Patents by Inventor Frederic Malet
Frederic Malet has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 12071538Abstract: A transparent antistatic composition based on polymethyl methacrylate (PMMA), including: 55% to 99.9% by weight of PMMA, and 0.1% to 45% by weight of at least one polyamide (PA) block-containing and polyether (PE) block-containing copolymer (PEBA) including polyethylene glycol (PEG), with respect to the total composition weight, said copolymer being characterized in that it includes in the range 50% to 80% by weight of PEG with respect to the total weight of copolymer.Type: GrantFiled: August 27, 2018Date of Patent: August 27, 2024Assignee: ARKEMA FRANCEInventors: Laure Berdin, Damien Rauline, Karine Loyen, Frederic Malet
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Patent number: 11344654Abstract: The present invention relates to the use of a copolymer containing polyether blocks and polyamide blocks for manufacturing an inflatable catheter element, such as a catheter balloon, with improved bursting strength, in which said copolymer has the following characteristics: a number-average molecular mass of the PE blocks greater than 500 g/mol, and a number-average molecular mass of the PA blocks greater than 10,000 g/mol.Type: GrantFiled: May 8, 2020Date of Patent: May 31, 2022Assignee: ARKEMA FRANCEInventors: Rene-Paul Eustache, Frederic Malet, Eric Gamache, Alejandra Reyna-Valencia, Damien Rauline
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Patent number: 11332576Abstract: The invention relates to a block copolymer derived from at least one ethylene oxide and/or propylene oxide monomer containing 14C. The present invention also relates to a method for preparing such a block copolymer.Type: GrantFiled: April 5, 2011Date of Patent: May 17, 2022Assignee: ARKEMA FRANCEInventors: Frederic Malet, Guillaume Le, Julien Jouanneau
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Patent number: 10759939Abstract: The present invention relates to an impact modified polyamide composition. In particular, the present invention relates to impact modified transparent polyamide compositions comprising a multistage polymer. More particularly, the present invention relates to the use of multistage polymer as impact modifier in a transparent polyamide composition.Type: GrantFiled: November 4, 2015Date of Patent: September 1, 2020Assignee: Arkema FranceInventor: Frederic Malet
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Publication number: 20200261627Abstract: The present invention relates to the use of a copolymer containing polyether blocks and polyamide blocks for manufacturing an inflatable catheter element, such as a catheter balloon, with improved bursting strength, in which said copolymer has the following characteristics: a number-average molecular mass of the PE blocks greater than 500 g/mol, and a number-average molecular mass of the PA blocks greater than 10,000 g/mol.Type: ApplicationFiled: May 8, 2020Publication date: August 20, 2020Inventors: Rene-Paul EUSTACHE, Frederic MALET, Eric GAMACHE, Alejandra REYNA-VALENCIA, Damien RAULINE
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Patent number: 10316127Abstract: The present invention relates to a multistage polymer, its composition, its process of preparation, and its use as impact modifier in thermoplastic compositions. More particularly the present invention relates to a process for manufacturing a polymer composition comprising a multistage polymer and its use as impact modifier in thermoplastic compositions.Type: GrantFiled: November 24, 2015Date of Patent: June 11, 2019Assignee: Arkema FranceInventors: Christophe Navarro, Aline O. Couffin, Rosangela Pirri, Frederic Malet
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Publication number: 20190062545Abstract: A transparent antistatic composition based on polymethyl methacrylate (PMMA), including: 55% to 99.9% by weight of PMMA, and 0.1% to 45% by weight of at least one polyamide (PA) block-containing and polyether (PE) block-containing copolymer (PEBA) inlcuding polyethylene glycol (PEG), with respect to the total composition weight, said copolymer being characterized in that it includes in the range 50% to 80% by weight of PEG with respect to the total weight of copolymer.Type: ApplicationFiled: August 27, 2018Publication date: February 28, 2019Applicant: ARKEMA FRANCEInventors: Laure BERDIN, Damien Rauline, Karine LOYEN, Frederic Malet
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Patent number: 9914804Abstract: The invention relates to a method for synthesising a block copolymer alloy including at least one rigid polyamide block PA, including the steps of: a) producing said block copolymer; b) adding, during step a) and to at least a portion of said block copolymer, 0.1 to 30 wt % of at least one organic salt in the molten state relative to the total weight of the alloy, so that the alloy thus obtained has improved antistatic properties and identical mechanical properties when compared to the same polymer produced without adding an organic salt. The invention also relates to a block copolymer alloy having improved antistatic properties and obtained by said method, to the use thereof in a polymer matrix, and to a composition containing same.Type: GrantFiled: February 2, 2010Date of Patent: March 13, 2018Assignee: ARKEMA FRANCEInventors: Frederic Malet, Eric Gamache, Perrine Babin, Benoit Andre, Michael Werth
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Publication number: 20180037701Abstract: The present invention relates to elastomeric thermoplastic polymers (ETP) and especially technical polymers with high added value used in varied sectors, such as electronics, motor vehicles or sport. The present invention more particularly relates to copolymers containing polyether blocks and polyamide blocks, abbreviated as “PEBA”, which have good antistatic properties. Even more particularly, the invention relates to a copolymer containing at least one polyamide (PA) block, at least one polyethylene glycol (PEG) block and at least one block that is more hydrophobic than the PEG block. A subject of the invention is also a process for synthesizing such thermoplastic elastomers which have good antistatic properties and the use thereof in any type of thermoplastic polymer matrix in order to afford this matrix antistatic properties.Type: ApplicationFiled: December 18, 2015Publication date: February 8, 2018Applicant: Arkema FranceInventors: Alejandra REYNA-VALENCIA, Frederic MALET, Quentin PINEAU
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Publication number: 20170355801Abstract: The present invention relates to a multistage polymer, its composition, its process of preparation, and its use as impact modifier in thermoplastic compositions. More particularly the present invention relates a process for manufacturing a multistage polymer, a multistage polymer in thermoplastic compositions, which provides the composition having satisfying thermal stability.Type: ApplicationFiled: November 24, 2015Publication date: December 14, 2017Inventors: Aline O. COUFFIN, Rosangela PIRRI, Frederic MALET
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Publication number: 20170355802Abstract: The present invention relates to a multistage polymer, its composition, its process of preparation, and its use as impact modifier in thermoplastic compositions. More particularly the present invention relates to a process for manufacturing a polymer composition comprising a multistage polymer and its use as impact modifier in thermoplastic compositions.Type: ApplicationFiled: November 24, 2015Publication date: December 14, 2017Inventors: Christophe NAVARRO, Aline O. COUFFIN, Rosangela PIRRI, Frederic MALET
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Patent number: 9809683Abstract: The invention relates to a copolymer comprising at least two distinct polyamide blocks and at least one polyether block, and a method for preparation of said copolymer comprising the following steps: —in a first step, the polyamide block PA1 is prepared by polycondensation of chosen monomers: amino acids, lactames or diamines and dicarboxylic acids, in the presence of an appropriate chain limiter; —then, in a second optional step, the polyamide PA1 block obtained is reacted with all or part of the polyether PE blocks, in the presence or absence of a catalyst; —in a third step, the polyamide PA2 block is prepared by polycondensation of the chosen isomers: amino acids, lactams or diamines and dicarboxylic acids, in the presence of an appropriate chain limiter; —in a fourth optional step, the polyamide PA2 block obtained is reacted with all or part of the polyether PE blocks, in the presence or absence of a catalyst; —in a fifth step, PA1 or the reaction medium from step 2 is reacted with PA2 or the reaction medType: GrantFiled: October 6, 2014Date of Patent: November 7, 2017Assignee: Arkema FranceInventor: Frederic Malet
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Publication number: 20170306149Abstract: The present invention relates to an impact modified polyamide composition. In particular, the present invention relates to impact modified transparent polyarnide compositions comprising a multistage polymer. More particularly, the present invention relates to the use of multistage polymer as impact modifier in a transparent polyamide composition.Type: ApplicationFiled: November 4, 2015Publication date: October 26, 2017Inventor: Frederic Malet
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Patent number: 9579838Abstract: The invention relates to a method for converting a polycondensed elastomeric thermoplastic polymer, including a step of extruding the polycondensed elastomeric thermoplastic polymer in the presence of water. The polycondensed elastomeric thermoplastic polymer is in particular chosen from copolymer block amides, copolyethers or copolyester block urethanes, copolyether block esters and the mixtures thereof, and is preferably a copolyether block amide.Type: GrantFiled: December 23, 2011Date of Patent: February 28, 2017Assignees: Arkema France, Universite Catholique De Louvain, Association Pour La Recherche Et Le Developpement Des Methodes Et Processus Industriels—ArminesInventors: Frederic Malet, Jean-Jacques Flat, Francois Touchaleaume, Jacques Devaux, Patricia Krawczak, Michel Sclavons, Jeremie Soulestin
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Publication number: 20160251484Abstract: The invention relates to a copolymer comprising at least two distinct polyamide blocks and at least one polyether block, and a method for preparation of said copolymer comprising the following steps:—in a first step, the polyamide block PA1 is prepared by polycondensation of chosen monomers: amino acids, lactames or diamines and dicarboxylic acids, in the presence of an appropriate chain limiter;—then, in a second optional step, the polyamide PA1 block obtained is reacted with all or part of the polyether PE blocks, in the presence or absence of a catalyst;—in a third step, the polyamide PA2 block is prepared by polycondensation of the chosen isomers: amino acids, lactams or diamines and dicarboxylic acids, in the presence of an appropriate chain limiter;—in a fourth optional step, the polyamide PA2 block obtained is reacted with all or part of the polyether PE blocks, in the presence or absence of a catalyst;—in a fifth step, PA1 or the reaction medium from step 2 is reacted with PA2 or the reaction medium fType: ApplicationFiled: October 6, 2014Publication date: September 1, 2016Applicant: Arkema FranceInventor: Frederic MALET
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Patent number: 9095189Abstract: The present invention relates to compositions based on a copolymer comprising homo- or copolyamide polyamide blocks (PA blocks), with the exclusion of completely aromatic PA blocks, and polyether blocks comprising: a) 500 to 10 000 ppm of at least one phenolic antioxidant; b) 0 to 5000 ppm of at least one antioxidant based on phosphorus or based on sulphur; c) 0 to 5000 ppm of at least one UV absorber; d) 200 to 3000 ppm of at least one methylated hindered amine light stabilizer or HALS and/or 200 to 1300 ppm of at least one nonmethylated HALS.Type: GrantFiled: September 15, 2006Date of Patent: August 4, 2015Assignee: ARKEMA FRANCEInventor: Frederic Malet
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Publication number: 20150048541Abstract: The invention relates to a method for converting a polycondensed elastomeric thermoplastic polymer, including a step of extruding the polycondensed elastomeric thermoplastic polymer in the presence of water. The polycondensed elastomeric thermoplastic polymer is in particular chosen from copolymer block amides, copolyethers or copolyester block urethanes, copolyether block esters and the mixtures thereof, and is preferably a copolyether block amide.Type: ApplicationFiled: December 23, 2011Publication date: February 19, 2015Applicants: ARKEMA FRANCE, ECOLE DES MINES DE DOUAI - ARMINES, UNIVERSITE CATHOLIQUE DE LOUVAINInventors: Frederic Malet, Jean-Jacques Flat, Francois Touchaleaume, Jacques Devaux, Patricia Krawczak, Michel Sclavons, Jeremie Soulestin
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Patent number: 8952103Abstract: The present invention is a copolymer based on amide units and ether units, wherein the amide units being comprise a major portion of an equimolar combination of at least one diamine and at least one dicarboxylic acid, the diamine(s) is/are mainly cycloaliphatic and the dicarboxylic acid(s) is/are mainly linear and aliphatic, the amide units optionally comprise, but in a minor proportion, at least one other polyamide comonomer, the respective proportions of ether and amide unit monomers are selected in such a way that said copolymer is highly transparent to such an extent that the transmittance at 560 nm on a plate 2 mm thick is greater than 75%; the crystallinity of said copolymer is such that the enthalpy of fusion during the first heating of a ISO DSC (delta Hm(2)) is at least 30 J/g, where the mass is related to the number of amide units contained or of polyamide contained, which fusion corresponds to that of the amide units; and said copolymer has a glass transition temperature of at least 75° C.Type: GrantFiled: June 8, 2007Date of Patent: February 10, 2015Assignee: Arkema FranceInventors: Philippe Blondel, Inci Turan, Thibaut Montanari, Frederic Malet
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Patent number: 8889822Abstract: The invention relates to a process for producing a shaped article having excellent mechanical properties, said article comprising a block copolymer PAX.Y/PE comprising polyamide (PA) blocks alternating with polyether (PE) blocks, prepared from homopolyamide blocks PAX.Y by polycondenstation of linear aliphatic diamines where PAX.Y is selected from the group consisting of PA 10,12; PA 6,18; PA 10,14; and PA 12.12, reacted with polyether PE blocks in the presence of a catalyst to produce a block copolymer PAX.Y/PE, wherein said PE blocks are either PE diols, or PE blocks comprising NH2 ends. The articles formed are either a fabric, film, sheet, rod, pipe, injection-molded component, or a shoe sole; the copolymer PAX.Y/PE has an improved flexural modulus of at least 300 MPa greater than a copolymer polyamide 12/polytetrametylene with the same size of PA block and with the same size of PE block respectively.Type: GrantFiled: April 9, 2013Date of Patent: November 18, 2014Assignee: Arkema FranceInventor: Frederic Malet
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Publication number: 20130202831Abstract: A copolymer containing polyether (PE) block(s) and polyamide (PE) block(s) issued for the manufacture of a transparent article having high-velocity impact resistance, and impact strength. In said copolymer: PA blocks comprise more than 50 mol % of an equimolar combination of at least one cycloaliphatic diamine and of at least one aliphatic dicarboxylic acid having from 12 to 36 carbon atoms, represent 20 to 90% by weight, out of the total weight of the copolymer, have a number-average molecular weight of 1000 to 10 000 g/mol, and the PE blocks represent 10 to 80% by weight, out of the total weight of the copolymer, and have a number-average molecular weight of 200-1000 g/mol.Type: ApplicationFiled: September 27, 2011Publication date: August 8, 2013Applicant: ARKEMA FRANCEInventors: Sophie Chhun, Benjamin Saillard, Frederic Malet, Jerome Allanic