Patents by Inventor Frederic Malet

Frederic Malet has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 12071538
    Abstract: A transparent antistatic composition based on polymethyl methacrylate (PMMA), including: 55% to 99.9% by weight of PMMA, and 0.1% to 45% by weight of at least one polyamide (PA) block-containing and polyether (PE) block-containing copolymer (PEBA) including polyethylene glycol (PEG), with respect to the total composition weight, said copolymer being characterized in that it includes in the range 50% to 80% by weight of PEG with respect to the total weight of copolymer.
    Type: Grant
    Filed: August 27, 2018
    Date of Patent: August 27, 2024
    Assignee: ARKEMA FRANCE
    Inventors: Laure Berdin, Damien Rauline, Karine Loyen, Frederic Malet
  • Patent number: 11344654
    Abstract: The present invention relates to the use of a copolymer containing polyether blocks and polyamide blocks for manufacturing an inflatable catheter element, such as a catheter balloon, with improved bursting strength, in which said copolymer has the following characteristics: a number-average molecular mass of the PE blocks greater than 500 g/mol, and a number-average molecular mass of the PA blocks greater than 10,000 g/mol.
    Type: Grant
    Filed: May 8, 2020
    Date of Patent: May 31, 2022
    Assignee: ARKEMA FRANCE
    Inventors: Rene-Paul Eustache, Frederic Malet, Eric Gamache, Alejandra Reyna-Valencia, Damien Rauline
  • Patent number: 11332576
    Abstract: The invention relates to a block copolymer derived from at least one ethylene oxide and/or propylene oxide monomer containing 14C. The present invention also relates to a method for preparing such a block copolymer.
    Type: Grant
    Filed: April 5, 2011
    Date of Patent: May 17, 2022
    Assignee: ARKEMA FRANCE
    Inventors: Frederic Malet, Guillaume Le, Julien Jouanneau
  • Patent number: 10759939
    Abstract: The present invention relates to an impact modified polyamide composition. In particular, the present invention relates to impact modified transparent polyamide compositions comprising a multistage polymer. More particularly, the present invention relates to the use of multistage polymer as impact modifier in a transparent polyamide composition.
    Type: Grant
    Filed: November 4, 2015
    Date of Patent: September 1, 2020
    Assignee: Arkema France
    Inventor: Frederic Malet
  • Publication number: 20200261627
    Abstract: The present invention relates to the use of a copolymer containing polyether blocks and polyamide blocks for manufacturing an inflatable catheter element, such as a catheter balloon, with improved bursting strength, in which said copolymer has the following characteristics: a number-average molecular mass of the PE blocks greater than 500 g/mol, and a number-average molecular mass of the PA blocks greater than 10,000 g/mol.
    Type: Application
    Filed: May 8, 2020
    Publication date: August 20, 2020
    Inventors: Rene-Paul EUSTACHE, Frederic MALET, Eric GAMACHE, Alejandra REYNA-VALENCIA, Damien RAULINE
  • Patent number: 10316127
    Abstract: The present invention relates to a multistage polymer, its composition, its process of preparation, and its use as impact modifier in thermoplastic compositions. More particularly the present invention relates to a process for manufacturing a polymer composition comprising a multistage polymer and its use as impact modifier in thermoplastic compositions.
    Type: Grant
    Filed: November 24, 2015
    Date of Patent: June 11, 2019
    Assignee: Arkema France
    Inventors: Christophe Navarro, Aline O. Couffin, Rosangela Pirri, Frederic Malet
  • Publication number: 20190062545
    Abstract: A transparent antistatic composition based on polymethyl methacrylate (PMMA), including: 55% to 99.9% by weight of PMMA, and 0.1% to 45% by weight of at least one polyamide (PA) block-containing and polyether (PE) block-containing copolymer (PEBA) inlcuding polyethylene glycol (PEG), with respect to the total composition weight, said copolymer being characterized in that it includes in the range 50% to 80% by weight of PEG with respect to the total weight of copolymer.
    Type: Application
    Filed: August 27, 2018
    Publication date: February 28, 2019
    Applicant: ARKEMA FRANCE
    Inventors: Laure BERDIN, Damien Rauline, Karine LOYEN, Frederic Malet
  • Patent number: 9914804
    Abstract: The invention relates to a method for synthesising a block copolymer alloy including at least one rigid polyamide block PA, including the steps of: a) producing said block copolymer; b) adding, during step a) and to at least a portion of said block copolymer, 0.1 to 30 wt % of at least one organic salt in the molten state relative to the total weight of the alloy, so that the alloy thus obtained has improved antistatic properties and identical mechanical properties when compared to the same polymer produced without adding an organic salt. The invention also relates to a block copolymer alloy having improved antistatic properties and obtained by said method, to the use thereof in a polymer matrix, and to a composition containing same.
    Type: Grant
    Filed: February 2, 2010
    Date of Patent: March 13, 2018
    Assignee: ARKEMA FRANCE
    Inventors: Frederic Malet, Eric Gamache, Perrine Babin, Benoit Andre, Michael Werth
  • Publication number: 20180037701
    Abstract: The present invention relates to elastomeric thermoplastic polymers (ETP) and especially technical polymers with high added value used in varied sectors, such as electronics, motor vehicles or sport. The present invention more particularly relates to copolymers containing polyether blocks and polyamide blocks, abbreviated as “PEBA”, which have good antistatic properties. Even more particularly, the invention relates to a copolymer containing at least one polyamide (PA) block, at least one polyethylene glycol (PEG) block and at least one block that is more hydrophobic than the PEG block. A subject of the invention is also a process for synthesizing such thermoplastic elastomers which have good antistatic properties and the use thereof in any type of thermoplastic polymer matrix in order to afford this matrix antistatic properties.
    Type: Application
    Filed: December 18, 2015
    Publication date: February 8, 2018
    Applicant: Arkema France
    Inventors: Alejandra REYNA-VALENCIA, Frederic MALET, Quentin PINEAU
  • Publication number: 20170355801
    Abstract: The present invention relates to a multistage polymer, its composition, its process of preparation, and its use as impact modifier in thermoplastic compositions. More particularly the present invention relates a process for manufacturing a multistage polymer, a multistage polymer in thermoplastic compositions, which provides the composition having satisfying thermal stability.
    Type: Application
    Filed: November 24, 2015
    Publication date: December 14, 2017
    Inventors: Aline O. COUFFIN, Rosangela PIRRI, Frederic MALET
  • Publication number: 20170355802
    Abstract: The present invention relates to a multistage polymer, its composition, its process of preparation, and its use as impact modifier in thermoplastic compositions. More particularly the present invention relates to a process for manufacturing a polymer composition comprising a multistage polymer and its use as impact modifier in thermoplastic compositions.
    Type: Application
    Filed: November 24, 2015
    Publication date: December 14, 2017
    Inventors: Christophe NAVARRO, Aline O. COUFFIN, Rosangela PIRRI, Frederic MALET
  • Patent number: 9809683
    Abstract: The invention relates to a copolymer comprising at least two distinct polyamide blocks and at least one polyether block, and a method for preparation of said copolymer comprising the following steps: —in a first step, the polyamide block PA1 is prepared by polycondensation of chosen monomers: amino acids, lactames or diamines and dicarboxylic acids, in the presence of an appropriate chain limiter; —then, in a second optional step, the polyamide PA1 block obtained is reacted with all or part of the polyether PE blocks, in the presence or absence of a catalyst; —in a third step, the polyamide PA2 block is prepared by polycondensation of the chosen isomers: amino acids, lactams or diamines and dicarboxylic acids, in the presence of an appropriate chain limiter; —in a fourth optional step, the polyamide PA2 block obtained is reacted with all or part of the polyether PE blocks, in the presence or absence of a catalyst; —in a fifth step, PA1 or the reaction medium from step 2 is reacted with PA2 or the reaction med
    Type: Grant
    Filed: October 6, 2014
    Date of Patent: November 7, 2017
    Assignee: Arkema France
    Inventor: Frederic Malet
  • Publication number: 20170306149
    Abstract: The present invention relates to an impact modified polyamide composition. In particular, the present invention relates to impact modified transparent polyarnide compositions comprising a multistage polymer. More particularly, the present invention relates to the use of multistage polymer as impact modifier in a transparent polyamide composition.
    Type: Application
    Filed: November 4, 2015
    Publication date: October 26, 2017
    Inventor: Frederic Malet
  • Patent number: 9579838
    Abstract: The invention relates to a method for converting a polycondensed elastomeric thermoplastic polymer, including a step of extruding the polycondensed elastomeric thermoplastic polymer in the presence of water. The polycondensed elastomeric thermoplastic polymer is in particular chosen from copolymer block amides, copolyethers or copolyester block urethanes, copolyether block esters and the mixtures thereof, and is preferably a copolyether block amide.
    Type: Grant
    Filed: December 23, 2011
    Date of Patent: February 28, 2017
    Assignees: Arkema France, Universite Catholique De Louvain, Association Pour La Recherche Et Le Developpement Des Methodes Et Processus Industriels—Armines
    Inventors: Frederic Malet, Jean-Jacques Flat, Francois Touchaleaume, Jacques Devaux, Patricia Krawczak, Michel Sclavons, Jeremie Soulestin
  • Publication number: 20160251484
    Abstract: The invention relates to a copolymer comprising at least two distinct polyamide blocks and at least one polyether block, and a method for preparation of said copolymer comprising the following steps:—in a first step, the polyamide block PA1 is prepared by polycondensation of chosen monomers: amino acids, lactames or diamines and dicarboxylic acids, in the presence of an appropriate chain limiter;—then, in a second optional step, the polyamide PA1 block obtained is reacted with all or part of the polyether PE blocks, in the presence or absence of a catalyst;—in a third step, the polyamide PA2 block is prepared by polycondensation of the chosen isomers: amino acids, lactams or diamines and dicarboxylic acids, in the presence of an appropriate chain limiter;—in a fourth optional step, the polyamide PA2 block obtained is reacted with all or part of the polyether PE blocks, in the presence or absence of a catalyst;—in a fifth step, PA1 or the reaction medium from step 2 is reacted with PA2 or the reaction medium f
    Type: Application
    Filed: October 6, 2014
    Publication date: September 1, 2016
    Applicant: Arkema France
    Inventor: Frederic MALET
  • Patent number: 9095189
    Abstract: The present invention relates to compositions based on a copolymer comprising homo- or copolyamide polyamide blocks (PA blocks), with the exclusion of completely aromatic PA blocks, and polyether blocks comprising: a) 500 to 10 000 ppm of at least one phenolic antioxidant; b) 0 to 5000 ppm of at least one antioxidant based on phosphorus or based on sulphur; c) 0 to 5000 ppm of at least one UV absorber; d) 200 to 3000 ppm of at least one methylated hindered amine light stabilizer or HALS and/or 200 to 1300 ppm of at least one nonmethylated HALS.
    Type: Grant
    Filed: September 15, 2006
    Date of Patent: August 4, 2015
    Assignee: ARKEMA FRANCE
    Inventor: Frederic Malet
  • Publication number: 20150048541
    Abstract: The invention relates to a method for converting a polycondensed elastomeric thermoplastic polymer, including a step of extruding the polycondensed elastomeric thermoplastic polymer in the presence of water. The polycondensed elastomeric thermoplastic polymer is in particular chosen from copolymer block amides, copolyethers or copolyester block urethanes, copolyether block esters and the mixtures thereof, and is preferably a copolyether block amide.
    Type: Application
    Filed: December 23, 2011
    Publication date: February 19, 2015
    Applicants: ARKEMA FRANCE, ECOLE DES MINES DE DOUAI - ARMINES, UNIVERSITE CATHOLIQUE DE LOUVAIN
    Inventors: Frederic Malet, Jean-Jacques Flat, Francois Touchaleaume, Jacques Devaux, Patricia Krawczak, Michel Sclavons, Jeremie Soulestin
  • Patent number: 8952103
    Abstract: The present invention is a copolymer based on amide units and ether units, wherein the amide units being comprise a major portion of an equimolar combination of at least one diamine and at least one dicarboxylic acid, the diamine(s) is/are mainly cycloaliphatic and the dicarboxylic acid(s) is/are mainly linear and aliphatic, the amide units optionally comprise, but in a minor proportion, at least one other polyamide comonomer, the respective proportions of ether and amide unit monomers are selected in such a way that said copolymer is highly transparent to such an extent that the transmittance at 560 nm on a plate 2 mm thick is greater than 75%; the crystallinity of said copolymer is such that the enthalpy of fusion during the first heating of a ISO DSC (delta Hm(2)) is at least 30 J/g, where the mass is related to the number of amide units contained or of polyamide contained, which fusion corresponds to that of the amide units; and said copolymer has a glass transition temperature of at least 75° C.
    Type: Grant
    Filed: June 8, 2007
    Date of Patent: February 10, 2015
    Assignee: Arkema France
    Inventors: Philippe Blondel, Inci Turan, Thibaut Montanari, Frederic Malet
  • Patent number: 8889822
    Abstract: The invention relates to a process for producing a shaped article having excellent mechanical properties, said article comprising a block copolymer PAX.Y/PE comprising polyamide (PA) blocks alternating with polyether (PE) blocks, prepared from homopolyamide blocks PAX.Y by polycondenstation of linear aliphatic diamines where PAX.Y is selected from the group consisting of PA 10,12; PA 6,18; PA 10,14; and PA 12.12, reacted with polyether PE blocks in the presence of a catalyst to produce a block copolymer PAX.Y/PE, wherein said PE blocks are either PE diols, or PE blocks comprising NH2 ends. The articles formed are either a fabric, film, sheet, rod, pipe, injection-molded component, or a shoe sole; the copolymer PAX.Y/PE has an improved flexural modulus of at least 300 MPa greater than a copolymer polyamide 12/polytetrametylene with the same size of PA block and with the same size of PE block respectively.
    Type: Grant
    Filed: April 9, 2013
    Date of Patent: November 18, 2014
    Assignee: Arkema France
    Inventor: Frederic Malet
  • Publication number: 20130202831
    Abstract: A copolymer containing polyether (PE) block(s) and polyamide (PE) block(s) issued for the manufacture of a transparent article having high-velocity impact resistance, and impact strength. In said copolymer: PA blocks comprise more than 50 mol % of an equimolar combination of at least one cycloaliphatic diamine and of at least one aliphatic dicarboxylic acid having from 12 to 36 carbon atoms, represent 20 to 90% by weight, out of the total weight of the copolymer, have a number-average molecular weight of 1000 to 10 000 g/mol, and the PE blocks represent 10 to 80% by weight, out of the total weight of the copolymer, and have a number-average molecular weight of 200-1000 g/mol.
    Type: Application
    Filed: September 27, 2011
    Publication date: August 8, 2013
    Applicant: ARKEMA FRANCE
    Inventors: Sophie Chhun, Benjamin Saillard, Frederic Malet, Jerome Allanic