Patents by Inventor Frank J. Sutman

Frank J. Sutman has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9034146
    Abstract: Disclosed are methods for increasing the filler content of paper or paperboard, comprising (a) combining a heterogeneous polymer blend with a ground calcium carbonate filler; (b) combining the resulting mixture with a pulp slurry; and (c) processing the resulting slurry mixture to form a sheet of paper or paperboard. Also disclosed are methods of increasing the filler content of paper or paperboard comprising (1) combining either a heterogeneous polymer blend or a ground calcium carbonate filler with a pulp slurry, (2) combining the remaining component with the pulp slurry; and (c) processing the resulting pulp slurry mixture to form a sheet of paper or paperboard.
    Type: Grant
    Filed: April 30, 2013
    Date of Patent: May 19, 2015
    Assignee: Solenis Technologies, L.P.
    Inventors: Joseph M. Mahoney, Frank J. Sutman
  • Patent number: 9011643
    Abstract: Disclosed herein are cellulase compositions useful as papermaking performance additives for improving paper dry strength of a paper product and reducing refining energy in papermaking processes, and improving paper production. These cellulase compositions are formulated using cellulase, papermaking contaminant control polymers, protein stabilizers and cellulase enhancers. These cellulase compositions measure higher in endo-cellulase activity with better stability than conventional cellulase, and have shown differentiating performance in improving paper dry strength properties versus cellulase alone.
    Type: Grant
    Filed: October 8, 2013
    Date of Patent: April 21, 2015
    Assignee: Solenis Technologies L.P.
    Inventors: Qu-Ming Gu, Frank J. Sutman
  • Patent number: 8932433
    Abstract: A method of improving retention and drainage in a papermaking process is disclosed. The addition of an associative polymer, a poly(vinylamine) and optionally a siliceous material to the papermaking slurry to improve retention and drainage is disclosed. Additionally a method to improve retention and drainage comprising addition of an organic microparticle, a poly(vinylamine) and optionally a siliceous material to the papermaking slurry is disclosed. A composition comprising an associative polymer, and a poly(vinylamine) and optionally further comprising cellulose fiber is disclosed.
    Type: Grant
    Filed: July 17, 2012
    Date of Patent: January 13, 2015
    Assignee: Solenis Technologies, L.P.
    Inventors: Frank J. Sutman, John C. Harrington, Robert A Gelman
  • Publication number: 20140174685
    Abstract: Disclosed herein are cellulase compositions useful as papermaking performance additives for improving paper dry strength of a paper product and reducing refining energy in papermaking processes, and improving paper production. These cellulase compositions are formulated using cellulase, papermaking contaminant control polymers, protein stabilizers and cellulase enhancers. These cellulase compositions measure higher in endo-cellulase activity with better stability than conventional cellulase, and have shown differentiating performance in improving paper dry strength properties versus cellulase alone.
    Type: Application
    Filed: October 8, 2013
    Publication date: June 26, 2014
    Applicant: HERCULES INCORPORATED
    Inventors: Qu-Ming Gu, Frank J. Sutman
  • Patent number: 8518216
    Abstract: Methods for making a heterogeneous polymer blend comprising one or more anionic polymers, one or more cationic polymers, and one or more non-ionic polymers, which method comprises (a) adding to a non-neutral solution a first amount of polymerization initiator and one or more anionic or cationic monomers, wherein each monomer has the same charge; (b) a second amount of the polymerization initiator and one or more non-ionic monomers; (c) adding a third amount of the polymerization initiator and one or more ionic monomers that are oppositely charged from the monomers of (a); adding stepwise, a fourth amount of the polymerization initiator to react any residual monomer, and (e) neutralizing the resulting polymer blend. Also claimed are heterogeneous polymer blends containing polymers formed from one or more anionic, cationic, and non-ionic monomers, either polymerized in situ or separately and then combined.
    Type: Grant
    Filed: November 10, 2011
    Date of Patent: August 27, 2013
    Assignee: Hercules Incorporated
    Inventors: Frank J. Sutman, Joseph Mahoney
  • Patent number: 8444818
    Abstract: A stable aqueous composition comprising polyvinylamine and liquid cationic starch in a ratio of from 90 to 55 parts of polyvinylamine on active basis to 10 to 45 parts of liquid cationic starch on active basis is disclosed. The composition can be used in papermaking as a strength or as a drainage aid.
    Type: Grant
    Filed: April 7, 2011
    Date of Patent: May 21, 2013
    Assignee: Hercules Incorporated
    Inventors: Frank J. Sutman, Christopher P. Dilkus, Qu-Ming Gu
  • Publication number: 20120291971
    Abstract: A method of improving retention and drainage in a papermaking process is disclosed. The addition of an associative polymer, a poly(vinylamine) and optionally a siliceous material to the papermaking slurry to improve retention and drainage is disclosed. Additionally a method to improve retention and drainage comprising addition of an organic microparticle, a poly(vinylamine) and optionally a siliceous material to the papermaking slurry is disclosed. A composition comprising an associative polymer, and a poly(vinylamine) and optionally further comprising cellulose fiber is disclosed.
    Type: Application
    Filed: July 17, 2012
    Publication date: November 22, 2012
    Applicant: HERCULES INCORPORATED
    Inventors: Frank J. Sutman, John C. Harrington, Robert A. Gelman
  • Patent number: 8163134
    Abstract: Methods for making a heterogeneous polymer blend comprising one or more anionic polymers, one or more cationic polymers, and one or more non-ionic polymers, which method comprises (a) adding to a non-neutral solution a first amount of polymerization initiator and one or more anionic or cationic monomers, wherein each monomer has the same charge; (b) adding a second amount of the polymerization initiator and one or more non-ionic monomers; (c) adding a third amount of the polymerization initiator and one or more ionic monomers that are oppositely charged from the monomers of (a); adding stepwise, a fourth amount of the polymerization initiator to react any residual monomer, and (e) neutralizing the resulting polymer blend. Also claimed are heterogeneous polymer blends containing polymers formed from one or more anionic, cationic, and non-ionic monomers, either polymerized in situ or separately and then combined.
    Type: Grant
    Filed: September 18, 2009
    Date of Patent: April 24, 2012
    Assignees: Hercules Incorporated, Specialty Minerals (Michigan) Inc.
    Inventors: Frank J. Sutman, Joseph M. Mahoney, Robert Anthony Gill, Daniel Bruce Evans
  • Publication number: 20120071608
    Abstract: Methods for making a heterogeneous polymer blend comprising one or more anionic polymers, one or more cationic polymers, and one or more non-ionic polymers, which method comprises (a) adding to a non-neutral solution a first amount of polymerization initiator and one or more anionic or cationic monomers, wherein each monomer has the same charge; (b) a second amount of the polymerization initiator and one or more non-ionic monomers; (c) adding a third amount of the polymerization initiator and one or more ionic monomers that are oppositely charged from the monomers of (a); adding stepwise, a fourth amount of the polymerization initiator to react any residual monomer, and (e) neutralizing the resulting polymer blend. Also claimed are heterogeneous polymer blends containing polymers formed from one or more anionic, cationic, and non-ionic monomers, either polymerized in situ or separately and then combined.
    Type: Application
    Filed: November 10, 2011
    Publication date: March 22, 2012
    Inventors: Frank J. Sutman, Joseph M. Mahoney
  • Publication number: 20110247775
    Abstract: A stable aqueous composition comprising polyvinylamine and liquid cationic starch in a ratio of from 90 to 55 parts of polyvinylamine on active basis to 10 to 45 parts of liquid cationic starch on active basis is disclosed. The composition can be used in papermaking as a strength or as a drainage aid.
    Type: Application
    Filed: April 7, 2011
    Publication date: October 13, 2011
    Inventors: Frank J. Sutman, Christopher P. Dilkus, Qu-Ming Gu
  • Publication number: 20100071863
    Abstract: Methods for making a heterogeneous polymer blend comprising one or more anionic polymers, one or more cationic polymers, and one or more non-ionic polymers, which method comprises (a) adding to a non-neutral solution a first amount of polymerization initiator and one or more anionic or cationic monomers, wherein each monomer has the same charge; (b) adding a second amount of the polymerization initiator and one or more non-ionic monomers; (c) adding a third amount of the polymerization initiator and one or more ionic monomers that are oppositely charged from the monomers of (a); adding stepwise, a fourth amount of the polymerization initiator to react any residual monomer, and (e) neutralizing the resulting polymer blend. Also claimed are heterogeneous polymer blends containing polymers formed from one or more anionic, cationic, and non-ionic monomers, either polymerized in situ or separately and then combined.
    Type: Application
    Filed: September 18, 2009
    Publication date: March 25, 2010
    Applicants: Hercules Inc., Specialty Minerals (Michigan) Inc.
    Inventors: Frank J. Sutman, Joseph M. Mahoney, Robert Anthony Gill, Daniel Bruce Evans
  • Patent number: 7396874
    Abstract: A papermaking method and a composition which utilize, as a drainage aid, a water-soluble cationic or amphoteric copolymer prepared via a water-in-oil polymerization technique that, absent a cross-linking agent, is characterized by a Huggins' constant (k?) determined in 0.01M NaCl greater than 0.3 and a storage modulus (G?) at 6.3 Hz greater than 50 Pa.
    Type: Grant
    Filed: December 4, 2003
    Date of Patent: July 8, 2008
    Assignee: Hercules Incorporated
    Inventors: Martha Hollomon, Brian L. Walchuk, Frank J. Sutman
  • Publication number: 20040143039
    Abstract: A papermaking method and a composition which utilize, as a drainage aid, a water-soluble cationic or amphoteric copolymer prepared via a water-in-oil polymerization technique that, absent a cross-linking agent, is characterized by a Huggins' constant (k′) determined in 0.01 M NaCl greater than 0.3 and a storage modulus (G′) at 6.3 Hz greater than 50 Pa.
    Type: Application
    Filed: December 4, 2003
    Publication date: July 22, 2004
    Inventors: Martha Hollomon, Brian L. Walchuk, Frank J. Sutman
  • Patent number: 6168686
    Abstract: A novel method of improving drainage rate and retention of fines which is effective in unfilled, newsprint-type furnish without a silica/bentonite-type particle is disclosed. The method comprises adding a cationic or amphoteric starch, and a cationic polyelectrolyte followed by the addition of a high molecular weight anionic polyacrylamide copolymer.
    Type: Grant
    Filed: August 19, 1998
    Date of Patent: January 2, 2001
    Assignee: Betzdearborn, Inc.
    Inventors: Frank J. Sutman, Richard A. Hobirk
  • Patent number: 5885413
    Abstract: A process for the deinking of wastepaper is disclosed. The process comprises administering a sufficient amount of a branched alcohol alkoxylate surfactant to a sample of waste paper for which treatment is desired. The surfactant is effective for the flotation of the ink.
    Type: Grant
    Filed: November 15, 1996
    Date of Patent: March 23, 1999
    Assignee: BetzDearborn Inc.
    Inventors: Sandra K. Richmann, Frank J. Sutman
  • Patent number: 5800719
    Abstract: A method for dewatering deinking sludge utilizing a water soluble block copolymer having the structure: ##STR1## wherein E is a polymeric segment obtained from the polymerization of hydrophobic monomers, x when present is a nonionic monomer, y is a cationic monomer, R.sub.1 and R.sub.2 are the same or different and are H or a lower alkyl group from C.sub.1 to C.sub.3 and F is a salt of an ammonium cation. Preferably, the polymer contains from about 20 mole % to 35 mole % cationicity.
    Type: Grant
    Filed: May 14, 1997
    Date of Patent: September 1, 1998
    Assignee: BetzDearborn Inc.
    Inventors: Frank J. Sutman, Richard A. Hobirk
  • Patent number: 5660683
    Abstract: A process and composition for deinking waste paper is disclosed. The process comprises administering a sufficient amount of a mixture containing (a) an alcohol, randomly alkoxylated with a mixture of alkylene oxides to form a surfactant, (b) a thiol ethoxylate surfactant, and (c) a secondary alcohol alkoxylate, to a sample of waste paper for which treatment is desired. The surfactant enhances the aggregation and densification of electrostatic toner particles, while promoting foaming in the aqueous slurry.
    Type: Grant
    Filed: May 2, 1995
    Date of Patent: August 26, 1997
    Assignee: BetzDearborn Inc.
    Inventor: Frank J. Sutman
  • Patent number: 5626718
    Abstract: The present invention is directed to a method for increasing the retention on a washing/thickening device in an aqueous papermaking system. The method generally comprises adding to the furnish solids of the system an effective amount of a cationic polyacrylamide polymer.
    Type: Grant
    Filed: September 16, 1994
    Date of Patent: May 6, 1997
    Assignee: Betz Laboratories, Inc.
    Inventors: Irenee J. Philippe, Frank J. Sutman, Thomas E. Taggart, Mary B. K. Letscher, Michael A. Schuster, John C. Harrington, IV