Patents by Inventor Franco Codignola

Franco Codignola has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7341666
    Abstract: A poly-?-carboxyacrylamide polymer of formula (I) wherein X is an alkaline metal or a substituent capable of bringing about an exchange reaction with a salt of an alkaline earth metal, said polymer having a ponderal average molecular weight greater than or equal to 2,000.
    Type: Grant
    Filed: March 27, 2002
    Date of Patent: March 11, 2008
    Assignee: Eurotecnica Contractors & Engineers S.p.A.
    Inventor: Franco Codignola
  • Patent number: 7335797
    Abstract: This invention refers to a process for the synthesis of cumene hydroperoxide and to the product thus obtained. More in particular, this invention refers to a process for the production of cumene hydroperoxide by oxidating cumene with oxygen, where this process is run in the presence of a basic medium insoluble in the reaction environment, and such as not to release inorganic cations to the reaction environment. Such a basic medium is preferably a pyridinic resin. The cumene hydroperoxide thus obtained, characterized by the fact of being free of inorganic cations, is a further object of the invention.
    Type: Grant
    Filed: March 14, 2002
    Date of Patent: February 26, 2008
    Assignee: Eurotechnica Development & Licensing S.p.A.
    Inventor: Franco Codignola
  • Patent number: 7314957
    Abstract: Compounds are described, having the following general formula (A) R(CONH—CHR10H)m (A) and their use as monomers in polymerization and polycondensation reactions.
    Type: Grant
    Filed: April 8, 2003
    Date of Patent: January 1, 2008
    Assignee: Eurotecnica Contractors & Engineers S.p.A.
    Inventor: Franco Codignola
  • Patent number: 7084309
    Abstract: This invention refers to a process for the synthesis of phenol and acetone starting from cumene hydroperoxide, and to a plant specifically developed for performing this process. More in particular, this invention refers to a process for the synthesis of phenol and acetone starting from cumene hydroperoxide, comprising the following steps: a) Pretreating of the starting cumene hydroperoxide with acidic resins, to obtain cumene hydroperoxide free of inorganic cations; b) Decomposing of the cumene hydroperoxide free of inorganic cations originating from the step (a) in the presence of acidic resins, to yield phenol and acetone.
    Type: Grant
    Filed: March 14, 2002
    Date of Patent: August 1, 2006
    Assignee: Eurotecnica Development & Licensing S.p.A.
    Inventor: Franco Codignola
  • Publication number: 20060014985
    Abstract: This invention refers to a process for the synthesis of cumene hydroperoxide and to the product thus obtained. More in particular, this invention refers to a process for the production of cumene hydroperoxide by oxidating cumene with oxygen, where this process is run in the presence of a basic medium insoluble in the reaction environment, and such as not to release inorganic cations to the reaction environment. Such a basic medium is preferably a pyridinic resin. The cumene hydroperoxide thus obtained, characterized by the fact of being free of inorganic cations, is a further object of the invention.
    Type: Application
    Filed: March 14, 2002
    Publication date: January 19, 2006
    Inventor: Franco Codignola
  • Publication number: 20050218079
    Abstract: A poly-?-carboxyacrylamide polymer of formula (I) wherein X is an alkaline metal or a substituent capable of bringing about an exchange reaction with a salt of an alkaline earth metal, said polymer having a ponderal average molecular weight greater than or equal to 2,000. The use of said polymer and process for preparing the same.
    Type: Application
    Filed: March 27, 2002
    Publication date: October 6, 2005
    Inventor: Franco Codignola
  • Publication number: 20050215761
    Abstract: Compounds are described, having the following general formula (A) R(CONH—CHR10H)m (A) and their use as monomers in polymerization and polycondensation reactions.
    Type: Application
    Filed: April 8, 2003
    Publication date: September 29, 2005
    Inventor: Franco Codignola
  • Publication number: 20050177004
    Abstract: This invention refers to a process for the synthesis of phenol and acetone starting from cumene hydroperoxide, and to a plant specifically developed for performing this process. More in particular, this invention refers to a process for the synthesis of phenol and acetone starting from cumene hydroperoxide, comprising the following steps: a) Pretreating of the starting cumene hydroperoxide with acidic resins, to obtain cumene hydroperoxide free of inorganic cations; b) Decomposing of the cumene hydroperoxide free of inorganic cations originating from the step (a) in the presence of acidic resins, to yield phenol and acetone.
    Type: Application
    Filed: March 14, 2002
    Publication date: August 11, 2005
    Inventor: Franco Codignola
  • Patent number: 6833472
    Abstract: A novel process for the purification of crude aromatic carboxylic acids, such as, for example, terephthalic acid, orthophthalic acid, trimesic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid and pyromellitic acid, which are obtained by oxidising the corresponding aromatic precursors is described; the process is based on the subsequent oxidation in heterogeneous phase of the crude product in aqueous solution.
    Type: Grant
    Filed: January 9, 2003
    Date of Patent: December 21, 2004
    Assignee: Eurotecnica Development and Licensing SpA
    Inventor: Franco Codignola
  • Patent number: 6761860
    Abstract: A description is given here of a novel process for the production of monocarboxylic and polycarboxylic aromatic acids by the catalytic oxidation in homogeneous phase of aromatic compounds carrying at least one oxidizable substituent group attached directly to the carbon atom of the corresponding aromatic nucleus. The novel process according to the present invention comprises the steps of: a) catalytically oxidizing the corresponding aromatic precursors in liquid phase in the presence of gaseous oxygen; b) filtering the end product; c) recycling into the oxidation reactor at least part of the mother liquors resulting from the filtration stage, and is characterized by the fact that said steps from (a) to (c) are carried out in a closed and continuous cycle operating substantially under the same pressure and temperature conditions, preferably at 2-10 barg and 100-140° C.
    Type: Grant
    Filed: June 3, 2002
    Date of Patent: July 13, 2004
    Inventors: Franco Codignola, Antonio Moro
  • Patent number: 6670502
    Abstract: Process for producing mono- and poly-carboxylic aromatic acids wherein an aromatic compound having at least one oxidizable substituent directly linked to the carbon atom of the corresponding aromatic nucleus is oxidized in the presence of a catalyst system in the liquid homogenous phase. The oxidation reaction is carried out in aqueous acetic acid, and the catalyst system consists of a combination of cobalt and zirconium organic salts. The oxidation reaction is carried out at an absolute pressure lower than 10 bar and at a temperature of 90-150° C.
    Type: Grant
    Filed: September 28, 2000
    Date of Patent: December 30, 2003
    Inventor: Franco Codignola
  • Publication number: 20030181755
    Abstract: A novel process for the purification of crude aromatic carboxylic acids, such as, for example, terephthalic acid, orthophthalic acid, trimesic acid, isophthalic acid, 2,6-naptlithalenedicarboxylic acid and pyromellitic acid, which are obtained by oxidising the corresponding aromatic precursors is described; the process is based on the subsequent oxidation in heterogeneous phase of the crude product in aqueous solution.
    Type: Application
    Filed: January 9, 2003
    Publication date: September 25, 2003
    Inventor: Franco Codignola
  • Patent number: 6565754
    Abstract: A description is given here of a novel process for the production of monocarboxylic and polycarboxylic aromatic acids by the catalytic oxidation in homogeneous phase of aromatic compounds carrying at least one oxidizable substituent group attached directly to the carbon atom of the corresponding aromatic nucleus. The process comprises a purification step in which the crude product resulting from the oxidation stage is supplied to a filling column containing a bed of material having a high adsorbent power with respect to hafnium and/or zirconium polyoxides, operating at a temperature of from 200 to 300° C. and at a pressure of from 30 to 90 barg.
    Type: Grant
    Filed: November 15, 2001
    Date of Patent: May 20, 2003
    Inventors: Franco Codignola, Antonio Moro
  • Patent number: 6521786
    Abstract: A description is given here of a novel process for the production of monocarboxylic and polycarboxylic aromatic acids by the catalytic oxidation in homogeneous phase of aromatic compounds carrying at least one oxidizable substituent group attached directly to the carbon atom of the corresponding aromatic nucleus. The novel process according to the present invention comprises the steps of: a) catalytically oxidizing the corresponding aromatic precursors in liquid phase in the presence of gaseous oxygen; b) filtering the end product; c) recycling into the oxidation reactor at least part of the mother liquors resulting from the filtration stage, and is characterized by the fact that said steps from (a) to (c) are carried out in a closed and continuous cycle operating substantially under the same pressure and temperature conditions, preferably at 2-10 barg and 100-140° C.
    Type: Grant
    Filed: August 8, 2001
    Date of Patent: February 18, 2003
    Inventors: Franco Codignola, Antonio Moro
  • Publication number: 20020188155
    Abstract: A description is given here of a novel process for the production of monocarboxylic and polycarboxylic aromatic acids by the catalytic oxidation in homogeneous phase of aromatic compounds carrying at least one oxidizable substituent group attached directly to the carbon atom of the corresponding aromatic nucleus. The novel process according to the present invention comprises the steps of: a) catalytically oxidizing the corresponding aromatic precursors in liquid phase in the presence of gaseous oxygen; b) filtering the end product; c) recycling into the oxidation reactor at least part of the mother liquors resulting from the filtration stage, and is characterized by the fact that said steps from (a) to (c) are carried out in a closed and continuous cycle operating substantially under the same pressure and temperature conditions, preferably at 2-10 barg and 100-140° C.
    Type: Application
    Filed: June 3, 2002
    Publication date: December 12, 2002
    Inventors: Franco Codignola, Antonio Moro
  • Patent number: 6160170
    Abstract: Process for producing mono- and poly-carboxylic aromatic acids by oxidation of the corresponding precursors with molecular oxygen and/or air in the presence of a catalytic complex formed by a combination of at least one metal selected from ruthenium, iridium, platinum and palladium, and/or at least one metal of Group VIIA, principally rhenium; and/or cerium, and B at least one metal belonging IVA of the periodic table of elements, principally zirconium and/or hafnium.
    Type: Grant
    Filed: June 25, 1999
    Date of Patent: December 12, 2000
    Inventor: Franco Codignola
  • Patent number: 5936121
    Abstract: An oligomer of an aspartic acid is provided having repeating monomeric units of aspartic acid of the formula: ##STR1## and by a first chain unit having formula: ##STR2## and a chain stopper unit A which is: ##STR3## wherein X is an alkali metal, R represents H or an alkyl containing from 1 to 4 carbon atoms and R.sub.1 is H or the group --COOX.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: August 10, 1999
    Assignee: Sisas Societa' Italiana Serie Acetica E Sintetica Spa
    Inventors: Davino Gelosa, Roberto Ruggieri, Andrea Sliepcevich, Franco Codignola
  • Patent number: 4542254
    Abstract: There is provided a process for the separation of aromatic hydrocarbons mixtures into single components, in which the mixtures in vapor phase pass onto an adsorption bed formed by a potassium-exchanged Y zeolite, which is preventively saturated with desorbent vapors. According to the invention the desorbent used is isopropylbenzene in vapor phase. This facilitates the quick separation of the pure components, with the exception of the presence of desorbent. The process according to this invention is quicker in comparison to traditional ones. It requires the use of lower charges of desorbent and allows the separation of single pure components of the mixtures. It especially improves the paraxylene separation in higher concentrations with respect to the desorbent.
    Type: Grant
    Filed: May 3, 1983
    Date of Patent: September 17, 1985
    Assignee: Sisassocieta Italianaserie Acetica Sintetica
    Inventors: Elio Santacesaria, Franco Codignola, Davino Gelosa, Sergio Carra'
  • Patent number: 4438285
    Abstract: A process for producing 1-4 butanediol comprising reacting 1-4 butynediol with hydrogen in the presence of a catalyst comprising ruthenium and palladium in a weight ratio of about 4:1, at a temperature of from 60.degree. to 180.degree. C. and at a pressure of between 1 to 50 bars.
    Type: Grant
    Filed: November 12, 1981
    Date of Patent: March 20, 1984
    Assignee: S.I.S.A.S. Societa Italina Serie Acetica Sintetica S.p.A.
    Inventor: Franco Codignola
  • Patent number: 4420634
    Abstract: The invention relates to a process for the oxidation of unsaturated hydrocarbons, particularly butenes and isobutylene, for the production of acetic acid, propionic acid and acetone. Specifically the invention comprises the highly selective oxidation of an unsaturated hydrocarbon or of a mixture of unsaturated hydrocarbons in the presence of a catalyst consisting of a complex of trivalent cobalt and of a carbonyl compound, of the aldehydic or ketonic type.
    Type: Grant
    Filed: December 8, 1980
    Date of Patent: December 13, 1983
    Inventors: Franco Codignola, Paolo Gronchi, Renato del Rosso, Paolo Centola