Patents by Inventor Francis P. McCullough, Jr.

Francis P. McCullough, Jr. has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5858530
    Abstract: A flexible, ignition resistant, biregional fiber is disclosed, wherein the fiber is preferably derived from a single homogeneous polymeric precursor composition, said biregional fiber comprising an inner core region of a thermoplastic polymeric composition and a surrounding outer sheath region of a thermoset carbonaceous material. The biregional fiber is particularly characterized by having a ratio of the radius of the core region with respect to the total radius of the fiber (r:R) of from about 1:4 to about 1:1.05, an LOI value of greater than 40, a breaking twist angle of from 4 to 13 degrees, and a bending strain value of from greater than 0.01 to less than 50%.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: January 12, 1999
    Inventor: Francis P. McCullough, Jr.
  • Patent number: 5582908
    Abstract: A process for preparing an ignition resistant carbonaceous material by exposing a meltblown or spunbonded acrylic precursor material in the form of at least one ply of a generally planar fibrous web, matt or batt to ionizing radiation to crosslink said acrylic material which is then heat treated in an inert atmosphere to increase the carbon content of said irradiated material to form said carbonaceous material. The invention also resides in a continuous self bonded fibrous carbonaceous material having a carbon content of from about 65% to less than about 92%, an oxygen content of less than about 2%, and a specific resistivity of from about 10.sup.-1 to about 10.sup.10 ohm-cm. Preferably said carbonaceous material has an oxygen content of less than about 1% and a nitrogen content of from about 5% to about 30%.
    Type: Grant
    Filed: November 3, 1995
    Date of Patent: December 10, 1996
    Assignee: The Dow Chemical Company
    Inventor: Francis P. McCullough, Jr.
  • Patent number: 5582912
    Abstract: The present invention resides in ignition resistant non-linear carbonaceous fiber or fiber tow having a reversible deflection ratio of greater than 1:1 but equal to or less than 1.2:1. The fibers have a multiplicity of crimps along their length with a crimp frequency on the order of from 6 to 15 crimps per inch. Fibers of the invention have an elongatability of from about 2 to about 9%, a pseudo-elongatability of from about 0.2 to about 18%, and a tenacity without a loss of elongation on the order of at least 6 g/d. The carbonaceous fibers can be used, for example, as thermal insulation and/or fire resistant insulation in vehicles, building structures or clothing in furniture coverings, carpets, and the like, and can be used alone or blended with other fibers to form fine yarns.
    Type: Grant
    Filed: May 3, 1994
    Date of Patent: December 10, 1996
    Assignee: The Dow Chemical Company
    Inventors: Francis P. McCullough, Jr., Stephen E. Hill, Bhuvenesh C. Goswami
  • Patent number: 5509986
    Abstract: A process for preparing an ignition resistant carbonaceous material by exposing a meltblown or spunbonded acrylic precursor material in the form of at least one ply of a generally planar fibrous web, matt or batt to ionizing radiation to crosslink said acrylic material which is then heat treated in an inert atmosphere to increase the carbon content of said irradiated material to form said carbonaceous material. The invention also resides in a continuous self bonded fibrous carbonaceous material having a carbon content of from about 65% to less than about 92%, an oxygen content of less than about 2%, and a specific resistivity of from about 10.sup.-1 to about 10.sup.-10 ohm-cm. Preferably said carbonaceous material has an oxygen content of less than about 1% and a nitrogen content of from about 5% to about 30%.
    Type: Grant
    Filed: August 22, 1994
    Date of Patent: April 23, 1996
    Assignee: The Dow Chemical Company
    Inventor: Francis P. McCullough, Jr.
  • Patent number: 5503929
    Abstract: A process for preparing a non-flammable linear non-graphitic carbonaceous polymeric fiber, yarn or tow having improved elongability containing the step of heat treating a linear stabilized polymeric fiber, yarn or tow having an LOI greater than 40 without any substantial tension or stress in an inert non-oxidizing atmosphere at a temperature so as to irreversibly heat set said fiber yarn or tow.
    Type: Grant
    Filed: May 3, 1994
    Date of Patent: April 2, 1996
    Inventors: Francis P. McCullough, Jr., R. Vernon Snelgrove, Bhuvenesh C. Goswami
  • Patent number: 5384193
    Abstract: There is provided a non-flammable expanded fiber comprising carbonaceous polymeric substantially irreversibly heat set fiber having an LOI value of greater than 40, and the fibrous structures thereof. Also, provided are stabilized expanded polymeric fibers.
    Type: Grant
    Filed: March 28, 1994
    Date of Patent: January 24, 1995
    Assignee: The Dow Chemical Company
    Inventors: Kyung W. Suh, William G. Stobby, Francis P. McCullough, Jr.
  • Patent number: 5356707
    Abstract: The present invention resides in ignition resistant non-linear carbonaceous fiber or fiber tow having a reversible deflection ratio equal to or less than 1.2:1. The fibers have a multiplicity of crimps along their length with a crimp frequency on the order of from 6 to 15 crimps per inch. Fibers of the invention have improved elongatability of from about 2 to about 9%, a pseudo-elongatability of from about 0.2 to about 18%, and a tenacity without a loss of elongation on the order of at least 6 g/d. The carbonaceous fibers can be used, for example, as thermal insulation and/or fire resistant insulation in vehicles, building structures or clothing in furniture coverings, carpets, and the like, and can be blended with other fibers to form fine yarns.
    Type: Grant
    Filed: March 5, 1993
    Date of Patent: October 18, 1994
    Assignee: The Dow Chemical Company
    Inventors: Francis P. McCullough, Jr., Bhuvenesh C. Goswami, Stephen E. Hill
  • Patent number: 5328764
    Abstract: A process for preparing a non-flammable linear non-graphitic carbonaceous polymeric fiber, yarn or tow having improved elongability which comprises the step of heat treating a linear stabilized polymeric fiber, yarn or tow having an LOI greater than 40 without any substantial tension or stress in an inert non-oxidizing atmosphere at a temperature so as to irreversibly heat set said fiber yarn or tow.
    Type: Grant
    Filed: April 30, 1992
    Date of Patent: July 12, 1994
    Assignee: The Dow Chemical Company
    Inventors: Francis P. McCullough, Jr., R. Vernon Snelgrove, Bhuvenesh C. Goswami
  • Patent number: 5312678
    Abstract: A structure is provided comprising carbonaceous materials for absorbing and/or reflecting radiated energy or electromagnetic energy. The structure is useful for camouflage or for shielding electromagnetic radiation, especially microwaves.
    Type: Grant
    Filed: October 6, 1989
    Date of Patent: May 17, 1994
    Assignee: The Dow Chemical Company
    Inventors: Francis P. McCullough, Jr., Leo R. Novak, David M. Hall
  • Patent number: 5264137
    Abstract: An improvement in an apparatus for separating fluids or non-biotechnological products in solution, wherein said apparatus has a fibrous element which permits flow of fluids therethrough and is composed of irreversibly set non-graphitic carbonaceous fibers having an LOI greater than 40.
    Type: Grant
    Filed: June 8, 1992
    Date of Patent: November 23, 1993
    Assignee: The Dow Chemical Company
    Inventors: Francis P. McCullough, Jr., Stuart D. Stein
  • Patent number: 5223324
    Abstract: A flame retardant polymeric foam having a flame retarding amount of non-graphitic carbonaceous materials having an LOI value greater than 40.
    Type: Grant
    Filed: July 21, 1989
    Date of Patent: June 29, 1993
    Assignee: The Dow Chemical Company
    Inventors: Francis P. McCullough, Jr., Bhuvenesh C. Goswami, R. Vernon Snelgrove
  • Patent number: 5151198
    Abstract: An improvement in an apparatus for separating fluids or non-biotechnological products in solution, wherein said apparatus has a fibrous element which permits flow of fluids therethrough the improvement wherein the fibrous element is composed of non-flammable irreversibly heat set non-graphitic carbonaceous fibers having an LOI greater than 40.
    Type: Grant
    Filed: September 11, 1990
    Date of Patent: September 29, 1992
    Assignee: The Dow Chemical Company
    Inventors: Francis P. McCullough, Jr., Stuart D. Stein
  • Patent number: 5068061
    Abstract: A composition comprising a thermoplastic electroconductive resin matrix containing a multiplicity of reinforcing carbonaceous fibers, the improvement which comprises said reinforcing fibers comprising resilient shaped reforming elongatable non-linear non-flammable conductive carbonaceous fibers, the fibers having a reversible deflection ratio of greater than 1.2:1 and an aspect ratio (1/d) of greater than 10:1.
    Type: Grant
    Filed: December 8, 1989
    Date of Patent: November 26, 1991
    Assignee: The Dow Chemical Company
    Inventors: Thomas M. Knobel, Francis P. McCullough, Jr., Lance L. Black
  • Patent number: 5034267
    Abstract: A thermally stable metal coated carbonaceous fiber batting, fiber tow, yarn or fabric which maintains loft, has some degree of resiliency and some degree of stability in the presence of various concentrations of oxygen at elevated temperatures said fibers having a reversible deflection ratio of greater than 1.2:1 and an aspect ratio greater than 10:1.
    Type: Grant
    Filed: June 14, 1989
    Date of Patent: July 23, 1991
    Assignee: The Dow Chemical Company
    Inventors: Francis P. McCullough, Jr., Steven L. Brewster, R. Vernon Snelgrove, George C. Higgins
  • Patent number: 5030509
    Abstract: A thermally stable ceramic and/or metal coated carbonaceous linear fiber batting, fiber tow, yarn or fabric which maintains some degree of stability in the presence of various concentrations of oxygen at elevated temperatures.
    Type: Grant
    Filed: July 27, 1989
    Date of Patent: July 9, 1991
    Assignee: The Dow Chemical Company
    Inventors: Francis P. McCullough, Jr., Steven L. Brewster, R. Vernon Snelgrove, George C. Higgins
  • Patent number: 5028477
    Abstract: A thermally stable ceramic coated carbonaceous fiber batting, fiber tow, yarn or fabric which maintains loft, has some degree of resiliency and some degree of stability in the presence of various concentrations of oxygen at elevated temperatures said fibers having a reversible deflection ratio of greater than 1.2:1 and an aspect ratio greater than 10:1.
    Type: Grant
    Filed: June 14, 1989
    Date of Patent: July 2, 1991
    Assignee: The Dow Chemical Company
    Inventors: Francis P. McCullough, Jr., R. Vernon Snelgrove, Steven L. Brewster, George C. Higgins
  • Patent number: 5024877
    Abstract: A means for improving the fire resistance of carbonaceous polymeric substance comprising a non-graphitic carbonaceous polymeric material having an LOI value greater than 40, produces a char formation greater than 65% and a thermoconductivity less than 1 BTU ft/Hr ft.sup.2 .degree.F. by utilizing an organosilicone polymer in an amount to provide ignition resistance. Also, there is provided a means for improving the fire resistance and thermal stability of resins and polymers.
    Type: Grant
    Filed: February 14, 1990
    Date of Patent: June 18, 1991
    Assignee: The Dow Chemical Company
    Inventors: Francis P. McCullough, Jr., R. Vernon Snelgrove, David M. Hall
  • Patent number: 5015522
    Abstract: A multicomponent polymeric fiber, film or foam having at least one component comprising fire resistant carbonaceous material and another component comprising non-carbonaceous material.
    Type: Grant
    Filed: September 5, 1990
    Date of Patent: May 14, 1991
    Assignee: The Dow Chemical Company
    Inventors: Francis P. McCullough, Jr., R. Vernon Snelgrove, David M. Hall
  • Patent number: 4999385
    Abstract: A flame-retardant polymeric foam which comprises a carbonaceous irreversibly heat set, cellular polymer derived from a stabilized polyacrylonitrile based foam.
    Type: Grant
    Filed: February 6, 1990
    Date of Patent: March 12, 1991
    Assignee: The Dow Chemical Company
    Inventors: Francis P. McCullough, Jr., David M. Hall, William G. Stobby, Kyung W. Suh
  • Patent number: 4999236
    Abstract: The invention relates to improvements in hot air balloons and the like. An insulation of carbonaceous fibers is provided on the interior of the balloon's envelope and/or the skirt, nozzle or scoop which is light weight and provides flame and scortch protection.
    Type: Grant
    Filed: June 8, 1989
    Date of Patent: March 12, 1991
    Assignee: The Dow Chemical Company
    Inventors: Francis P. McCullough, Jr., Robert L. Matoy