Patents by Inventor Francois Ropital

Francois Ropital has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8349281
    Abstract: A process for sequestrating carbon emitted into the atmosphere in the form of CO2 comprises: a) a step for concentrating CO2 in the liquid phase; b) a step for electro-reduction in an aprotic medium to a compound in which the carbon changes to oxidation number +3 in the form of oxalic acid or formic acid; c) if appropriate, a step for re-extracting oxalic or formic acid in the aqueous phase; and d) a step for mineralization by reaction with a compound of an element M, resulting in a stable compound in which the atomic ratio C/M is about 2/1.
    Type: Grant
    Filed: December 10, 2004
    Date of Patent: January 8, 2013
    Assignee: IFP Energies nouvelles
    Inventors: Hervé Toulhoat, François Ropital, Sébastien Duval
  • Patent number: 7867464
    Abstract: A process for the reversible storage of hydrogen, comprising bringing an alloy of alkaline metal and silicon into contact with gaseous hydrogen leading to the formation of the hydride or corresponding hydrides, comprises the use of at least one balanced system that corresponds to the formula: MXMSi?MXMSiHn ?where M is selected from among Li, Na, or K and in which atomic ratios XM take on the following values: XLi=1 1?XNa?3 1?XK?2 ?n is the number of hydrogen atoms corresponding to the stoichiometry of the hydride or formed hydrides. or to the formula MSiXSi?MSiXSiH2XSi+1 ?where M is selected from among Li, Na, or K and in which the atomic ratio XSi=Si/M takes on a value of 1 to 4.
    Type: Grant
    Filed: June 8, 2009
    Date of Patent: January 11, 2011
    Assignee: IFP Energies Nouvelles
    Inventors: Pascal Raybaud, François Ropital
  • Publication number: 20090302270
    Abstract: A process for the reversible storage of hydrogen, comprising bringing an alloy of alkaline metal and silicon into contact with gaseous hydrogen leading to the formation of the hydride or corresponding hydrides, comprises the use of at least one balanced system that corresponds to the formula: MXMSiMXMSiHn where M is selected from among Li, Na, or K and in which atomic ratios XM take on the following values: XLi=1 1?XNa?3 1?XK?2 n is the number of hydrogen atoms corresponding to the stoichiometry of the hydride or formed hydrides. or to the formula MSiXSiMSiXSiH2XSi+1 where M is selected from among Li, Na, or K and in which the atomic ratio XSi=Si/M takes on a value of 1 to 4.
    Type: Application
    Filed: June 8, 2009
    Publication date: December 10, 2009
    Inventors: Pascal Raybaud, Francois Ropital
  • Patent number: 7608239
    Abstract: A process for the reversible storage of hydrogen, comprising bringing into contact a material that consists of magnesium elements and nitrogen elements with gaseous hydrogen leading to the formation of an amide or corresponding hydrides, comprises the use of a balanced system corresponding to the formula: Mg3N2Mg(NH2)2+2MgHn where n is the number of hydrogen atoms corresponding to the stoichiometry of the hydride or hydrides formed. The material can also comprise, in a minor proportion, at least one transition metal of groups 3 to 12 of the periodic table that is selected from among Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn and Pd.
    Type: Grant
    Filed: February 6, 2006
    Date of Patent: October 27, 2009
    Assignee: Institut Francais du Petrole
    Inventors: Pascal Raybaud, François Ropital
  • Patent number: 7547432
    Abstract: A process for the reversible storage of hydrogen, comprising bringing into contact an alloy of magnesium and palladium with the gaseous hydrogen leading to the formation of hydride or corresponding hydrides, comprises the use of a balanced system corresponding to the formula: MgxPdMgxPdHn in which atomic ratio x takes on a value of 3 to 6, and n is the number of hydrogen atoms corresponding to the stoichiometry of the hydride or hydrides formed or to the formula: MgxPdMg2PdH4+Mgx-2Hn in which the atomic ratio x takes on a value of 7 to 9, and n is the number of hydrogen atoms corresponding to the stoichiometry of the hydride or hydrides formed.
    Type: Grant
    Filed: February 6, 2006
    Date of Patent: June 16, 2009
    Assignee: Institut Francais du Petrole
    Inventors: Pascal Raybaud, François Ropital
  • Publication number: 20080296146
    Abstract: A process for sequestrating carbon emitted into the atmosphere in the form of CO2 comprises: a) a step for concentrating CO2 in the liquid phase; b) a step for electro-reduction in an aprotic medium to a compound in which the carbon changes to oxidation number +3 in the form of oxalic acid or formic acid; c) if appropriate, a step for re-extracting oxalic or formic acid in the aqueous phase; and d) a step for mineralization by reaction with a compound of an element M, resulting in a stable compound in which the atomic ratio C/M is about 2/1.
    Type: Application
    Filed: December 10, 2004
    Publication date: December 4, 2008
    Inventors: Herve Toulhoat, Francois Ropital, Sebastien Duval
  • Patent number: 7442264
    Abstract: The use is described, in the fabrication of apparatus and equipment used in refining and in petrochemicals (for example furnace, reactor or line elements), of a steel composition comprising: at most 0.25% C; more than 1% up to 10% Mn; 1.5% to 5% Si; at most 0.03% P; at most 0.03% S; 4% to 10% Cr; 0.5% to 2% Mo; at most 0.40% V; and at most 0.10% N; the complement to 100% being essentially iron. Steels comprising: at most 0.15% C; more than 2% up to 10% Mn; 1.5% to 5% Si; at most 0.03% P; at most 0.03% S; 4% to 10% Cr; more than 0.5% up to 2% Mo; at most 0.40% V; and at most 0.10% N; the complement to 100% being essentially iron; are themselves novel.
    Type: Grant
    Filed: February 27, 2004
    Date of Patent: October 28, 2008
    Assignee: Institute Francais du Petrole
    Inventors: Francois Ropital, Xavier Longaygue
  • Patent number: 7246516
    Abstract: The present invention relates to a device comprising a thermobalance equipped with a detector (5) for measuring acoustic signals emitted by a sample (6) hanging from the balance beam and a preamplifier (2) incorporated in the vicinity of the head of the balance. The invention allows gas phase kinetic study of the degradation of materials and of depositions on these materials under temperature (100 to 1400° C.). In particular, corrosion phenomena such as: oxidation, sulfurization, carbonizing, metal dusting, nitriding, hydridation, chlorination, molten salt attack, and combinations of these degradations. Besides, deposits on the materials can be due to coking phenomena (carbon deposits), deposition of molten salts, volatile compounds condensation. The invention allows evaluation of the efficiency of inhibitors against corrosion and deposition processes.
    Type: Grant
    Filed: August 22, 2005
    Date of Patent: July 24, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Francois Ropital, Philippe Dascotte
  • Publication number: 20060193767
    Abstract: A process for the reversible storage of hydrogen, comprising bringing into contact a material that consists of magnesium elements and nitrogen elements with gaseous hydrogen leading to the formation of an amide or corresponding hydrides, comprises the use of a balanced system corresponding to the formula: Mg3N2 <Mg(NH2)2 +2MgHn where n is the number of hydrogen atoms corresponding to the stoichiometry of the hydride or hydrides formed. The material can also comprise, in a minor proportion, at least one transition metal of groups 3 to 12 of the periodic table that is selected from among Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn and Pd.
    Type: Application
    Filed: February 6, 2006
    Publication date: August 31, 2006
    Inventors: Pascal Raybaud, Francois Ropital
  • Publication number: 20060188425
    Abstract: A process for the reversible storage of hydrogen, comprising bringing an alloy of alkaline metal and silicon into contact with gaseous hydrogen leading to the formation of the hydride or corresponding hydrides, comprises the use of at least one balanced system that corresponds to the formula: MXMSiMXMSiHn where M is selected from among Li, Na, or K and in which atomic ratios XM take on the following values: XLi=1
    Type: Application
    Filed: February 6, 2006
    Publication date: August 24, 2006
    Inventors: Pascal Raybaud, Francois Ropital
  • Publication number: 20060037386
    Abstract: The present invention relates to a device comprising a thermobalance equipped with a detector (5) for measuring acoustic signals emitted by a sample (6) hanging from the balance beam and a preamplifier (2) incorporated in the vicinity of the head of the balance. The invention allows gas phase kinetic study of the degradation of materials and of depositions on these materials under temperature (100 to 1400° C.). In particular, corrosion phenomena such as: oxidation, sulfurization, carbonizing, metal dusting, nitriding, hydridation, chlorination, molten salt attack, and combinations of these degradations. Besides, deposits on the materials can be due to coking phenomena (carbon deposits), deposition of molten salts, volatile compounds condensation. The invention allows evaluation of the efficiency of inhibitors against corrosion and deposition processes.
    Type: Application
    Filed: August 22, 2005
    Publication date: February 23, 2006
    Inventors: Francois Ropital, Philippe Dascotte
  • Patent number: 6824672
    Abstract: An austenitic stainless steel with a composition comprising: at most 0.15% of C; 2% to 10% of Mn; at most 2% of Ni; at most 4% of Cu; 0.1% to 0.4% of N; 10% to 20% of Cr; at most 1% of Si; at most 3% of Mo; and at most 0.7% of Ti; is used to manufacture equipment, for example furnaces, reactors or ducts, or elements of this equipment, or to coat the internal walls of this equipment, said equipment being used to implement petrochemical processes conducted at temperatures of 350° C. to 1100° C. and in which coke can be formed.
    Type: Grant
    Filed: January 15, 2002
    Date of Patent: November 30, 2004
    Assignees: Institute Francais du Petrole, USINOR
    Inventors: Philippe Lecour, Xavier Longaygue, François Ropital, Laurent Antoni
  • Publication number: 20040234409
    Abstract: The use is described, in the fabrication of apparatus and equipment used in refining and in petrochemicals (for example furnace, reactor or line elements), of a steel composition comprising:
    Type: Application
    Filed: February 27, 2004
    Publication date: November 25, 2004
    Inventors: Francois Ropital, Xavier Longaygue
  • Publication number: 20030153800
    Abstract: Materials that consist at least in part of aluminum quasi-crystals whose composition is represented by the general formula:
    Type: Application
    Filed: December 2, 2002
    Publication date: August 14, 2003
    Applicant: Institut Francais du Petrole
    Inventors: Philippe Lecour, Xavier Longaygue, Francois Ropital
  • Patent number: 6524402
    Abstract: A passivation method for the metallic surface of a nickel and iron-based superalloy which is used as the constituent material of reactor or furnace walls is described, in which the superalloy is coated on at least one of its surfaces which comes into contact with a corrosive atmosphere containing either hydrocarbons at high temperature or containing oxidizing gases at high temperature, with at least two successive layers resulting from successive chemical vapour deposition of its one or more constituent elements, the external phase, resulting from chemical vapour deposition of at least one silicon compound and the layer(s) deposited between the superalloy surface, and the external layer resulting from chemical vapour deposition of at least one of a metal or metalloid.
    Type: Grant
    Filed: June 23, 1995
    Date of Patent: February 25, 2003
    Assignee: Institut Francais du Petrole
    Inventors: Paul Broutin, Pascal Nisio, François Ropital
  • Publication number: 20020129876
    Abstract: An austenitic stainless steel with a composition comprising:
    Type: Application
    Filed: January 15, 2002
    Publication date: September 19, 2002
    Applicant: Institut Francais du Petrole
    Inventors: Philippe Lecour, Xavier Longaygue, Francois Ropital, Laurent Antoni
  • Patent number: 6444168
    Abstract: In order to produce elements for furnaces, reactors or conduits on the walls of which coke can appear, steels are used with a composition which is adapted to resist coking comprising, by weight, at most 0.25% of C, 1.5% to 5% of Si, 4% to 10% of Cr, 0.5% to 2% of Mo, 0.3% to 1% of Mn, at most 0.030% of S and at most 0.03% of P, the complement to 100% being essentially iron. Novel steel compositions for use in these applications are those which comprise, by weight, at most 0.25% of C, more than 2.5% and up to 5% of Si, 4% to 10% of Cr, 0.5% to 2% of Mo, 0.3% to 1% of Mn, at most 0.03% of S and at most 0.03% of P, the complement to 100% being essentially iron.
    Type: Grant
    Filed: October 2, 2000
    Date of Patent: September 3, 2002
    Assignee: Institu Francais du Petrole
    Inventors: Philipe Lecour, Xavier Longaygue, Francois Ropital
  • Patent number: 6348145
    Abstract: Coated steel articles are described which exhibit anti-coking properties, and a process for producing such articles by depositing an anti-coking coating on a matrix constituted by a steel, in general a refractory steel. These articles comprise: a refractory steel substrate comprising at least 0.2% by weight of carbon; a carbon-rich diffusion barrier; and an outer layer containing 90% to 99% by weight of chromium, coated by a cementation method. More particularly, the coated steel articles constitute tubes for reactors or stills used in various refining or petrochemical processes.
    Type: Grant
    Filed: July 6, 1998
    Date of Patent: February 19, 2002
    Assignee: Institut Francais du Petrole
    Inventors: François Ropital, Paul Broutin, Marcel François, Alain Bertoli
  • Patent number: 6291079
    Abstract: The invention concerns a method for manufacturing steel wire comprising the following steps: manufacturing a reinforcing wire of sizeable length by rolling or hot wire drawing from steel containing the following elements: 0.18% to 0.45 % C, 0.4% to 1.8% Mn, 1% to 4% Cr, 0.1% to 0.6% Si, 0% to 1.5% Mo, 0% to 1.5% Ni, at most 0.01% S and 0.02% P, the reinforcing wire having, after being rolled or hot drawn, a temperature at least higher than the AC3 temperature, preferably by 50 to 200° C. and in particular by 100 to 150° C.; winding the wire in reels before air cooling the raw manufacturing wire to obtain a HRC hardness not less than 40 and preferably higher than 45. In a variant, the method consists in quenching and tempering so that the wire has a hardness between 20 HRC and 35 HRC. The invention also concerns a reinforcing wire and a flexible tube for carrying effluents.
    Type: Grant
    Filed: May 10, 1999
    Date of Patent: September 18, 2001
    Assignees: Institut Francais du Petrole, Coflexip
    Inventors: José Mallen Herrero, François Ropital
  • Patent number: 6235238
    Abstract: In order to produce elements for furnaces, reactors or conduits on the walls of which coke can appear, steels are used with a composition which is adapted to resist coking comprising, by weight, at most 0.25% of C, 1.5% to 5% of Si, 4% to 10% of Cr, 0.5% to 2% of Mo, 0.3% to 1% of Mn, at most 0.030% of S and at to most 0.03% of P, the complement to 100% being essentially iron. Novel steel compositions for use in these applications are those which comprise, by weight, at most 0.25% of C, more than 2.5% and up to 5% of Si, 4% to 10% of Cr, 0.5% to 2% of Mo, 0.3% to 1% of Mn, at most 0.03% of S and at most 0.03% of P, the complement to 100% being essentially iron.
    Type: Grant
    Filed: March 31, 1999
    Date of Patent: May 22, 2001
    Assignee: Institut Francais du Petrole
    Inventors: Philippe Lecour, Xavier Longaygue, François Ropital