Publication number: 20140179973
Abstract: A process for metathesis of olefins, bringing olefins into contact with a catalyst activated by heating to a temperature in the range 100° C. to 1000° C. in an atmosphere of non-reducing gas, the catalyst containing at least one inorganic material having at least two elementary spherical particles, each of which are metal oxide particles with a size of at most 300 nm and containing at least one of tungsten, molybdenum, rhenium, cobalt, tin, ruthenium, iron or titanium, alone or a mixture, the metal oxide particles being present within a mesostructured matrix of an oxide of at least one element Y: silicon, aluminium, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium or neodymium or a mixture thereof, the matrix having pore size 1.5 to 50 nm and amorphous walls with thickness 1 to 30 nm and maximum diameter of 200 ?m.
Type:
Application
Filed:
July 11, 2012
Publication date:
June 26, 2014
Applicants:
UNIVERSITE DE PARIS 6 - PIERRE ET MARIE CURIE, IFP ENERGIES NOUVELLES, UNIVERSITE CATHOLIQUE DE LOUVAIN
Inventors:
Damien Debecker, Frederic Colbeau-Justin, Clement Sanchez, Alexandra Chaumonnot, Mikael Berthod
Publication number: 20140027346
Abstract: An inorganic material is described, constituted by at least two elementary spherical particles, each of said spherical particles comprising metallic nanoparticles having at least one band with a wave number in the range 750 to 1050 cm?1 in Raman spectroscopy and containing one or more metals selected from vanadium, niobium, tantalum, molybdenum and tungsten, said metallic nanoparticles being trapped in a mesostructured matrix based on an oxide of an element Y selected from silicon, aluminium, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium and neodymium. Said matrix has pores with a diameter in the range 1.5 to 50 nm and amorphous walls with a thickness in the range 1 to 30 nm. Said elementary spherical particles have a maximum diameter of 200 microns and said metallic nanoparticles have a maximum dimension strictly less than 1 nm.
Type:
Application
Filed:
December 15, 2011
Publication date:
January 30, 2014
Applicants:
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, IFP ENERGIES NOUVELLES, UNIVERSITE PIERRE ET MARIE CURIE
Inventors:
Alexandra Chaumonnot, Clement Sanchez, Cedric Boissiere, Frederic Colbeau-Justin, Audrey Bonduelle
Publication number: 20140005031
Abstract: Inorganic material having at least two elementary spherical particles, each of said spherical metallic particles: a polyoxometallate with formula (XxMmOyHh)q?, where H is hydrogen, O is oxygen, X is phosphorus, silicon, boron, nickel or cobalt and M is one or more vanadium, niobium, tantalum, molybdenum, tungsten, iron, copper, zinc, cobalt and nickel, x is 0, 1, 2 or 4, m is 5, 6, 7, 8, 9, 10, 11, 12 or 18, y is 17 to 72, h is 0 to 12 and q is 1 to 20.
Type:
Application
Filed:
December 15, 2011
Publication date:
January 2, 2014
Applicants:
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, IFP ENERGIES NOUVELLES, UNIVERSITE PIERRE ET MARIE CURIE
Inventors:
Alexandra Chaumonnot, Clement Sanchez, Cedric Boissiere, Frederic Colbeau-Justin, Karin Marchand, Elodie Devers, Audrey Bonduelle, Denis Uzio, Antoine Daudin, Bertrand Guichard, Denis Uzio, Antoine Daudin