Patents by Inventor Frank Klippel

Frank Klippel has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20210307317
    Abstract: Described herein is a polymeric stabilizing agent selected from poly-lysine derivatives obtained by process including heating an aqueous lysine solution to boiling, increasing a temperature of the aqueous lysine solution to a reaction temperature in the range of about 105° C. to about 180° C., and keeping the reaction temperature in the range of about 105° C. to about 180° C. until a melt viscosity of the reaction mixture is in the range of about 350 mPa*s to about 6,500 mPa*s, and (ii) an amine number in the range of about 100 mg KOH/g to about 500 mg KOH/g is achieved. The process also includes adding alkyl-carboxylic acid or alkenyl-carboxylic acid in amounts of 2.5 mol % to 10 mol %, and increasing or keeping the reaction temperature in the range of about 105° C. to about 180° C. until number of free alkyl-carboxylic acid or alkenyl-carboxylic acid is ?9% by weight.
    Type: Application
    Filed: May 11, 2018
    Publication date: October 7, 2021
    Inventors: Markus Kalt, Janine Rude, Helmut Witteler, Markus Meise, Frank Klippel, Tina Schroeder-Grimonpont, Hans-Peter Seelmann-Eggebert
  • Publication number: 20210289773
    Abstract: Described herein is a poly-lysine derivative obtained by a process including heating an aqueous lysine solution to boiling, increasing a temperature of the aqueous lysine solution to a reaction temperature in the range of about 105° C. to about 180° C., and keeping the reaction temperature in the range of about 105° C. to about 180° C. until (i) a melt viscosity of the reaction mixture is in the range of about 350 mPa*s to about 6,500 mPa*s, and (ii) an amine number in the range of about 100 mg KOH/g to about 500 mg KOH/g is achieved. The process also includes adding alkyl-carboxylic acid or alkenyl-carboxylic acid in amounts of 2.5 mol % to 10 mol %, and increasing or keeping the reaction temperature in the range of about 105° C. to about 180° C. until number of free alkyl-carboxylic acid or alkenyl-carboxylic acid is ?9% by weight.
    Type: Application
    Filed: April 17, 2018
    Publication date: September 23, 2021
    Inventors: Markus Kalt, Helmut Witteler, Tina Schroeder-Grimonpot, Markus Meise, Hans-Peter Seelmann-Eggebert, Frank Klippel
  • Patent number: 8568522
    Abstract: Process for passivating metallic surfaces, and a preparation suitable for implementing the process, comprising at least water, an acid, and a copolymer of functionalized (meth)acrylic esters, monomers containing phosphoric and/or phosphonic acid groups, monomers having COOH groups, and, if appropriate, further monomers. Copolymer which comprises said monomers.
    Type: Grant
    Filed: July 18, 2007
    Date of Patent: October 29, 2013
    Assignee: BASF SE
    Inventors: Frank Klippel, Alexander Göthlich, Gunnar Schornick, Dietrich Fehringer, Thomas Heidenfelder, Helmut Witteler, Walter Bertkau
  • Patent number: 8420174
    Abstract: The present invention relates to a composition for coating metallic surfaces, comprising a binder component; a corrosion inhibitor polymer based on an ethylenically monocarboxylic and dicarboxylic acid and, if appropriate, further ethylenical monomers, a solvent component, and, if appropriate, crosslinkable components, and also pigment/filler components. The invention further relates to processes for its preparation and also to methods of coating a metallic surface using the composition, to coated metallic surfaces thus obtained, and to the use of the composition as a primer, particularly in coil coating or in atmospheric corrosion control. After drying, the applied layer preferably has a thickness of at least 3.1 ?m and is therefore thicker than a typical pretreatment layer.
    Type: Grant
    Filed: August 9, 2006
    Date of Patent: April 16, 2013
    Assignee: BASF SE
    Inventors: Alexander Goethlich, Frank Klippel, Gunnar Schornick, Guido Vandermeulen, Helmut Witteler, Thomas Heidenfelder, Markus Hickl, Michael Dornbusch, Konrad Roschmann, Monica Fernandez Gonzalez
  • Patent number: 8394208
    Abstract: The present invention relates to a composition for treating surfaces, comprising a copolymer as component A, synthesized from (meth)acrylic acid or salts thereof, a carboxylate-containing monomer and/or monomers containing groups containing phosphoric and/or phosphoric acid or salts thereof, and further comonomers if desired, to a passivating layer on a metal surface, which comprises component A, to a process for forming said passivating layer, and to the use of the composition of the invention to passivate a metal surface.
    Type: Grant
    Filed: March 23, 2010
    Date of Patent: March 12, 2013
    Assignee: BASF Aktiengesellschaft
    Inventors: Frank Dietsche, Helmut Witteler, Matthias Kluglein, Frank Klippel
  • Patent number: 8268404
    Abstract: The present invention relates to a method of applying atmospheric corrosion control coats to metallic surfaces, using copolymers comprising as monomeric building blocks monomers containing nitrile groups, monomers containing acidic groups, and vinylaromatic monomers. It relates, furthermore, to preparations for applying corrosion control coats.
    Type: Grant
    Filed: June 18, 2008
    Date of Patent: September 18, 2012
    Assignee: BASF SE
    Inventors: Guido Vandermeulen, Konrad Roschmann, Stephan Amthor, Marc Schroeder, Alexsandro Berger, Frank Klippel
  • Patent number: 8241745
    Abstract: The present invention relates to a substantially chromium-free process for passivating metallic surfaces of Zn, Zn alloys, Al or Al alloys by treating the surface with an acidic aqueous formulation which comprises at least one substantially noncrosslinked, water-soluble polymer or copolymer containing at least 50% by weight of (meth)acrylic acid units and comprises water or an aqueous solvent mixture comprising at least 50% by weight of water, and by further treating the surface with at least one water-soluble crosslinker comprising at least 2 crosslinking groups selected from the group consisting of azirane, oxirane, and thiirane groups. The invention further relates to passivating layers obtainable by means of the process and to a formulation suitable for this process.
    Type: Grant
    Filed: October 15, 2004
    Date of Patent: August 14, 2012
    Assignee: BASF SE
    Inventors: Frank Dietsche, Frank Klippel, Matthias Klüglein, Alexander Göthlich
  • Patent number: 8002119
    Abstract: A method for controlling the thickening of aqueous systems comprising silicates, which comprises adding to the aqueous system at least one copolymer of a mean molecular weight Mw of at least 3000 g/mol to at most 60 000 g/mol and the copolymer being made up essentially randomly from monoethylenically unsaturated monocarboxylic acids, monoethylenically unsaturated dicarboxylic acids and other ethylenically unsaturated comonomers, the polymerization for producing the copolymer being performed in the presence of from 0.01 to 100 mol % of at least one base, based on the total amount of all COOH groups of the monocarboxylic and dicarboxylic acids, the quantitative figures in % by weight being respectively based on the total amount of all monomers used.
    Type: Grant
    Filed: January 30, 2007
    Date of Patent: August 23, 2011
    Assignee: BASF SE
    Inventors: Karl-Heinz Buechner, Stephan Nied, Alexander Goethlich, Frank Klippel, Gunnar Schornick
  • Patent number: 7879158
    Abstract: The present invention relates to a passivating layer on a metal surface, obtainable by contacting the metal surface with a composition comprising a water-soluble nitrogenous polymer, to a surface composed of a metal surface and the passivating layer of the invention, to a process for forming a passivating layer on a metal surface, to the use of a composition comprising a water-soluble nitrogenous polymer to passivate a metal surface, and to a system on a metal surface that comprises a passivating layer of the invention and further coating films.
    Type: Grant
    Filed: March 12, 2004
    Date of Patent: February 1, 2011
    Assignee: BASF SE
    Inventors: Frank Dietsche, Helmut Witteler, Matthias Klüglein, Frank Klippel
  • Publication number: 20100255206
    Abstract: The present invention relates to a method of applying atmospheric corrosion control coats to metallic surfaces, using copolymers comprising as monomeric building blocks monomers containing nitrile groups, monomers containing acidic groups, and vinylaromatic monomers. It relates, furthermore, to preparations for applying corrosion control coats.
    Type: Application
    Filed: June 18, 2008
    Publication date: October 7, 2010
    Applicant: BASF SE
    Inventors: Guido Vandermeulen, Konrad Roschmann, Stephan Amthor, Marc Schroeder, Alexsandro Berger, Frank Klippel
  • Publication number: 20100175792
    Abstract: The present invention relates to a composition for treating surfaces, comprising a copolymer as component A, synthesized from (meth)acrylic acid or salts thereof, a carboxylate-containing monomer and/or monomers containing groups containing phosphoric and/or phosphoric acid or salts thereof, and further comonomers if desired, to a passivating layer on a metal surface, which comprises component A, to a process for forming said passivating layer, and to the use of the composition of the invention to passivate a metal surface.
    Type: Application
    Filed: March 23, 2010
    Publication date: July 15, 2010
    Applicant: BASF AKTIENGESELLSCHAFT
    Inventors: Frank DIETSCHE, Helmut WITTELER, Matthias KLÜGLEIN, Frank KLIPPEL
  • Patent number: 7749337
    Abstract: Process for the passivation of metallic surfaces by treatment of the surface with an acidic, aqueous preparation which comprises at least one water-soluble acid group-containing polymer and Zn, Ca, Mg or Al ions, said process being in particular a continuous process for the passivation of strip metals.
    Type: Grant
    Filed: June 13, 2006
    Date of Patent: July 6, 2010
    Assignee: BASF SE
    Inventors: Helmut Witteler, Walter Bertkau, Thomas Heidenfelder, Alexander Göthlich, Jens Haas, Frank Klippel, Gunnar Schornick
  • Patent number: 7655279
    Abstract: The present invention relates to a composition for treating surfaces, comprising a copolymer as component A, synthesized from (meth)acrylic acid or salts thereof, a carboxylate-containing monomer and/or monomers containing groups containing phosphoric and/or phosphonic acid or salts thereof, and further comonomers if desired, to a passivating layer on a metal surface, which comprises component A, to a process for forming said passivating layer, and to the use of the composition of the invention to passivate a metal surface.
    Type: Grant
    Filed: February 19, 2004
    Date of Patent: February 2, 2010
    Assignee: BASF Aktiengesellschaft
    Inventors: Frank Dietsche, Helmut Witteler, Matthias Klüglein, Frank Klippel
  • Publication number: 20090324839
    Abstract: Process for passivating metallic surfaces, and a preparation suitable for implementing the process, comprising at least water, an acid, and a copolymer of functionalized (meth)acrylic esters, monomers containing phosphoric and/or phosphonic acid groups, monomers having COOH groups, and, if appropriate, further monomers. Copolymer which comprises said monomers.
    Type: Application
    Filed: July 18, 2007
    Publication date: December 31, 2009
    Applicant: BASF SE Patents, Trademarks and Licenses
    Inventors: Frank Klippel, Alexander Göthlich, Gunnar Schornick, Dietrich Fehringer, Thomas Heidenfelder, Helmut Witteler, Walter Bertkau
  • Publication number: 20090025896
    Abstract: A method for controlling the thickening of aqueous systems comprising silicates, which comprises adding to the aqueous system at least one copolymer of a mean molecular weight Mw of at least 3000 g/mol to at most 60 000 g/mol and the copolymer being made up essentially randomly from monoethylenically unsaturated monocarboxylic acids, monoethylenically unsaturated dicarboxylic acids and other ethylenically unsaturated comonomers, the polymerization for producing the copolymer being performed in the presence of from 0.01 to 100 mol % of at least one base, based on the total amount of all COOH groups of the monocarboxylic and dicarboxylic acids, the quantitative figures in % by weight being respectively based on the total amount of all monomers used.
    Type: Application
    Filed: January 30, 2007
    Publication date: January 29, 2009
    Applicant: BASF SE
    Inventors: Karl-Heinz Büchner, Stephan Nied, Alexander Gothlich, Frank Klippel, Gunnar Schornick
  • Publication number: 20090020728
    Abstract: A method for controlling the thickening of aqueous systems comprising silicates, which comprises adding to the aqueous system at least one copolymer of a mean molecular weight Mw of greater than 60 000 g/mol and the copolymer being made up essentially randomly from monoethylenically unsaturated monocarboxylic acids, monoethylenically unsaturated dicarboxylic acids and optionally other ethylenically unsaturated comonomers, the quantitative figures being respectively based on the total amount of all monomers used.
    Type: Application
    Filed: January 31, 2007
    Publication date: January 22, 2009
    Applicant: BASF SE
    Inventors: Karl-Heinz Buchner, Stephan Nied, Frank Klippel, Alexander Gothlich, Gunnar Schornick
  • Publication number: 20090007990
    Abstract: A process for passivating a metallic surface by treating it with an acidic aqueous preparation comprising at least one itaconic acid homo- or copolymer. Passivating layers and metallic surfaces obtainable by means of the process.
    Type: Application
    Filed: August 4, 2005
    Publication date: January 8, 2009
    Inventors: Frank Klippel, Matthias Kluglein, Gunnar Schornick, Alexander Gothlich, Frank Dietsche, Helmut Witteler
  • Publication number: 20080269446
    Abstract: Partially neutralized carboxylate-rich copolymers, processes for their preparation and methods of using the same are disclosed, the copolymers comprising: monomers (A), (B), and (C); wherein monomer (A) comprises at least one monoethylenically unsaturated monocarboxylic acid, and is present in an amount of 30% to 79.99% by weight; wherein monomer (B) comprises at least one monoethylenically unsaturated dicarboxylic acid selected from the group consisting of acids corresponding to general formula I, acids corresponding to general formula II, anhydrides thereof, and other hydrolyzable derivatives thereof, and is present in an amount of 20.
    Type: Application
    Filed: August 4, 2005
    Publication date: October 30, 2008
    Applicant: Basf Aktiengesellschaft
    Inventors: Kathrin Michl, Matthias Gerst, Frank Klippel, Alexander Gothlich, Frank Dietsche, Helmut Witteler, Dieter Faul
  • Publication number: 20080233390
    Abstract: The present invention relates to a composition for coating metallic surfaces, comprising a binder component; a corrosion inhibitor polymer based on an ethylenically monocarboxylic and dicarboxylic acid and, if appropriate, further ethylenical monomers, a solvent component, and, if appropriate, crosslinkable components, and also pigment/filler components. The invention further relates to processes for its preparation and also to methods of coating a metallic surface using the composition, to coated metallic surfaces thus obtained, and to the use of the composition as a primer, particularly in coil coating or in atmospheric corrosion control. After drying, the applied layer preferably has a thickness of at least 3.1 ?m and is therefore thicker than a typical pretreatment layer.
    Type: Application
    Filed: August 9, 2006
    Publication date: September 25, 2008
    Inventors: Alexander Gothlich, Frank Klippel, Gunnar Schornick, Guido Vandermeulen, Helmut Witteler, Thomas Heidenfelder, Markus Hickl, Michael Dornbusch, Konrad Roschmann, Monica Fernandez Gonzalez
  • Publication number: 20080197020
    Abstract: Flat shaped bodies which comprise at least one metallic layer, a conversion coat applied thereto, and at least one paint coat, and methods for producing such bodies starting from flat, metallic, semifinished products.
    Type: Application
    Filed: June 13, 2006
    Publication date: August 21, 2008
    Applicant: BASF Aktiengesellschaft
    Inventors: Helmut Witteler, Alexander Gothlich, Thomas Heidenfelder, Walter Bertkau, Frank Klippel, Gunnar Schornick