Patents by Inventor Franz-Josef Stark

Franz-Josef Stark has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9249513
    Abstract: A plating formulation for the electroless deposition of a metal layer on a substrate, wherein a ?-amino acid and/or ?-amino acid derivative is used as a stabilizer. The ?-amino acid is present within a range of 1 mg/L to 2 g/L. Typically, the electrolyte is free of heavy metal stabilizers, cyanides, selenium compounds and sulfur compounds comprising sulfur in an oxidation state between ?2 and +5. The inventive plating formulation can comprise 3-aminopropionic acid, 3-aminobutyric acid, 3-amino-4-methylvaleric acid, and 2-aminoethane-sulfonic acid.
    Type: Grant
    Filed: February 24, 2015
    Date of Patent: February 2, 2016
    Assignee: Enthone Inc.
    Inventors: Franz-Josef Stark, Christoph Werner
  • Publication number: 20150167175
    Abstract: A plating formulation for the electroless deposition of a metal layer on a substrate, wherein a ?-amino acid and/or ?-amino acid derivative is used as a stabilizer. The ?-amino acid is present within a range of 1 mg/L to 2 g/L. Typically, the electrolyte is free of heavy metal stabilizers, cyanides, selenium compounds and sulfur compounds comprising sulfur in an oxidation state between ?2 and +5. The inventive plating formulation can comprise 3-aminopropionic acid, 3-aminobutyric acid, 3-amino-4-methylvaleric acid, and 2-aminoethane-sulfonic acid.
    Type: Application
    Filed: February 24, 2015
    Publication date: June 18, 2015
    Applicant: ENTHONE INC.
    Inventors: Franz-Josef Stark, Christoph Werner
  • Patent number: 8962070
    Abstract: The present invention relates to an electrolyte for the electroless deposition of a metal layer on a substrate, wherein the electrolyte is free of heavy metal stabilizers, cyanides, selenium compounds and sulfur compounds comprising sulfur in an oxidation state between ?2 and +5, and in which instead a ?-amino acid is used as stabilizer. In particular, the inventive electrolyte can comprise 3-aminopropionic acid, 3-aminobutyric acid, 3-amino-4-methylvaleric acid, and 2-aminoethane-sulfonic acid. Furthermore, the invention is directed to a method for the electroless deposition of metal layers utilizing an inventive electrolyte as well as the use of ?-amino acids as stabilizer in electrolytes for the electroless deposition of metal layers in general.
    Type: Grant
    Filed: July 6, 2010
    Date of Patent: February 24, 2015
    Assignee: Enthone Inc.
    Inventors: Franz-Josef Stark, Christoph Werner
  • Publication number: 20120156387
    Abstract: The present invention relates to an electrolyte for the electroless deposition of a metal layer on a substrate, wherein the electrolyte is free of heavy metal stabilizers, cyanides, selenium compounds and sulfur compounds comprising sulfur in an oxidation state between ?2 and +5, and in which instead a ?-amino acid is used as stabilizer. In particular, the inventive electrolyte can comprise 3-aminopropionic acid, 3-aminobutyric acid, 3-amino-4-methylvaleric acid, and 2-aminoethane-sulfonic acid. Furthermore, the invention is directed to a method for the electroless deposition of metal layers utilizing an inventive electrolyte as well as the use of ?-amino acids as stabilizer in electrolytes for the electroless deposition of metal layers in general.
    Type: Application
    Filed: July 6, 2010
    Publication date: June 21, 2012
    Applicant: ENTHONE INC.
    Inventors: Franz-Josef Stark, Christoph Werner
  • Patent number: 7846503
    Abstract: The invention concerns an electrolyte for electroless deposition of metal layers with internal compressive stresses containing a metal base salt, a reducing agent, a complexing agent, an accelerator and a stabilizer. In order to make available an electrolyte of the said kind, from which uniform pore-free and crack-free metal-phosphorus coatings can be deposited with constant layers properties and high phosphorus contents at an elevated deposition rate over a long period of time, it is proposed by means of the invention that the electrolyte contain as metal base salt a metal salt whose anions contain at least one carbon atom and that is present in a starting concentration from 0.01 to 0.3 mol/L. At least one salt consisting of metal acetate, metal formate, metal oxalate, metal propionate, metal citrate and metal ascorbate, especially preferably metal acetate, is used as the metal salt whose anion contains at least one carbon atom.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: December 7, 2010
    Assignee: Enthone Inc.
    Inventors: Franz-Josef Stark, Helmut Horsthemke, Ulrich Treuner
  • Patent number: 7846316
    Abstract: Method and plating bath apparatus for setting the ionic strength of a plating composition using Donnan dialysis by flowing the plating composition along a first surface of a membrane while simultaneously flowing a deposition metal ion exchange composition along a second surface of the membrane such that the deposition metal ion crosses the membrane from the deposition metal ion exchange composition to the plating composition while an exchange cation different from the deposition metal ion crosses the membrane from the plating composition to the deposition metal ion exchange composition.
    Type: Grant
    Filed: May 25, 2006
    Date of Patent: December 7, 2010
    Assignee: Enthone Inc.
    Inventors: Axel Koenig, Andreas Möbius, Franz-Josef Stark
  • Publication number: 20090324804
    Abstract: The invention relates to a method for coating substrate surfaces with a metal or oxide layer in a coating bath. Said bath has at least one component the concentration of which changes during the coating process and which therefore has to be replenished or removed in order to maintain the quality of the bath. The method according to the invention is characterized in that the component is replenished and/or removed depending on the strength of the composition of the bath.
    Type: Application
    Filed: January 26, 2007
    Publication date: December 31, 2009
    Applicant: ENTHONE INC.
    Inventors: Helmut Horsthemke, Franz-Josef Stark
  • Publication number: 20060266654
    Abstract: Method and plating bath apparatus for setting the ionic strength of a plating composition using Donnan dialysis by flowing the plating composition along a first surface of a membrane while simultaneously flowing a deposition metal ion exchange composition along a second surface of the membrane such that the deposition metal ion crosses the membrane from the deposition metal ion exchange composition to the plating composition while an exchange cation different from the deposition metal ion crosses the membrane from the plating composition to the deposition metal ion exchange composition.
    Type: Application
    Filed: May 25, 2006
    Publication date: November 30, 2006
    Applicant: ENTHONE INC.
    Inventors: Axel Koenig, Andreas Mobius, Franz-Josef Stark
  • Publication number: 20040144285
    Abstract: The invention concerns an electrolyte for electroless deposition of metal layers with internal compressive stresses containing a metal base salt, a reducing agent, a complexing agent, an accelerator and a stabilizer. In order to make available an electrolyte of the said kind, from which uniform pore-free and crack-free metal-phosphorus coatings can be deposited with constant layers properties and high phosphorus contents at an elevated deposition rate over a long period of time, it is proposed by means of the invention that the electrolyte contain as metal base salt a metal salt whose anions contain at least one carbon atom and that is present in a starting concentration from 0.01 to 0.3 mol/L. At least one salt consisting of metal acetate, metal formate, metal oxalate, metal propionate, metal citrate and metal ascorbate, especially preferably metal acetate, is used as the metal salt whose anion contains at least one carbon atom.
    Type: Application
    Filed: October 3, 2003
    Publication date: July 29, 2004
    Applicant: Enthone Inc.
    Inventors: Franz-Josef Stark, Helmut Horsthemke, Ulrich Treuner