compounds are particularly effective in the control of weeds associated with rice crops.
    Type: Grant
    Filed: April 28, 1986
    Date of Patent: September 22, 1987
    Assignee: Stauffer Chemical Company
    Inventors: Lawrence L. Buren, Donald R. James, Barney J. Randolph, Eugene G. Teach, Harry Tilles, Francis H. Walker
  • Patent number: 4650516
    Abstract: .alpha.-Halo-.OMEGA.-haloalkylamide compounds have the following formula ##STR1## in which R is selected from the group consisting of chlorine and bromine;R.sub.1 is selected from the group consisting of chlorine and bromine, provided that it is different from R;R.sub.2 is selected from the group consisting of hydrogen and methyl; andR.sub.3 is selected from the group consisting of alkyl having 1 to 10 carbon atoms, alkynyl having 2 to 10 carbon atoms, cyanoalkyl having 2 to 10 carbon atoms, methoxy substituted cyanoalkyl having 2 to 10 carbon atoms, cyanocycloalkyl having 5 to 14 carbon atoms. The compounds are useful as antidotes for the protection of crops from herbicidal injury.
    Type: Grant
    Filed: April 28, 1980
    Date of Patent: March 17, 1987
    Assignee: Stauffer Chemical Co.
    Inventor: Francis H. Walker
  • Patent number: 4561876
    Abstract: Herbicide antidote compounds having the formula: ##STR1## in which R is haloalkyl wherein halo is chlorine, bromine or iodine and the alkyl group has 1-4 carbon atoms, inclusive;R.sub.1 is selected from the group consisting of hydrogen; lower alkyl having 1-4 carbon atoms, inclusive; alkenyl having 2-4 carbon atoms, inclusive; and phenyl;R.sub.2 is selected from the group consisting of hydrogen and lower alkyl having 1-4 carbon atoms, inclusive;R.sub.3 is selected from the group consisting of hydrogen and lower alkyl having 1-4 carbon atoms, inclusive;R.sub.4 is selected from the group consisting of hydrogen and a nitro group; andeither R.sub.3 is hydrogen or R.sub.4 is hydrogen.
    Type: Grant
    Filed: June 16, 1981
    Date of Patent: December 31, 1985
    Assignee: Stauffer Chemical Co.
    Inventor: Francis H. Walker
  • Patent number: 4548641
    Abstract: Compounds having the formula ##STR1## in which R is chloro, fluoro, bromo, methyl, methoxy or methylthio, and R.sub.1 and R.sub.2 are each C.sub.1 -C.sub.4 alkyl are hebicides. In one embodiment the compound is an optical isomer.
    Type: Grant
    Filed: May 25, 1983
    Date of Patent: October 22, 1985
    Assignee: Stauffer Chemical Company
    Inventors: Francis H. Walker, Don R. Baker
  • Patent number: 4512796
    Abstract: Herbicide antidote compounds having the formula: ##STR1## in which X is halomethyl, wherein halo is selected from the group consisting of chlorine, bromine, and iodine and the methyl group is mono-, di-, or tri-substituted; andR.sub.1 is selected from the group consisting of lower alkyl having 1-4 carbon atoms, inclusive, and alkenyloxy having from 2-6 carbon atoms, inclusive, provided that, if R.sub.1 is alkyl the haloacetylaminomethyl moiety is attached to the ring at the 2-position.
    Type: Grant
    Filed: May 25, 1983
    Date of Patent: April 23, 1985
    Assignee: Stauffer Chemical Company
    Inventor: Francis H. Walker
  • Patent number: 4415351
    Abstract: A method of increasing the yield of legumes (soybeans) utilizing a compound of the formula ##STR1## wherein R.sub.1 is selected from the group consisting of --CH.sub.3, --C.sub.2 H.sub.5, --C.sub.3 H.sub.7 and --C.sub.4 H.sub.9, and R.sub.2 and R.sub.3 are independently selected from the group consisting of --OCH.sub.3, --OC.sub.2 H.sub.5 and --OC.sub.3 H.sub.7.
    Type: Grant
    Filed: August 26, 1981
    Date of Patent: November 15, 1983
    Assignee: Stauffer Chemical Company
    Inventors: Llewellyn W. Fancher, Francis H. Walker, Lawrence L. Buren
  • Patent number: 4406686
    Abstract: Herbicide antidote compounds having the formula: ##STR1## in which X is halomethyl, wherein halo is selected from the group consisting of chlorine, bromine, and iodine and the methyl group is mono-, di-, or tri-substituted; andR.sub.1 is selected from the group consisting of lower alkyl having 1-4 carbon atoms, inclusive, and alkenyloxy having from 2-6 carbon atoms, inclusive, provided that, if R.sub.1 is alkyl the haloacetylaminomethyl moiety is attached to the ring at the 2-position.
    Type: Grant
    Filed: July 24, 1981
    Date of Patent: September 27, 1983
    Assignee: Stauffer Chemical Company
    Inventor: Francis H. Walker
  • Patent number: 4385926
    Abstract: A method of increasing the yield of legumes (soybeans) utilizing a compound of the formula ##STR1## wherein R is selected from the group consisting of --CH.sub.3, --C.sub.2 H.sub.5 and --C.sub.3 H.sub.7.
    Type: Grant
    Filed: August 26, 1981
    Date of Patent: May 31, 1983
    Assignee: Stauffer Chemical Company
    Inventor: Francis H. Walker