Patents by Inventor Frederic Guernalec

Frederic Guernalec has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11078113
    Abstract: A method of treatment using a beam of singly- and multiply-charged gas ions produced by an electron cyclotron resonance (ECR) source of a glass material in which the ion acceleration voltage of between 5 kV and 1000 kV is chosen to create an implanted layer of a thickness equal to a multiple of 100 nm; and the ion dose per surface unit in a range of between 1012 ions/cm2 and 1018 ions/cm2 is chosen so as to create an atomic concentration of ions equal to 10% with a level of uncertainty of (+/?)5%. Advantageously this makes it possible to obtain materials made from glass that are non-reflective in the visible range.
    Type: Grant
    Filed: May 10, 2018
    Date of Patent: August 3, 2021
    Assignee: IONICS FRANCE
    Inventors: Denis Busardo, Frederic Guernalec
  • Patent number: 10982312
    Abstract: A treatment method of a sapphire material, said method comprising bombardment of a surface of the sapphire material, said surface facing a medium different from the sapphire material, by a single- and/or multi-charged gas ion beam so as to produce an ion implanted layer in the sapphire material, wherein the ions are selected from ions of the elements from the list consisting of helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), boron (B), carbon (C), nitrogen (N), oxygen (O), fluorine (F), silicon (Si), phosphorus (P) and sulphur (S). Use of said method to obtain a capacitive touch panel having a high transmission in the visible range.
    Type: Grant
    Filed: March 23, 2015
    Date of Patent: April 20, 2021
    Assignee: IONICS FRANCE
    Inventors: Denis Busardo, Frederic Guernalec
  • Patent number: 10923310
    Abstract: Process for treatment of a sapphire part with a beam of a mixture of mono- and multicharged ions of a gas which are produced by an electron cyclotron resonance (ECR) source, where: the voltage for acceleration of the ions is between 10 kV and 100 kV; the implanted dose, expressed in ions/cm2, is between (5×1016)×(M/14)?1/2 and 1017×(M/14)?1/2, where M is the atomic mass of the ion; the rate of displacement VD, expressed in cm/s, is between 0.025×(P/D) and 0.1×(P/D), where P is the power of the beam, expressed in W (watts), and D is the diameter of the beam, expressed in cm (centimetres). A part made of sapphire having a high transmittance and which is resistant to scratching is thus advantageously obtained.
    Type: Grant
    Filed: February 12, 2018
    Date of Patent: February 16, 2021
    Assignee: IONICS FRANCE
    Inventors: Denis Busardo, Frédéric Guernalec
  • Patent number: 10737242
    Abstract: A method of treating a powder (P) made from cerium oxide using an ion beam (F) in which: —the powder is stirred once or a plurality of times; —the ions of the ion beam are selected from the ions of the elements of the list consisting of helium (He), boron (B), carbon (C), nitrogen (N), oxygen (O), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe)—the acceleration voltage of the ions of the beam is between 10 kV and 1000 kV; —the treatment temperature of the powder (P) is less than or equal to Tf/3; —the ion dose per mass unit of powder to be treated is chosen from a range of between 1016 ions/g and 1022 ions/cm2 so as to lower the reduction temperature of the powder made from cerium oxide (P).
    Type: Grant
    Filed: April 30, 2018
    Date of Patent: August 11, 2020
    Assignee: IONICS FRANCE
    Inventors: Denis Busardo, Frederic Guernalec
  • Patent number: 10703674
    Abstract: The invention concerns a process for increasing the scratch resistance of a glass substrate by implantation of simple charge and multicharge ions, comprising maintaining the temperature of the area of the glass substrate being treated at a temperature that is less than or equal to the glass transition temperature of the glass substrate, selecting the ions to be implanted among the ions of Ar, He, and N, setting the acceleration voltage for the extraction of the ions at a value comprised between 5 kV and 200 kV and setting the ion dosage at a value comprised between 1014 ions/cm2 and 2.5×1017 ions/cm2.The invention further concerns glass substrates comprising an area treated by implantation of simple charge and multicharge ions according to this process and their use for reducing the probability of scratching on the glass substrate upon mechanical contact.
    Type: Grant
    Filed: October 21, 2015
    Date of Patent: July 7, 2020
    Assignees: AGC GLASS EUROPE, AGC Inc., QUERTECH INGENIERIE
    Inventors: Benjamine Navet, Pierre Boulanger, Lionel Ventelon, Denis Busardo, Frederic Guernalec
  • Patent number: 10655215
    Abstract: The disclosure relates to a treatment method for coloring a metal that includes a) bombardment of the metal with a beam of singly- or multiply-charged gas ions produced by an electron cyclotron resonance source; b) heat treatment in ambient air so as to color the implanted metal using a temperature between 100° C. and 400° C. and an exposure time of between 1 minute and 4 hours.
    Type: Grant
    Filed: January 17, 2017
    Date of Patent: May 19, 2020
    Assignee: IONICS FRANCE
    Inventors: Denis Busardo, Frédéric Guernalec
  • Patent number: 10570060
    Abstract: Process for treatment by an ion beam of a glass material where: the acceleration voltage of the ions is between 5 kV and 1000 kV; the temperature of the glass material is less than or equal to the glass transition temperature; the dose of nitrogen (N) or oxygen (O) ions per unit of surface area is chosen within a range of between 1012 ions/cm2 and 1018 ions/cm2 so as to reduce the contact angle of a drop of water below 20°; a prior pretreatment is carried out with argon (Ar), krypton (Kr) or xenon (Xe) ions in order to strengthen the durability of the superhydrophilic treatment. Superhydrophilic glass materials of long duration are thus advantageously obtained.
    Type: Grant
    Filed: March 26, 2014
    Date of Patent: February 25, 2020
    Assignee: IONICS FRANCE
    Inventors: Denis Busardo, Frédéric Guernalec
  • Publication number: 20200043694
    Abstract: Process for treatment of a sapphire part with a beam of a mixture of mono- and multicharged ions of a gas which are produced by an electron cyclotron resonance (ECR) source, where: the voltage for acceleration of the ions is between 10 kV and 100 kV; the implanted dose, expressed in ions/cm2, is between (5×1016)×(M/14)?1/2 and 1017×(M/14)?1/2, where M is the atomic mass of the ion; the rate of displacement VD, expressed in cm/s, is between 0.025×(P/D) and 0.1×(P/D), where P is the power of the beam, expressed in W (watts), and D is the diameter of the beam, expressed in cm (centimetres). A part made of sapphire having a high transmittance and which is resistant to scratching is thus advantageously obtained.
    Type: Application
    Filed: February 12, 2018
    Publication date: February 6, 2020
    Inventors: Denis Busardo, Frédéric Guernalec
  • Publication number: 20190352770
    Abstract: Method of antireflection and scratch-resistant treatment of a synthetic sapphire material where the acceleration voltage of the ions is between 5 kV and 1000 kV and is chosen in order to create an implanted layer having a thickness equal to a multiple of 100 nm; the microwave-induced annealing temperatures in the implanted surface are between 800° C. and 2000° C. with annealing times of between 1 and 1000 seconds. Synthetic sapphire materials are thus advantageously obtained where the reflection on the treated face is reduced by at least half while maintaining a hardness of greater than or equal to 8.
    Type: Application
    Filed: February 2, 2018
    Publication date: November 21, 2019
    Inventors: Denis Busardo, Frédéric Guernalec
  • Patent number: 10196731
    Abstract: A treatment method for modifying the reflected color of a sapphire material surface comprising bombardment by a single- and/or multi-charged gas ion beam so as to modify the reflected color of the treated sapphire material surface, wherein the ions are selected from ions of the elements from the list consisting of helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), boron (B), carbon (C), nitrogen (N), oxygen (O), fluorine (F), silicon (Si), phosphorus (P) and sulphur (S).
    Type: Grant
    Filed: May 22, 2015
    Date of Patent: February 5, 2019
    Assignee: IONICS FRANCE
    Inventors: Frederic Guernalec, Denis Busardo
  • Publication number: 20190032198
    Abstract: The disclosure relates to a treatment method for coloring a metal that includes a) bombardment of the metal with a beam of singly- or multiply-charged gas ions produced by an electron cyclotron resonance source; b) heat treatment in ambient air so as to color the implanted metal using a temperature between 100° C. and 400° C. and an exposure time of between 1 minute and 4 hours.
    Type: Application
    Filed: January 17, 2017
    Publication date: January 31, 2019
    Inventors: Denis Busardo, Frédéric Guernalec
  • Publication number: 20180265404
    Abstract: A method of treatment using a beam of singly- and multiply-charged gas ions produced by an electron cyclotron resonance (ECR) source of a glass material in which —the ion acceleration voltage of between 5 kV and 1000 kV is chosen to create an implanted layer of a thickness equal to a multiple of 100 nm; —the ion dose per surface unit in a range of between 1012 ions/cm2 and 1018 ions/cm2 is chosen so as to create an atomic concentration of ions equal to 10% with a level of uncertainty of (+/?)5%.
    Type: Application
    Filed: May 10, 2018
    Publication date: September 20, 2018
    Inventors: Denis Busardo, Frederic Guernalec
  • Publication number: 20180243726
    Abstract: A method of treating a powder (P) made from cerium oxide using an ion beam (F) in which: —the powder is stirred once or a plurality of times; —the ions of the ion beam are selected from the ions of the elements of the list consisting of helium (He), boron (B), carbon (C), nitrogen (N), oxygen (O), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe)—the acceleration voltage of the ions of the beam is between 10 kV and 1000 kV; —the treatment temperature of the powder (P) is less than or equal to Tf/3; —the ion dose per mass unit of powder to be treated is chosen from a range of between 1016 ions/g and 1022 ions/cm2 so as to lower the reduction temperature of the powder made from cerium oxide (P).
    Type: Application
    Filed: April 30, 2018
    Publication date: August 30, 2018
    Inventors: Denis Busardo, Frederic Guernalec
  • Patent number: 9988305
    Abstract: A method of treatment using a beam of singly- and multiply-charged gas ions produced by an electron cyclotron resonance (ECR) source of a glass material in which—the ion acceleration voltage of between 5 kV and 1000 kV is chosen to create an implanted layer of a thickness equal to a multiple of 100 nm; —the ion dose per surface unit in a range of between 1012 ions/cm2 and 1018 ions/cm2 is chosen so as to create an atomic concentration of ions equal to 10% with a level of uncertainty of (+/?)5%. Advantageously this makes it possible to obtain materials made from glass that is non-reflective in the visible range.
    Type: Grant
    Filed: February 12, 2014
    Date of Patent: June 5, 2018
    Assignee: IONICS FRANCE
    Inventors: Denis Busardo, Frederic Guernalec
  • Patent number: 9981249
    Abstract: A method of treating a powder (P) made from cerium oxide using an ion beam (F) in which: —the powder is stirred once or a plurality of times; —the ions of the ion beam are selected from the ions of the elements of the list consisting of helium (He), boron (B), carbon (C), nitrogen (N), oxygen (O), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe)—the acceleration voltage of the ions of the beam is between 10 kV and 1000 kV; —the treatment temperature of the powder (P) is less than or equal to Tf/3; —the ion dose per mass unit of powder to be treated is chosen from a range of between 1016 ions/g and 1022 ions/cm2 so as to lower the reduction temperature of the powder made from cerium oxide (P).
    Type: Grant
    Filed: July 24, 2014
    Date of Patent: May 29, 2018
    Assignee: IONICS FRANCE
    Inventors: Denis Busardo, Frederic Guernalec
  • Publication number: 20170334775
    Abstract: The invention concerns a process for increasing the scratch resistance of a glass substrate by implantation of simple charge and multicharge ions, comprising maintaining the temperature of the area of the glass substrate being treated at a temperature that is less than or equal to the glass transition temperature of the glass substrate, selecting the ions to be implanted among the ions of Ar, He, and N, setting the acceleration voltage for the extraction of the ions at a value comprised between 5 kV and 200 kV and setting the ion dosage at a value comprised between 1014 ions/cm2 and 2.5×1017 ions/cm2.The invention further concerns glass substrates comprising an area treated by implantation of simple charge and multicharge ions according to this process and their use for reducing the probability of scratching on the glass substrate upon mechanical contact.
    Type: Application
    Filed: October 21, 2015
    Publication date: November 23, 2017
    Applicants: AGC GLASS EUROPE, ASAHI GLASS CO LTD, QUERTECH INGENIERIE
    Inventors: Benjamine NAVET, Pierre BOULANGER, Lionel VENTELON, Denis BUSARDO, Frederic GUERNALEC
  • Publication number: 20170114442
    Abstract: A treatment method for modifying the reflected colour of a sapphire material surface comprising bombardment by a single- and/or multi-charged gas ion beam so as to modify the reflected colour of the treated sapphire material surface, wherein the ions are selected from ions of the elements from the list consisting of helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), boron (B), carbon (C), nitrogen (N), oxygen (O), fluorine (F), silicon (Si), phosphorus (P) and sulphur (S).
    Type: Application
    Filed: May 22, 2015
    Publication date: April 27, 2017
    Inventors: Frederic Guernalec, Denis Busardo
  • Publication number: 20170107641
    Abstract: A treatment method of a sapphire material, said method comprising bombardment of a surface of the sapphire material, said surface facing a medium different from the sapphire material, by a single- and/or multi-charged gas ion beam so as to produce an ion implanted layer in the sapphire material, wherein the ions are selected from ions of the elements from the list consisting of helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), boron (B), carbon (C), nitrogen (N), oxygen (O), fluorine (F), silicon (Si), phosphorus (P) and sulphur (S). Use of said method to obtain a capacitive touch panel having a high transmission in the visible range.
    Type: Application
    Filed: March 23, 2015
    Publication date: April 20, 2017
    Inventors: Denis Busardo, Frédéric Guernalec
  • Publication number: 20160193589
    Abstract: A method of treating a powder (P) made from cerium oxide using an ion beam (F) in which: the powder is stirred once or a plurality of times; the ions of the ion beam are selected from the ions of the elements of the list consisting of helium (He), boron (B), carbon (C), nitrogen (N), oxygen (O), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe) the acceleration voltage of the ions of the beam is between 10 kV and 1000 kV; the treatment temperature of the powder (P) is less than or equal to Tf/3; the ion dose per mass unit of powder to be treated is chosen from a range of between 1016 ions/g and 1022 ions/cm2 so as to lower the reduction temperature of the powder made from cerium oxide (P).
    Type: Application
    Filed: July 24, 2014
    Publication date: July 7, 2016
    Applicant: QUERTECH
    Inventors: Denis Busardo, Frederic Guernalec
  • Publication number: 20160052821
    Abstract: Process for treatment by an ion beam of a glass material where: the acceleration voltage of the ions is between 5 kV and 1000 kV; the temperature of the glass material is less than or equal to the glass transition temperature; the dose of nitrogen (N) or oxygen (O) ions per unit of surface area is chosen within a range of between 1012 ions/cm2 and 1018 ions/cm2 so as to reduce the contact angle of a drop of water below 20°; a prior pretreatment is carried out with argon (Ar), krypton (Kr) or xenon (Xe) ions in order to stengthen the durability of the superhydrophilic treatment. Superhydrophilic glass materials of long duration are thus advantageously obtained.
    Type: Application
    Filed: March 26, 2014
    Publication date: February 25, 2016
    Applicant: QUERTECH
    Inventors: Denis Busardo, Frédéric Guernalec