Abstract: This invention relates to an improved process for providing water repellency and stain resistance to a masonry surface wherein an aqueous based water repellant polymeric coating is applied thereto and the water removed leaving a water repellent polymeric film adhered to the masonry surface. The improvement in the process resides in the use of an aqueous emulsion of a semi-crystalline ethylene-vinyl acetate polymer formed by emulsion polymerization wherein the polymer has: (a) a crystalline melting point ranging from 35 to 110° C. measured at a heat rate of 20° C. per minute; and, (b) a tensile storage modulus of at least 1×105 dynes/cm2 at a temperature of 115° C. and measured at 6.28 rad/sec.

Abstract: An aqueous polymeric coating composition having a polymer for forming a polymer matrix having carboxylate functionality and nano-scale zinc oxide particles dispersed in the polymer. The particles provide the polymer with at least partial crosslinking and alcohol resistance when incorporated into the polymer matrix upon curing. A polymeric material formed from the aqueous composition and a coated article are also disclosed.

Abstract: The invention relates to an improvement in a process for imparting barrier properties to porous substrates, such as, concrete, masonry products, and wood products. The process comprises the steps of: applying an aqueous based sealing composition comprising a polymeric resin to said porous substrate, evaporating the water and forming a water repellent coating of said polymeric resin on said porous substrate. The improvement comprises: deriving the polymeric resin from an aqueous based polymer emulsion comprising a polymer comprised of emulsion polymerized units of vinyl acetate and ethylene, preferably with a carboxylic acid monomer, the polymer containing amorphous and crystalline ethylene segments and having: (a) a crystalline melting point (Tm) ranging from 35 to 110° C., preferably 50 to 100° C.; measured at a heat rate of 20° C./minute; and, (b) a tensile storage modulus of at least 1×105 dynes/cm2 at 115° C. measured at 6.28 rad/sec.

Abstract: A multilayer packaging material comprising (a) at least one layer of a gas-permeable material, and (b) at least one layer of a gas-barrier coating comprising a polymeric polyol made by copolymerizing a multifunctional epoxide resin and water in the presence of an amount of acid effective for polymerizing the epoxide resin and the water, the amount of water being sufficient to avoid gelation, the polymeric polyol optionally reacted with a crosslinking agent for hydroxyl functionality, especially an amino resin.

Abstract: A multilayer packaging material comprising

Abstract: A substantially solvent free, aqueous, pigmented, two component polyurethane-polyurea dispersion comprising: (a) an aqueous mixture of an acid-containing polymeric polyol and a polyol free of acid groups, wherein the mixture has an average hydroxyl functionality of at least 1.5 and an acid number between about 15 and 200; and an amine or a blend of amines having an average active hydrogen functionality of at least 1.5, the amine or blend of amines being present in a sufficient amount to substantially neutralize the acid-containing polymeric polyol; (b) one or more polyisocyanates; and (c) two or more different pigments; characterized by reducing or eliminating flooding of the pigments with (d) an aqueous polymer emulsion present in an amount sufficient to impart thixotropy to the mixture of (a) and (d).