Patents by Inventor Frederick R. Hopf

Frederick R. Hopf has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5190565
    Abstract: A new class of sulfonated 2-(2'-hydroxyaryl)-2H-benzotriazole compounds and method for using them and other sulfonated hydroxyaryl benzotriazoles on nylon fibers to improve stain resistance and dye lightfastness has been discovered. A process is provided for improving stain resistance of nylon fibers by treatment with sulfonated aromatic-formaldehyde condensate and fluorinated dry soil resist agents.
    Type: Grant
    Filed: February 1, 1991
    Date of Patent: March 2, 1993
    Assignee: Allied-Signal Inc.
    Inventors: Morris B. Berenbaum, John H. Bonfield, Charles J. Cole, Paul W. Harris, Thomas P. J. Izod, Harry E. Ulmer, Frederick R. Hopf, James T. Yardley, Karen M. Bland
  • Patent number: 5059513
    Abstract: Actinic (deep ultraviolet, ultraviolet and visible) light sensitive positive photoresist compositions containing a mixture of an alkali-insoluble photoactive compound capable of being transformed into an alkali-soluble species upon exposure to actinic radiation, in an amount sufficient to render the mixture relatively alkali insoluble and a polymer comprising an amount of CO--NH--CO groups, such as maleimide and especially maleimide--substituted styrene copolymers, sufficient to render the mixture readily alkali soluble upon exposure to actinic radiation are disclosed. The preferred copolymers include maleimide/styrene or .alpha.-methylstyrene in a 1:1 molar ratio. The preferred methylstyrene in a 1:1 molar ratio. The preferred photoactive compound suitable for a positive photoresist composition responsive to deep UV actinic radiation has the formula 18-B in Table I.
    Type: Grant
    Filed: June 14, 1989
    Date of Patent: October 22, 1991
    Assignee: Hoechst Celanese Corporation
    Inventors: Frederick R. Hopf, Michael J. McFarland, Christopher E. Osuch
  • Patent number: 4990623
    Abstract: A new class of sulfonated 2-(2'-hydroxyaryl)-2H-benzotriazole compounds and method for using them and other sulfonated hydroxyaryl benzotriazoles on nylon fibers to improve stain resistance and dye lightfastness has been discovered. A process is provided for improving stain resistance of nylon fibers by treatment with sulfonated aromatic-formaldehyde condensate and fluorinated dry soil resist agents.
    Type: Grant
    Filed: July 24, 1989
    Date of Patent: February 5, 1991
    Inventors: Morris B. Berenbaum, John H. Bonfield, Charles J. Cole, Paul W. Harris, Thomas P. J. Izod, Harry E. Ulmer, Frederick R. Hopf, James T. Yardley, Karen M. Bland
  • Patent number: 4959248
    Abstract: This invention relates to novel compositions for imparting stain resistance to fibers, which composition comprises a phenolic or naphtholic resin.
    Type: Grant
    Filed: November 20, 1987
    Date of Patent: September 25, 1990
    Assignees: Allied-Signal
    Inventors: Bryce C. Oxenrider, Frederick R. Hopf
  • Patent number: 4902784
    Abstract: Disclosed are substituted derivatives of 5-diazobarbituric acid selected from those having the formulas: ##STR1## wherein R.sub.1 and R.sub.2 are substituents selected from the group consisting of C.sub.3 to C.sub.12 alkyl, cyclohexyl, benzyl and C.sub.2 to C.sub.6 aralkyl groups, wherein R.sub.3 and R.sub.4 are substituents selected from the group consisting of C.sub.1 to C.sub.12 alkyl, cyclohexyl, benzyl or other C.sub.2 to C.sub.6 aralkyl groups and R.sub.5 is selected from the group consisting of .alpha.,.omega.-disubstituted C.sub.2 to C.sub.12 alkyl, methylene dicyclohexyl, or C.sub.1 to C.sub.6 dialkylphenylene.These compounds provide DUV response with an absorption maximum near 260 nm. The substituents are chosen to be nonabsorbing alkyl groups that allow efficient photobleaching of the sensitizer during exposure.The sensitizers of the present invention are designed to function in the DUV region and are useful in the manufacture of semi-conductor devices.
    Type: Grant
    Filed: December 28, 1987
    Date of Patent: February 20, 1990
    Assignee: Hoechst Celanese Corporation
    Inventors: Frederick R. Hopf, Michael J. McFarland
  • Patent number: 4857435
    Abstract: Actinic (deep ultraviolet, ultraviolet and visible) light sensitive positive photoresist compositions containing a mixture of an alkali-insoluble photoactive compound capable of being transformed into an alkali-soluble species upon exposure to actinic radiation, in an amount sufficient to render the mixture relatively alkali insoluble and a polymer comprising an amount of --CO--NH--CO-- groups, such as maleimide and especially maleimide-substituted styrene copolymers, sufficient to render the mixture readily alkali soluble upon exposure to actinic radiation are disclosed. The preferred copolymers include maleimide/styrene or .alpha.-methylstyrene in a 1:1 molar ratio. The preferred photoactive compound suitable for a positive photoresist composition responsive to deep UV actinic radiation has the formula 18-B in Table I. The present invention also contemplates photosensitive elements and thermally stable photochemically imaged systems based on the actinic light sensitive positive photoresist compositions.
    Type: Grant
    Filed: March 17, 1987
    Date of Patent: August 15, 1989
    Assignee: Hoechst Celanese Corporation
    Inventors: Frederick R. Hopf, Michael J. McFarland, Christopher E. Osuch
  • Patent number: 4735885
    Abstract: Disclosed are substituted derivatives of 5-diazobarbituric acid selected from those having the formulas: ##STR1## wherein R.sub.1 and R.sub.2 are substituents selected from the group consisting of C.sub.3 to C.sub.12 alkyl, cyclohexyl, benzyl and C.sub.2 to C.sub.6 aralkyl groups, wherein R.sub.3 and R.sub.4 are substituents selected from the group consisting of C.sub.1 to C.sub.12 alkyl, cyclohexyl, benzyl or other C.sub.2 to C.sub.6 aralkyl groups and R.sub.5 is selected from the group consisting of .alpha.,.omega.-disubstituted C.sub.2 to C.sub.12 alkyl, methylene dicyclohexyl, or C.sub.1 to C.sub.6 dialkylphenylene.These compounds provide DUV response with an absorption maximum near 260 nm. The substituents are chosen to be nonabsorbing alkyl groups that allow efficient photobleaching of the sensitizer during exposure.The sensitizers of the present invention are designed to function in the DUV region and are useful in the manufacture of semi-conductor devices.
    Type: Grant
    Filed: December 6, 1985
    Date of Patent: April 5, 1988
    Assignee: Allied Corporation
    Inventors: Frederick R. Hopf, Michael J. McFarland
  • Patent number: 4457992
    Abstract: An etchable electrophotographic printing plate comprising a coating on a surface of an electroconductive support such as grained, anodized aluminum of effective amounts of photoconductive ZnO and of a sensitizing dye dispersed in an organic resin binder comprised of about 60-90 wt. % of C.sub.2 -C.sub.4 alkenyl C.sub.2 -C.sub.8 alkanoate, about 5-30 wt. % of di(C.sub.1 -C.sub.8 alkyl) C.sub.4 -C.sub.8 alkenedionate, about 2-8 wt. % of C.sub.3 -C.sub.8 alkenoic acid or C.sub.4 -C.sub.8 alkenedioic acid, and about 0.5-5.0 wt. % of a cross-linking agent. The preferred thermally cross-linkable organic resin binder is a random copolymer of 70 wt. % vinyl acetate, 24 wt. % dibutyl maleate; 5 wt. % acrylic acid and 1 wt. % glycidyl methacrylate. The etchable printing plate of the present invention is environmentally safe, has excellent shelf life and high sensitivity to actinic radiation.
    Type: Grant
    Filed: May 9, 1983
    Date of Patent: July 3, 1984
    Assignee: Allied Corporation
    Inventors: Himangshu R. Bhattacharjee, Frederick R. Hopf, Karl W. Beeson
  • Patent number: 4418135
    Abstract: Electrophotographic compositions containing zinc oxide dispersed in a certain resin binder mixture and sensitized with a cyanine dye having a particular structure provide high sensitivity in the 780-840 nm wavelength range, excellent thermal stability, long dark decay time and near-white appearance. The compositions are particularly useful for non-transfer electrophotography and for electrostatic printing applications.
    Type: Grant
    Filed: September 22, 1982
    Date of Patent: November 29, 1983
    Assignee: Allied Corporation
    Inventors: Karl W. Beeson, Himangshu R. Bhattacharjee, Frederick R. Hopf