Patents by Inventor Francois L'Eplattenier
Francois L'Eplattenier has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4327212Abstract: The isoindoline-azine nickel complex of the formula ##STR1## colors plastics, lacquers and printing inks in yellow shades of outstanding fastness properties.Type: GrantFiled: May 19, 1980Date of Patent: April 27, 1982Assignee: Ciba-Geigy CorporationInventors: Paul Lienhard, Francois L'Eplattenier
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Patent number: 4237286Abstract: Metal complexes of azomethines of the formula ##STR1## are useful for coloring plastics and lacquers in yellow to red shades of excellent fastness properties.Type: GrantFiled: October 26, 1978Date of Patent: December 2, 1980Assignee: Ciba-Geigy CorporationInventors: Francois L'Eplattenier, Andre Pugin, Jost von der Crone
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Patent number: 4237292Abstract: Metal complexes of azomethines of the formula ##STR1## are useful for coloring plastics and lacquers in yellow to red shades of excellent fastness properties.Type: GrantFiled: October 26, 1978Date of Patent: December 2, 1980Assignee: Ciba-Geigy CorporationInventors: Francois L'Eplattenier, Andre Pugin, Jost von der Crone
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Patent number: 4237293Abstract: Metal complexes of azomethines of the formula ##STR1## are useful for coloring plastics and lacquers in yellow to red shades of excellent fastness properties.Type: GrantFiled: October 26, 1978Date of Patent: December 2, 1980Assignee: Ciba-Geigy CorporationInventors: Francois L'Eplattenier, Andre Pugin, Jost von der Crone
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Patent number: 4144258Abstract: 1:1-Metal complexes of azomethines of the formula I ##STR1## wherein A and B are isocyclic or heterocyclic aromatic radicals, with however only one of the radicals A and B being a benzene ring, R represents a hydrogen atom, an alkyl group containing 1 to 6 carbon atoms, or an aryl radical, and the complexing metal ions are bivalent cations of the transition metals, zinc ions or cadmium ions which are useful for pigmenting high molecular organic material.Type: GrantFiled: October 11, 1977Date of Patent: March 13, 1979Assignee: Ciba-Geigy CorporationInventors: Francois L'Eplattenier, Laurent Vuitel
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Patent number: 4132708Abstract: Metal complexes of azomethines of the formula ##STR1## are useful for coloring plastics and lacquers in yellow to red shades of excellent fastness properties.Type: GrantFiled: March 3, 1977Date of Patent: January 2, 1979Assignee: Ciba-Geigy CorporationInventors: Francois L'Eplattenier, Andre Pugin, Jost VON DER Crone
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Patent number: 4111947Abstract: Metal complexes of azomethines of the formula ##STR1## are useful for coloring plastics and lacquers in yellow to red shades of excellent fastness properties.Type: GrantFiled: March 1, 1977Date of Patent: September 5, 1978Assignee: Ciba-Geigy CorporationInventors: Francois L'Eplattenier, Andre Pugin, Jost VON DER Crone
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Patent number: 4097484Abstract: Mixed complexes of methine dyes of formula ##STR1## wherein M.sub.1 represents zinc, cadmium, lead or manganese, M.sub.2 represents cobalt, copper or nickel, R represents an organic radical, Z.sub.1 represents an oxygen or a sulphur atom or an imino group, X.sub.1 and Y.sub.1 represent hydrogen or halogen atoms, alkyl, alkoxy, alkoxycarbonyl, alkylsulphonyl or alkylcarbamoyl groups of 1 to 6 carbon atoms, nitro, carbamoyl or arylcarbamoyl groups, or the radicals X.sub.1 and Y.sub.1 form a fused benzene ring, X represents a hydrogen atom, Y represents a halogen atom and Z represents a nitro group or a group of formula R.sub.1 Y.sub.2 --, wherein R.sub.1 represents a hydrogen atom, an alkyl or cycloalkyl group of 1 to 6 carbon atoms, an aralkyl or aryl group, and Y.sub.2 represents an oxygen or a sulphur atom, m is 0 to 4, n is 0 to 4, p is 0 to 3, and the sum of m+n+p must be 4, and wherein the atomic ratio of M.sub.1 :M.sub.Type: GrantFiled: October 6, 1975Date of Patent: June 27, 1978Assignee: Ciba-Geigy CorporationInventors: Alexander von Zelewsky, Christoph Frey, Francois L'Eplattenier
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Patent number: 4065481Abstract: 1:1-Metal complexes of azomethines of the formula I ##STR1## wherein A and B are isocyclic or heterocyclic aromatic radicals, with however only one of the radicals A and B being a benzene ring, R represents a hydrogen atom, an alkyl group containing 1 to 6 carbon atoms, or an aryl radical, and the complexing metal ions are bivalent cations of the transition metals, zinc ions or cadmium ions which are useful for pigmenting high molecular organic material.Type: GrantFiled: December 12, 1975Date of Patent: December 27, 1977Assignee: Ciba-Geigy CorporationInventors: Francois L'Eplattenier, Laurent Vuitel
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Patent number: 4044036Abstract: 1:1 metal complexes of bis-azomethines of the formula ##STR1## wherein R denotes an alkylene radical which contains 2-8 C atoms and is optionally interrupted by hetero-atoms, X denotes a H or halogen atom or an alkyl, alkoxy, carboxyl, alkoxy-carbonyl or phenylazo group and Y and Z denote H or halogen atoms, or wherein the substituents Y and Z form a fused benzene ring, if R contains a hetero-atom, Y and Z must not be H atoms, and if R contains 2 C atoms, X, Y and Z must not be H atoms, and a metal are valuable pigments coloring plastics and printing inks in fast yellow to range shades.Type: GrantFiled: September 9, 1974Date of Patent: August 23, 1977Assignee: Ciba-Geigy CorporationInventors: Stefan Hari, Alexander McHugh Irvine, James McGeachie McCrae, Laurent Vuitel, Francois L'Eplattenier
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Patent number: 4024132Abstract: Azomethine pigments of the formula ##STR1## and metal complexes thereof, wherein A denotes an isocyclic or heterocyclic aromatic radical, R denotes a H atom, an alkyl group containing 1-6 C atoms, or an aryl radical, X.sub.2 and X.sub.4 denote H atoms or halogen atoms, X.sub.1 and X.sub.3 denote H atoms or halogen atoms, alkoxy or alkylmercapto groups containing 1-6 C atoms, cycloalkoxy groups containing 5-6 C atoms, or aralkoxy, aryloxy or arylmercapto groups, it being possible for one of the substituents X.sub.1 -X.sub.4 also to be a nitro group which are useful for pigmenting of high molecular material.Type: GrantFiled: June 7, 1976Date of Patent: May 17, 1977Assignee: Ciba-Geigy CorporationInventors: Francois L'Eplattenier, Andre Pugin, Laurent Vuitel
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Patent number: 4022770Abstract: Metal complexes of azomethines of the formula ##STR1## are useful for coloring plastics and lacquers in yellow to red shades of excellent fastness properties.Type: GrantFiled: January 30, 1975Date of Patent: May 10, 1977Assignee: Ciba-Geigy CorporationInventors: Francois L'Eplattenier, Andre Pugin, Jost VON DER Crone
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Patent number: 4016157Abstract: Bis-hydrazone metal complexes of the formula ##STR1## wherein A denotes an isocyclic or heterocyclic radical, R denotes a H atom, an alkyl group or an aryl radical, M denotes a divalent transition metal and zinc or cadmium, X.sub.1 and X.sub.2 independently of one another represent alkyl, cycloalkyl, aralkyl or aryl radicals, or conjointly form a fused carbocyclic or heterocyclic aromatic ring, L denotes a ligand having one or more coordinating N or S atoms, and n denotes the number 1 - 5, are useful for coloring plastic and lacquers in fast yellow to red shades.Type: GrantFiled: August 26, 1975Date of Patent: April 5, 1977Assignee: Ciba-Geigy CorporationInventors: Laurent Vuitel, Francois L'Eplattenier, Andre Pugin
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Patent number: 4012371Abstract: Azo colorants of the formula ##STR1## wherein A denotes the radical of a heterocyclic diazo component, R.sub.1 denotes a hydroxyl, alkyl, phenyl or alkoxycarbonyl group, R.sub.2 denotes a H atom or an alkyl, phenyl, acyl, nitrile, alkoxycarbonyl or carbamoyl group, and X and Y denote substituents which do not confer solubility in water are prepared. The compounds are useful for pigmenting high molecular weight organic materials, such as polyesters, polyolefins and rubber. The compounds have excellent fastness to light, weathering and migration.Type: GrantFiled: March 10, 1975Date of Patent: March 15, 1977Assignee: Ciba-Geigy CorporationInventors: Armand Roueche, Francois L'Eplattenier
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Patent number: 4008225Abstract: Process for the manufacture of bis-azomethine metal complex colorants of the formula ##STR1## wherein A denotes an isocyclic or heterocyclic aromatic radical, X denotes an isocyclic or heterocyclic aromatic radical to which the N-atoms are bonded in the o-position or peri-position, or an alkylene radical containing 2-8 C atoms, and M denotes a divalent transition metal ion, a zinc ion or cadmium ion, characterized in that an o-hydroxyaldimine compound of the formula ##STR2## wherein A has the abovementioned meaning and R denotes an alkyl, cycloalkyl or aryl radical, is reacted with a diamine of the formulaNH.sub.2 --X--NH.sub.2wherein X has the abovementioned meaning, in the molar ratio of 2:1, in the presence of a compound which donates a divalent transition metal cation, zinc ion or cadmium ion.Type: GrantFiled: July 28, 1975Date of Patent: February 15, 1977Assignee: Ciba-Geigy CorporationInventors: Francois L'Eplattenier, Laurent Vuitel, Andre Pugin
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Patent number: 3988323Abstract: 1:1- and 2:1-metal complexes of bishydrazides of the formula I ##SPC1##wherein both A's represent identical or different isocyclic or heterocyclic aromatic radicals, B represents an isocyclic or heterocyclic aromatic radical, and R represents hydrogen, an alkyl group containing 1 - 6 carbon atoms, or an alkyl radical, and the complexing metal ions are bivalent cations of the transition metals, zinc ions or cadmium ions which are useful for pigmenting high molecular organic material.Type: GrantFiled: December 12, 1975Date of Patent: October 26, 1976Assignee: Ciba-Geigy CorporationInventors: Francois L'Eplattenier, Laurent Vuitel
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Patent number: 3974149Abstract: Azomethine pigments of the formula ##SPC1##And metal complexes thereof, wherein A denotes an isocyclic or heterocyclic aromatic radical, R denotes a H atom, an alkyl group containing 1-6 C atoms, or an aryl radical, X.sub.2 and X.sub.4 denote H atoms or halogen atoms, X.sub.1 and X.sub.3 denote H atoms or halogen atoms, alkoxy or alkylmercapto groups containing 1-6 C atoms, cycloalkoxy groups containing 5-6 C atoms, or aralkoxy, aryloxy or arylmercapto groups, it being possible for one of the substituents X.sub.1 -X.sub.4 also to be a nitro group which are useful for pigmenting of high molecular material.Type: GrantFiled: August 30, 1974Date of Patent: August 10, 1976Assignee: Ciba-Geigy CorporationInventors: Francois L'Eplattenier, Andre Pugin, Laurent Vuitel
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Patent number: 3963708Abstract: Bis-azomethine metal complex colorants of the formulae ##SPC1##Wherein M denotes a divalent transition metal cation, zinc ion or cadmium ion, X denotes an isocyclic or heterocyclic aromatic radical to which the two nitrogen atoms are bonded in the o- or peri-position to one another and Y.sub.1 and Y.sub.2 denote hydrogen, halogen, alkyl, aryl, nitro, alkoxy, phenoxy or hydroxyl, which are suitable for pigmenting high-molecular organic material.Type: GrantFiled: July 28, 1975Date of Patent: June 15, 1976Assignee: Ciba-Geigy CorporationInventors: Francois L'Eplattenier, Laurent Vuitel, Andre Pugin
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Patent number: 3939194Abstract: Bis-azomethine pigments of the formula ##SPC1##Wherein X denotes an aromatic radical on which the imino groups are in the o-position, Y denotes a hydroxyl, alkoxy, cycloalkoxy, aralkoxy or aryloxy, amino, alkylamino or arylamino group and Z denotes a H or halogen atom or an alkoxy, nitro or nitrile group, the radical X having to be free of nitro groups if Y denotes an arylamino group and Z denotes a H atom, as well as metal complexes of these bis-azomethines are useful for coloring plastics and lacquers in yellow to red shades of good fastness properties.Type: GrantFiled: January 2, 1975Date of Patent: February 17, 1976Assignee: Ciba-Geigy CorporationInventors: Francois L'Eplattenier, Andre Pugin, Laurent Vuitel