Patents by Inventor Frederick Carl Wilhelm
Frederick Carl Wilhelm has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 8877673Abstract: A method of making a supported catalyst for reforming of steam and hydrocarbons and a steam-hydrocarbon reforming process using the supported catalyst. The supported catalyst is made from a mixture comprising 20 to 99.5 mass % of lanthanum-stabilized ?-alumina and/or lanthanum-stabilized ?-alumina, 0 to 60 mass % oalumina, 0 to 25 mass % of calcium carbonate and/or magnesium carbonate, and 0.5 to 5 mass % of graphite, a cellulose ether, and/or magnesium stearate. The supported catalyst has a porosity between 55% and 75% and a pore volume between 0.3 cc/g and 0.65 cc/g.Type: GrantFiled: November 8, 2011Date of Patent: November 4, 2014Assignee: Air Products and Chemicals, Inc.Inventors: Diwakar Garg, Frederick Carl Wilhelm
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Publication number: 20130225399Abstract: A method of making a supported catalyst for reforming of steam and hydrocarbons and a steam-hydrocarbon reforming process using the supported catalyst. The supported catalyst is made from a mixture comprising 20 to 99.5 mass % of lanthanum-stabilized ?-alumina and/or lanthanum-stabilized ?-alumina, 0 to 60 mass % oalumina, 0 to 25 mass % of calcium carbonate and/or magnesium carbonate, and 0.5 to 5 mass % of graphite, a cellulose ether, and/or magnesium stearate. The supported catalyst has a porosity between 55% and 75% and a pore volume between 0.3 cc/g and 0.65 cc/g.Type: ApplicationFiled: November 8, 2011Publication date: August 29, 2013Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Diwakar Garg, Frederick Carl Wilhelm
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Patent number: 8038981Abstract: Complex metal oxide-containing pellets and their use for producing hydrogen. The complex metal oxide-containing pellets are suitable for use in a fixed bed reactor due to sufficient crush strength. The complex metal oxide-containing pellets comprise one or more complex metal oxides and at least one of in-situ formed calcium titanate and calcium aluminate. calcium titanate and calcium aluminate are formed by reaction of suitable precursors in a mixture with one or more complex metal carbonates. The complex metal oxide-containing pellets optionally comprise at least one precious metal.Type: GrantFiled: January 13, 2009Date of Patent: October 18, 2011Assignee: Air Products and Chemicals, Inc.Inventors: Diwakar Garg, Robert Quinn, Frederick Carl Wilhelm, Gokhan Alptekin, Margarita Dubovik, Matthew Schaefer
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Patent number: 7897128Abstract: The present invention provides a process for making a complex metal oxide comprising the formula AxByOz. The process comprises the steps of: (a) reacting in solution at a temperature of between about 75° C. to about 100° C. at least one water-soluble salt of A, at least one water-soluble salt of B and a stoichiometric amount of a carbonate salt or a bicarbonate salt required to form a mole of a carbonate precipitate represented by the formula AxBy(CO3)n, wherein the reacting is conducted in a substantial absence of carbon dioxide to form the carbonate precipitate and wherein the molar amount of carbonate salt or bicarbonate salt is at least three times the stoichiometric amount of carbonate or bicarbonate salt required to form a mole of the carbonate precipitate; and (b) reacting the carbonate precipitate with an oxygen containing fluid under conditions to form the complex metal oxide.Type: GrantFiled: April 20, 2007Date of Patent: March 1, 2011Assignee: Air Products and Chemicals, Inc.Inventors: Robert Quinn, Diwakar Garg, Frederick Carl Wilhelm, Terry Lee Slager
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Publication number: 20100196259Abstract: CO2 sorptive pellets and/or granules and their use for removing CO2 from CO2-containing gases and for producing hydrogen. CO2 sorptive pellets are suitable for use in fixed bed reactors and the like due to sufficient crush strength. CO2 sorptive granules are suitable for moving, ebullated, expanded and fluidized beds. The CO2 sorptive pellets and/or granules comprise calcium oxide and/or magnesium oxide and at least one binding agent such as calcium titanate, calcium aluminate, calcium zirconate, magnesium titanate, magnesium aluminate, and magnesium zirconate. A method for making the CO2-sorptive pellets is described. The CO2 sorptive pellets optionally comprise at Ni, Pd, Pt, and/or Rh.Type: ApplicationFiled: December 3, 2009Publication date: August 5, 2010Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Diwakar Garg, Frederick Carl Wilhelm
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Publication number: 20100068130Abstract: The present invention provides a process for producing a gaseous product comprising hydrogen, said process comprising: contacting a feed gas mixture comprising steam and a gas comprising from 1 to 5 carbon atoms with a catalyst structure under reaction conditions sufficient to produce the product gas comprising hydrogen, wherein the catalyst structure comprises: a metal substrate comprising a metal; at least one layer of a catalyst support material coated onto the metal substrate, wherein the catalyst support material comprises: ?-alumina, zirconia, and at least one rare earth metal oxide; and at least one catalytically active component, wherein the at least one catalytically active component is incorporated either into or onto the catalyst support material.Type: ApplicationFiled: September 17, 2008Publication date: March 18, 2010Inventors: Frederick Carl Wilhelm, Robert R. Broekhuis, Diwakar Garg, Sudipta Chattopadhyay, William B. Retallick
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Publication number: 20090196822Abstract: Complex metal oxide-containing pellets and their use for producing hydrogen. The complex metal oxide-containing pellets are suitable for use in a fixed bed reactor due to sufficient crush strength. The complex metal oxide-containing pellets comprise one or more complex metal oxides and at least one of in-situ formed calcium titanate and calcium aluminate. calcium titanate and calcium aluminate are formed by reaction of suitable precursors in a mixture with one or more complex metal carbonates. The complex metal oxide-containing pellets optionally comprise at least one precious metal.Type: ApplicationFiled: January 13, 2009Publication date: August 6, 2009Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Diwakar Garg, Robert Quinn, Frederick Carl Wilhelm, Gokhan Alptekin, Margarita Dubovik, Matthew Schaefer
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Publication number: 20080260621Abstract: The present invention provides a process for making a complex metal oxide comprising the formula AxByOz. The process comprises the steps of: (a) reacting in solution at a temperature of between about 75° C. to about 100° C. at least one water-soluble salt of A, at least one water-soluble salt of B and a stoichiometric amount of a carbonate salt or a bicarbonate salt required to form a mole of a carbonate precipitate represented by the formula AxBy(CO3)n, wherein the reacting is conducted in a substantial absence of carbon dioxide to form the carbonate precipitate and wherein the molar amount of carbonate salt or bicarbonate salt is at least three times the stoichiometric amount of carbonate or bicarbonate salt required to form a mole of the carbonate precipitate; and (b) reacting the carbonate precipitate with an oxygen containing fluid under conditions to form the complex metal oxide.Type: ApplicationFiled: April 20, 2007Publication date: October 23, 2008Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Robert Quinn, Diwakar Garg, Frederick Carl Wilhelm, Terry Lee Slager
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Patent number: 7351395Abstract: Processes are provided for the storage and release of hydrogen by means of a substantially reversible catalytic hydrogenation of extended pi-conjugated substrates which include large polycyclic aromatic hydrocarbons, polycyclic aromatic hydrocarbons with nitrogen heteroatoms, polycyclic aromatic hydrocarbons with oxygen heteroatoms, polycyclic aromatic hydrocarbons with alkyl, alkoxy, nitrile, ketone, ether or polyether substituents, pi-conjugated molecules comprising 5 membered rings, pi-conjugated molecules comprising six and five membered rings with nitrogen or oxygen hetero atoms, and extended pi-conjugated organic polymers. The hydrogen, contained in the at least partially hydrogenated form of the extended pi-conjugated system, can be facilely released for use by a catalytic dehydrogenation of the latter in the presence of a dehydrogenation catalyst which can be effected by lowering the hydrogen gas pressure, generally to pressures greater than 0.1 bar or raising the temperature to less than 250° C.Type: GrantFiled: November 4, 2005Date of Patent: April 1, 2008Assignee: Air Products and Chemicals, Inc.Inventors: Guido Peter Pez, Aaron Raymond Scott, Alan Charles Cooper, Hansong Cheng, Frederick Carl Wilhelm, Atteye Houssein Abdourazak
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Patent number: 6774264Abstract: This invention relates to an improvement in a process for effecting decolorization of an alkanolamine by subjecting the alkanolamine to hydrogenation in the presence of a hydrogenation catalyst. The improvement for removing color, by-products, or both from a dialkylalkanolamine represented by the formula: wherein R and R1 are methyl, ethyl, or a mixture thereof, which comprises: utilizing a catalyst comprised of palladium carried on gamma alumina as the hydrogenation catalyst.Type: GrantFiled: December 6, 2002Date of Patent: August 10, 2004Assignee: Air Products and Chemicals, Inc.Inventors: Nathalie Cecile Delanghe, Gamini Ananda Vedage, Frederick Carl Wilhelm
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Publication number: 20040110988Abstract: This invention relates to an improvement in a process for effecting decolorization of an alkanolamine by subjecting the alkanolamine to hydrogenation in the presence of a hydrogenation catalyst.Type: ApplicationFiled: December 6, 2002Publication date: June 10, 2004Inventors: Nathalie Cecile Delanghe, Gamini Ananda Vedage, Frederick Carl Wilhelm
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Patent number: 6610628Abstract: The present invention relates to an improved monolith catalytic reactor and a monolith support. The improvement in the support resides in a polymer network/carbon coating applied to the surface of a porous substrate and a catalytic metal, preferably a transition metal catalyst applied to the surface of the polymer network/carbon coating. The monolith support has from 100 to 800 cells per square inch and a polymer network/carbon coating with surface area of from 0.1 to 15 m2/gram as measured by adsorption of N2 or Kr using the BET method.Type: GrantFiled: May 30, 2001Date of Patent: August 26, 2003Assignee: Air Products and Chemicals, Inc.Inventors: Andrew Francis Nordquist, Frederick Carl Wilhelm, Francis Joseph Waller, Reinaldo Mario Machado
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Publication number: 20030036477Abstract: The present invention relates to monolith catalysts comprising a catalytic metal deposited onto a coated monolith substrate comprising a wash coat applied to a monolith substrate wherein the monolith catalysts have a surface area ranging from 0.1 to 25 m2/gram as measured by adsorption of N2 or Kr using the BET method. The invention also relates to the coated monolith substrates used in such monolith catalysts. The monolith catalysts of the present invention are particularly suited toward use in hydrogenation processes which employ an immiscible mixture of an organic reactant in water.Type: ApplicationFiled: October 26, 2001Publication date: February 20, 2003Inventors: Andrew Francis Nordquist, Frederick Carl Wilhelm, Francis Joseph Waller, Reinaldo Mario Machado
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Patent number: 6521791Abstract: The invention is a process to regenerate monolith catalytic reactors employed in the liquid phase hydrogenation reactions, particularly those kinds of reactions involving nitroaromatic compounds. The catalytic metals in the monolith catalytic reactor are deactivated by carbonaceous and deactivating byproducts and must be regenerated to extend the catalyst service life and reduce costs. The regeneration process involves two steps: initially passing an oxidizing gaseous mixture through the monolith catalytic reactor at an elevated temperature and for a time sufficient to remove carbonaceous and deactivating byproducts; and then passing a reducing gas though the monolith catalytic reactor previously exposed to the oxidizing gas under conditions for reducing the catalytic metal to its reduced state.Type: GrantFiled: November 9, 2001Date of Patent: February 18, 2003Assignee: Air Products and Chemicals, Inc.Inventors: Keith Allen Welp, Anthony Rocco Cartolano, Frederick Carl Wilhelm, William Joseph Mazzafro
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Publication number: 20030027718Abstract: The present invention relates to an improved monolith catalytic reactor and a monolith support. The improvement in the support resides in a polymer network/carbon coating applied to the surface of a porous substrate and a catalytic metal, preferably a transition metal catalyst applied to the surface of the polymer network/carbon coating. The monolith support has from 100 to 800 cells per square inch and a polymer network/carbon coating with surface area of from 0.1 to 15 m2/gram as measured by adsorption of N2 or Kr using the BET method.Type: ApplicationFiled: May 30, 2001Publication date: February 6, 2003Inventors: Andrew Francis Nordquist, Frederick Carl Wilhelm, Francis Joseph Waller, Reinaldo Mario Machado
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Patent number: 6479704Abstract: The present invention relates to an improved for the hydrogenation of an immiscible mixture of an organic reactant in water. The immiscible mixture can result from the generation of water by the hydrogenation reaction itself or, by the addition of, water to the reactant prior to contact with the catalyst. The improvement resides in effecting the hydrogenation reaction in a monolith catalytic reactor from 100 to 800 cpi, at a superficial velocity of from 0.1 to 2 m/second in the absence of a cosolvent for the immiscible mixture. In a preferred embodiment, the hydrogenation is carried out using a monolith support which has a polymer network/carbon coating onto which a transition metal is deposited.Type: GrantFiled: April 20, 2001Date of Patent: November 12, 2002Assignee: Air Products and Chemicals, Inc.Inventors: Andrew Francis Nordquist, Frederick Carl Wilhelm, Francis Joseph Waller, Reinaldo Mario Machado
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Publication number: 20020147364Abstract: Active fluoride catalysts that are useful in producing electrophilic fluorination agents; especially useful in producing BDM from the reaction of fluorine with carbon dioxide and FTM from the reaction of fluorine with carbonyl fluoride. The fluoride catalyst comprises a mixture of two or more fluorides selected from a transition metal fluoride, an alkali metal fluoride and/or an alkaline earth metal fluoride. Alternately, the fluoride catalyst is one or more fluorides, such as alkali metal fluorides, alkaline earth metal fluorides, and/or transition metal fluorides, deposited on an inert support.Type: ApplicationFiled: February 15, 2001Publication date: October 10, 2002Inventors: Robert George Syvret, Philip Bruce Henderson, Donald Elson Fowler, Beth Ann Campion, Frederick Carl Wilhelm
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Patent number: 6184416Abstract: This invention relates to an improvement in a process for the catalytic hydrogenation of aromatic amines and to the resultant catalyst. The basic process for hydrogenating both mononuclear and polynuclear aromatic amines comprises contacting an aromatic amine with hydrogen in the presence of a rhodium catalyst under conditions for effecting ring hydrogenation. The improvement in the ring hydrogenation process resides in the use of a rhodium catalyst carried on a lithium aluminate support. Often ruthenium is included.Type: GrantFiled: April 28, 2000Date of Patent: February 6, 2001Assignee: Air Products and Chemicals, Inc.Inventors: Hao Ding, John Nelson Armor, Lenore Ann Emig, Dorai Ramprasad, Gamini Ananda Vedage, Frederick Carl Wilhelm