Abstract: A solid-state thermochromic device and method for producing the device, the device including: a stack successively including, from a rear face to a front face exposed to solar radiation: a) a solid substrate of an inorganic material resistant up to a temperature of 550° C.; b) an infrared-reflective layer of an electronically conductive material; c) electronically insulating interface layers; d) an electronically insulating inorganic dielectric layer transparent to infrared radiation, of cerium oxide CeO2, with a thickness between 400 and 900 nm; e) electronically insulating interface layers; f) a layer of an infrared-active thermochromic material, an n-doped VO2 vanadium oxide, and crystallized in a monoclinic or rutile phase, with a thickness between 30 and 50 nm; and g) a solar-protective coating, transparent to infrared radiation.

Abstract: A solid-state thermochromic device and method for producing the device, the device including: a stack successively including, from a rear face to a front face exposed to solar radiation: a) a solid substrate of an inorganic material resistant up to a temperature of 550° C.; b) an infrared-reflective layer of an electronically conductive material; c) electronically insulating interface layers; d) an electronically insulating inorganic dielectric layer transparent to infrared radiation, of cerium oxide CeO2, with a thickness between 400 and 900 nm; e) electronically insulating interface layers; f) a layer of an infrared-active thermochromic material, an n-doped VO2 vanadium oxide, and crystallized in a monoclinic or rutile phase, with a thickness between 30 and 50 nm; and g) a solar-protective coating, transparent to infrared radiation.

Abstract: An all-solid electrochromic device with controlled infrared reflection or emission is provided, in particular of electro-controllable type, comprising a stack successively comprising from a back face (3) as far as a front face (1) exposed to infrared radiation (2): a substrate (4) made of an electron-conducting material, or a substrate made of a non-electron-conducting material coated with a layer made of an electron-conducting material, forming a first electrode; a layer made of a first proton storage electrochromic material (5); a layer of a proton-conducting and electron-insulating electrolyte (6); a bilayer comprising a layer of a non-electrochromic, sub-stoichiometric tungsten oxide WO3-y forming a second electrode; said tungsten oxide WO3-y layer being arranged underneath a layer with variable infrared reflection of a second electrochromic material with variable proton intercalation rate, chosen from among crystallized tungsten oxide HxWO3-c and hydrated crystallized tungsten oxide HxWO3.

Abstract: An all-solid electrochromic device with controlled infrared reflection or emission is provided, in particular of electro-controllable type, comprising a stack successively comprising from a back face (3) as far as a front face (1) exposed to infrared radiation (2): a substrate (4) made of an electron-conducting material, or a substrate made of a non-electron-conducting material coated with a layer made of an electron-conducting material, forming a first electrode; a layer made of a first proton storage electrochromic material (5); a layer of a proton-conducting and electron-insulating electrolyte (6); a bilayer comprising a layer of a non-electrochromic, sub-stoichiometric tungsten oxide WO3-y forming a second electrode; said tungsten oxide WO3-y layer being arranged underneath a layer with variable infrared reflection of a second electrochromic material with variable proton intercalation rate, chosen from among crystallized tungsten oxide HxWO3-c and hydrated crystallized tungsten oxide HxWO3.

Abstract: An all-solid electrochromic device with controlled infrared reflection or emission, in particular of electro-controllable type, comprising a stack successively comprising from a back face (3) as far as a front face (1) exposed to infrared radiation (2): a substrate (4) made of an electron-conducting material, or a substrate made of a non-electron-conducting material coated with a layer made of an electron-conducting material, forming a first electrode; a layer made of a first proton storage electrochromic material (5); a layer of a proton-conducting and electron-insulating electrolyte (6); a bilayer comprising a layer of a non-electrochromic, sub-stoichiometric tungsten oxide WO3-y forming a second electrode; said tungsten oxide WO3-y layer being arranged underneath a layer with variable infrared reflection of a second electrochromic material with variable proton intercalation rate, chosen from among crystallized tungsten oxide HxWO3-c and hydrated crystallized tungsten oxide HxWO3.

Abstract: An all-solid electrochromic device with controlled infrared reflection or emission, in particular of electro-controllable type, comprising a stack successively comprising from a back face (3) as far as a front face (1) exposed to infrared radiation (2): a substrate (4) made of an electron-conducting material, or a substrate made of a non-electron-conducting material coated with a layer made of an electron-conducting material, forming a first electrode; a layer made of a first proton storage electrochromic material (5); a layer of a proton-conducting and electron-insulating electrolyte (6); a bilayer comprising a layer of a non-electrochromic, sub-stoichiometric tungsten oxide WO3-y forming a second electrode; said tungsten oxide WO3-y layer being arranged underneath a layer with variable infrared reflection of a second electrochromic material with variable proton intercalation rate, chosen from among crystallized tungsten oxide HxWO3-c and hydrated crystallized tungsten oxide HxWO3.