Patents by Inventor Frederick K. Mallon
Frederick K. Mallon has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 9115244Abstract: The invention concerns processes for forming polymer crumb comprising residues of 2-(4-amino phenyl)-5 (6) amino benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride, comprising the steps of: (a) forming a slurry of b mole percent DAPBI and y mole percent PPD in a solvent system comprising organic solvent and c weight percent of an inorganic salt, wherein the inorganic salt is present in an amount of at least 5 weight percent of the organic solvent, DAPBI and PPD being present in an amount sufficient for providing a polymer solution having a weight percent solids of 12 percent or greater on a polymer basis; and (b) contacting the slurry of step a) with a stoichiometric amount of terephthaloyl dichloride to form a product comprising the polymer; wherein the sum of y+b is 100 and the product of b×c is 225 or greater.Type: GrantFiled: November 21, 2014Date of Patent: August 25, 2015Assignee: E I DU PONT DE NEMOURS AND COMPANYInventor: Frederick K Mallon
-
Patent number: 9102788Abstract: The invention concerns processes for forming polymer crumb comprising residues of 2-(4-amino phenyl)-5 (6) amino benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride (TCl), comprising the steps of: i) forming a slurry of b mole percent DAPBI in a solvent system comprising organic solvent and c weight percent of an inorganic salt, wherein the inorganic salt is present in an amount of at least 5 weight present of the organic solvent; ii) contacting the slurry with a less than stoichiometric amount of terephthaloyl chloride to form an prepolymer solution; and iii) contacting the prepolymer solution with y mole percent of PPD and additional TCL to form a polymer solution; wherein the total amount of TCL added in steps ii) and iii) is a stoichiometric amount based on the total amount of DAPBI and PPD added in steps i) and iii); the DAPBI and PPD are added in an amount sufficient for providing a polymer solution having a weight percent solids of 12 percent or greater on a polymer basis;Type: GrantFiled: November 20, 2014Date of Patent: August 11, 2015Assignee: E I DU PONT DE NEMOURS AND COMPANYInventor: Frederick K Mallon
-
Publication number: 20150087801Abstract: The invention concerns processes for forming polymer crumb comprising residues of 2-(4-amino phenyl)-5 (6) amino benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride (TCl), comprising the steps of: i) forming a slurry of b mole percent DAPBI in a solvent system comprising organic solvent and c weight percent of an inorganic salt, wherein the inorganic salt is present in an amount of at least 5 weight present of the organic solvent; ii) contacting the slurry with a less than stoichiometric amount of terephthaloyl chloride to form an prepolymer solution; and iii) contacting the prepolymer solution with y mole percent of PPD and additional TCL to form a polymer solution; wherein the total amount of TCL added in steps ii) and iii) is a stoichiometric amount based on the total amount of DAPBI and PPD added in steps i) and iii); the DAPBI and PPD are added in an amount sufficient for providing a polymer solution having a weight percent solids of 12 percent or greater on a polymer basis;Type: ApplicationFiled: November 20, 2014Publication date: March 26, 2015Inventor: FREDERICK K. MALLON
-
Publication number: 20150080548Abstract: The invention concerns processes for forming polymer crumb comprising residues of 2-(4-amino phenyl)-5 (6) amino benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride, comprising the steps of: (a) forming a slurry of b mole percent DAPBI and y mole percent PPD in a solvent system comprising organic solvent and c weight percent of an inorganic salt, wherein the inorganic salt is present in an amount of at least 5 weight percent of the organic solvent, DAPBI and PPD being present in an amount sufficient for providing a polymer solution having a weight percent solids of 12 percent or greater on a polymer basis; and (b) contacting the slurry of step a) with a stoichiometric amount of terephthaloyl dichloride to form a product comprising the polymer; wherein the sum of y+b is 100 and the product of b×c is 225 or greater.Type: ApplicationFiled: November 21, 2014Publication date: March 19, 2015Inventor: FREDERICK K MALLON
-
Patent number: 8921511Abstract: The invention concerns processes for forming polymer crumb comprising residues of 2-(4-amino phenyl)-5 (6) amino benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride (TCl), comprising the steps of: i) forming a slurry of b mole percent DAPBI in a solvent system comprising organic solvent and c weight percent of an inorganic salt, wherein the inorganic salt is present in an amount of at least 5 weight present of the organic solvent; ii) contacting the slurry with a less than stoichiometric amount of terephthaloyl chloride to form an prepolymer solution; and iii) contacting the prepolymer solution with y mole percent of PPD and additional TCL to form a polymer solution; wherein the total amount of TCL added in steps ii) and iii) is a stoichiometric amount based on the total amount of DAPBI and PPD added in steps i) and iii); the DAPBI and PPD are added in an amount sufficient for providing a polymer solution having a weight percent solids of 12 percent or greater on a polymer basis;Type: GrantFiled: July 27, 2012Date of Patent: December 30, 2014Assignee: E I du Pont de Nemours and CompanyInventor: Frederick K Mallon
-
Patent number: 8921512Abstract: The invention concerns processes for forming polymer crumb comprising residues of 2-(4-amino phenyl)-5(6)amino benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride, comprising the steps of: (a) forming a slurry of b mole percent DAPBI and y mole percent PPD in a solvent system comprising organic solvent and c weight percent of an inorganic salt, wherein the inorganic salt is present in an amount of at least 5 weight percent of the organic solvent, DAPBI and PPD being present in an amount sufficient for providing a polymer solution having a weight percent solids of 12 percent or greater on a polymer basis; and (b) contacting the slurry of step a) with a stoichiometric amount of terephthaloyl dichloride to form a product comprising the polymer; wherein the sum of y+b is 100 and the product of b×c is 225 or greater.Type: GrantFiled: July 27, 2012Date of Patent: December 30, 2014Assignee: E I du Pont de Nemours and CompanyInventor: Frederick K Mallon
-
Patent number: 8716430Abstract: The invention concerns polymer comprising residues of 2-(4-amino phenyl)-5 (6) amino benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride, made by a process comprising the steps of: (a) forming a slurry of b mole percent DAPBI and y mole percent PPD in a solvent system comprising organic solvent and c weight percent of an inorganic salt, wherein the inorganic salt is present in an amount of at least 5 weight percent of the organic solvent, DAPBI and PPD being present in an amount sufficient for providing a polymer solution having a weight percent solids of 12 percent or greater on a polymer basis; and (b) contacting the slurry of step a) with a stoichiometric amount of terephthaloyl dichloride to form a product comprising the polymer; wherein the sum of y+b is 100 and the product of b×c is 225 or greater.Type: GrantFiled: July 27, 2012Date of Patent: May 6, 2014Assignee: E I du Pont de Nemours and CompanyInventor: Frederick K Mallon
-
Patent number: 8664348Abstract: New triaminophenol compositions and related compounds are disclosed, as are processes for their preparation and for the preparation of novel salts and diacid complexes from such compounds. Polymers prepared from these compositions can be made into high strength fiber, film, and tape and are useful in applications such as protective apparel, aircraft, automotive components, personal electronics, and sports equipment.Type: GrantFiled: December 21, 2010Date of Patent: March 4, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Rajiv Dhawan, Joachim C Ritter, Frederick K Mallon, Steven R Allen, David J Rodini, Roger K Siemionko
-
Publication number: 20140031477Abstract: The invention concerns processes for forming polymer crumb comprising residues of 2-(4-amino phenyl)-5 (6) amino phenyl benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride (TCl), comprising the steps of: i) forming a slurry of b mole percent DAPBI in a solvent system comprising organic solvent and c weight percent of an inorganic salt, wherein the inorganic salt is present in an amount of at least 5 weight present of the organic solvent; ii) contacting the slurry with a less than stoichiometric amount of terephthaloyl chloride to form an prepolymer solution; and iii) contacting the prepolymer solution with y mole percent of PPD and additional TCL to form a polymer solution; wherein the total amount of TCL added in steps ii) and iii) is a stoichiometric amount based on the total amount of DAPBI and PPD added in steps i) and iii); the DAPBI and PPD are added in an amount sufficient for providing a polymer solution having a weight percent solids of 12 percent or greater on a polymerType: ApplicationFiled: July 27, 2012Publication date: January 30, 2014Applicant: E I DU PONT DE NEMOURS AND COMPANYInventor: FREDERICK K. MALLON
-
Publication number: 20130197147Abstract: The invention concerns processes for forming polymer crumb comprising residues of 2- (4-amino phenyl)-5 (6) amino phenyl benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride, comprising the steps of: (a) forming a slurry of b mole percent DAPBI and y mole percent PPD in a solvent system comprising organic solvent and c weight percent of an inorganic salt, wherein the inorganic salt is present in an amount of at least 5 weight percent of the organic solvent, DAPBI and PPD being present in an amount sufficient for providing a polymer solution having a weight percent solids of 12 percent or greater on a polymer basis; and (b) contacting the slurry of step a) with a stoichiometric amount of terephthaloyl dichloride to form a product comprising the polymer; wherein the sum of y+b is 100 and the product of b×c is 225 or greater.Type: ApplicationFiled: July 27, 2012Publication date: August 1, 2013Applicant: E I DU PONT DE NEMOURS AND COMPANYInventor: FREDERICK K. MALLON
-
Publication number: 20130197185Abstract: The invention concerns polymer comprising residues of 2-(4-amino phenyl)-5 (6) amino phenyl benzimidazole (DAPBI), paraphenylene diamine (PPD), and terephthaloyl dichloride, made by a process comprising the steps of: (a) forming a slurry of b mole percent DAPBI and y mole percent PPD in a solvent system comprising organic solvent and c weight percent of an inorganic salt, wherein the inorganic salt is present in an amount of at least 5 weight percent of the organic solvent, DAPBI and PPD being present in an amount sufficient for providing a polymer solution having a weight percent solids of 12 percent or greater on a polymer basis; and (b) contacting the slurry of step a) with a stoichiometric amount of terephthaloyl dichloride to form a product comprising the polymer; wherein the sum of y+b is 100 and the product of b×c is 225 or greater.Type: ApplicationFiled: July 27, 2012Publication date: August 1, 2013Applicant: E I DU PONT DE NEMOURS AND COMPANYInventor: FREDERICK K. MALLON
-
Publication number: 20130018138Abstract: The invention concerns copolymer crumb derived from the copolymerization of para-phenylenediamine, 5(6)-amino-2-(p-aminophenyl)benzimidazole, and terephthaloyl dichloride having an inherent viscosity of at least 3 dl/g having less than 0.4 mol/Kg of titrate-able acid. In addition, the invention concerns filaments and yarn formed from such polymer crumb and processes for forming the filaments and yarn.Type: ApplicationFiled: January 13, 2012Publication date: January 17, 2013Applicant: E.I. DU PONT DE NEMOURS AND COMPANYInventors: KIU-SEUNG LEE, FREDERICK K. MALLON, CHRISTOPHER WILLIAM NEWTON
-
Publication number: 20130012679Abstract: New triaminophenol compositions and related compounds are disclosed, as are processes for their preparation and for the preparation of novel salts and diacid complexes from such compounds. Polymers prepared from these compositions can be made into high strength fiber, film, and tape and are useful in applications such as protective apparel, aircraft, automotive components, personal electronics, and sports equipment.Type: ApplicationFiled: December 21, 2010Publication date: January 10, 2013Applicant: E I DU PONT DE NEMOURS AND COMPANYInventors: Rajiv Dhawan, Joachim C. Ritter, Frederick K. Mallon, Steven R. Allen, David J. Rodini, Roger K. Siamionko
-
Patent number: 7009028Abstract: In a two-step precondensate process for preparing polyamides diamines are reacted with dicarboxylic acid dihalides in a polar, non-basic, inert organic liquid medium under conditions such that a condensation product having a low degree of polymerization is formed. The resulting condensation then is contacted with an aqueous solution of a water-soluble acid acceptor by continuously feeding the components into a reactor system having a total residence time from about 2 seconds to about 2 minutes, and having a Peclet number greater than about 3.5 to form a polyamide product having a high degree of polymerization.Type: GrantFiled: May 16, 2003Date of Patent: March 7, 2006Assignee: E. I. du Pont de Nemours and CompanyInventors: Arthur William Etchells, III, Frederick K. Mallon
-
Publication number: 20040230027Abstract: In a two-step precondensate process for preparing polyamides diamines are reacted with dicarboxylic acid dihalides in a polar, non-basic, inert organic liquid medium under conditions such that a condensation product having a low degree of polymerization is formed. The resulting condensation then is contacted with an aqueous solution of a water-soluble acid acceptor by continuously feeding the components into a reactor system having a total residence time from about 2 seconds to about 2 minutes, and having a Peclet number greater than about 3.5 to form a polyamide product having a high degree of polymerization.Type: ApplicationFiled: May 16, 2003Publication date: November 18, 2004Inventors: Arthur William Etchells, Frederick K. Mallon
-
Patent number: 6541598Abstract: A composition that can be used as catalyst is disclosed. The composition comprises, or is produced by combining, (A) a titanium compound; (B) either (i) a complexing agent, (ii) a combination of a complexing agent, hypophosphorous acid or a salt thereof, and optionally a solvent, a zirconium compound, or both, (iii) combinations thereof; (C) a phosphorus compound; and optionally a solvent. Also disclosed is a process that can be used for producing a polyester. The process comprises contacting, in the presence of an esterification or transesterification or polycondensation catalyst composition and a phosphorus compound, a carbonyl compound and an alcohol under a condition suitable for esterification, transesterification, or polymerization. Further disclosed is a process to make polyester with reduced insoluble particles or solids using a phosphorus compound other than the commonly used phosphoric acid.Type: GrantFiled: July 16, 2002Date of Patent: April 1, 2003Assignee: E. I. du Pont de Nemours and CompanyInventors: Jiwen F. Duan, Donald E. Putzig, Frederick K. Mallon, Timothy M. Davis
-
Publication number: 20030045672Abstract: A composition that can be used as catalyst is disclosed. The composition comprises, or is produced by combining, (A) a titanium compound; (B) either (i) a complexing agent, (ii) a combination of a complexing agent, hypophosphorous acid or a salt thereof, and optionally a solvent, a zirconium compound, or both, (iii) combinations thereof; (C) a phosphorus compound; and optionally a solvent. Also disclosed is a process that can be used for producing a polyester. The process comprises contacting, in the presence of an esterification or transesterification or polycondensation catalyst composition and a phosphorus compound, a carbonyl compound and an alcohol under a condition suitable for esterification, transesterification, or polymerization. Further disclosed is a process to make polyester with reduced insoluble particles or solids using a phosphorus compound other than the commonly used phosphoric acid.Type: ApplicationFiled: July 16, 2002Publication date: March 6, 2003Inventors: Jiwen F. Duan, Donald E. Putzig, Frederick K. Mallon, Timothy M. Davis
-
Patent number: 6489433Abstract: A composition that can be used as catalyst is disclosed. The composition comprises, or is produced by combining, (A) a titanium compound; (B) either (i) a complexing agent, (ii) a combination of a complexing agent, hypophosphorous acid or a salt thereof, and optionally a solvent, a zirconium compound, or both, (iii) combinations thereof; (C) a phosphorus compound; and optionally a solvent. Also disclosed is a process that can be used for producing a polyester. The process comprises contacting, in the presence of an esterification or transesterification or polycondensation catalyst composition and a phosphorus compound, a carbonyl compound and an alcohol under a condition suitable for esterification, transesterification, or polymerization. Further disclosed is a process to make polyester with reduced insoluble particles or solids using a phosphorus compound other than the commonly used phosphoric acid.Type: GrantFiled: February 23, 2001Date of Patent: December 3, 2002Assignee: E. I. du Pont de Nemours and CompanyInventors: Jiwen F. Duan, Donald E. Putzig, Frederick K. Mallon, Timothy M. Davis
-
Publication number: 20020165336Abstract: A composition that can be used as catalyst is disclosed. The composition comprises, or is produced by combining, (A) a titanium compound; (B) either (i) a complexing agent, (ii) a combination of a complexing agent, hypophosphorous acid or a salt thereof, and optionally a solvent, a zirconium compound, or both, (iii) combinations thereof; (C) a phosphorus compound; and optionally a solvent. Also disclosed is a process that can be used for producing a polyester. The process comprises contacting, in the presence of an esterification or transesterification or polycondensation catalyst composition and a phosphorus compound, a carbonyl compound and an alcohol under a condition suitable for esterification, transesterification, or polymerization. Further disclosed is a process to make polyester with reduced insoluble particles or solids using a phosphorus compound other than the commonly used phosphoric acid.Type: ApplicationFiled: February 23, 2001Publication date: November 7, 2002Inventors: Jiwen F. Duan, Donald E. Putzig, Frederick K. Mallon, Timothy M. Davis