Patents by Inventor Frederick W. Gray

Frederick W. Gray has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4664837
    Abstract: An improved bleaching and laundering composition is provided comprising monoperoxyphthalic acid and/or a water-soluble salt thereof, a chelating agent capable of forming a substantially water-soluble complex with metal ion in aqueous solution, a peroxygen compound and an activator for said peroxygen compound comprising phthalic anhydride. A method of bleaching and laundering soiled and/or stained materials with the aforesaid bleaching composition is also described.
    Type: Grant
    Filed: January 17, 1985
    Date of Patent: May 12, 1987
    Assignee: Colgate Palmolive Co.
    Inventor: Frederick W. Gray
  • Patent number: 4522739
    Abstract: An activated peroxy compound bleaching composition includes a peroxy bleaching compound, such as sodium perborate, and an activator for such bleaching compound, which improves the bleaching effect thereof, which activator is a sulfonyl halide, such as an alkoxybenzenesulfonyl halide, preferably an ortho- or para-substituted methoxybenzenesulfonyl chloride, such as p-methoxybenzenesulfonyl chloride. Preferably, the peroxy bleaching compound and activator are included in a synthetic organic detergent composition such as one based on anionic and/or nonionic normally solid detergent(s), preferably also with builder salt(s) present, and bleaching is effected during the washing of fabrics or articles made thereof, in wash waters of various temperatures, even in water which is only warm. The bleaching compound and activator may also be included in pre-soak compositions.
    Type: Grant
    Filed: August 17, 1981
    Date of Patent: June 11, 1985
    Assignee: Colgate-Palmolive Company
    Inventor: Frederick W. Gray
  • Patent number: 4448705
    Abstract: An improved bleaching and laundering composition is provided comprising monoperoxyphthalic acid and/or a water-soluble salt thereof and a chelating agent capable of forming a substantially water-soluble complex with metal ion in aqueous solution. A method of bleaching and laundering soiled and/or stained materials with the aforesaid bleaching composition is also described. A preferred chelating agent is diethylene triamine pentamethylene phosphonic acid (DTPMP) and/or a water-soluble salt thereof.
    Type: Grant
    Filed: May 20, 1982
    Date of Patent: May 15, 1984
    Assignee: Colgate-Palmolive Company
    Inventor: Frederick W. Gray
  • Patent number: 4378300
    Abstract: A bleaching and laundering composition comprising a peroxygen compound, an activator comprising phthalic anhydride and diethylene triamine pentamethylene phosphonic acid and/or a water-soluble salt thereof. A method of bleaching and laundering soiled and/or stained materials with the aforesaid bleaching composition is also described.
    Type: Grant
    Filed: December 10, 1981
    Date of Patent: March 29, 1983
    Assignee: Colgate-Palmolive Company
    Inventor: Frederick W. Gray
  • Patent number: 4300897
    Abstract: A method of bleaching fabrics, effective to remove stains and safe for dyed fabrics, includes bleaching such a fabric in an aqueous medium containing bleaching composition including a water soluble peroxymonosulfate bleach, a water soluble inorganic bromide which promotes the bleaching activity of the peroxymonosulfate and an N-hydrogen compound of a certain type, such as para-tolulenesulfonamide or 5,5 dimethylhydantoin which inhibits destruction of dyes and overbleaching of dyed materials while stains to be bleached are effectively removed. Washing may also be effected with the bleaching in which case bleaching detergent composition are employed, which also contain a normally solid, water synthetic organic detergent, such as an anionic detergent, which may be a sodium linear higher alkylbenzenesulfonate or a higher fatty alcohol polyethylene oxide condensate, or a mixture thereof. Such compositions and the aqueous washing media may also include a builder salt.
    Type: Grant
    Filed: October 30, 1978
    Date of Patent: November 17, 1981
    Assignee: Colgate-Palmolive Company
    Inventor: Frederick W. Gray
  • Patent number: 4292191
    Abstract: An activated peroxy compound bleaching composition includes a peroxy bleaching compound, such as sodium perborate, and an activator for such bleaching compound, which improves the bleaching effect thereof, which activator is a sulfonyl halide, such as an alkoxybenzenesulfonyl halide, preferably an ortho- or para-substituted methoxybenzenesulfonyl chloride, such as p-methoxybenzenesulfonyl chloride. Preferably, the peroxy bleaching compound and activator are included in a synthetic organic detergent composition such as one based on anionic and/or nonionic normally solid detergent(s), preferably also with builder salt(s) present, and bleaching is effected during the washing of fabrics or articles made thereof, in wash waters of various temperatures, even in water which is only warm. The bleaching compound and activator may also be included in pre-soak compositions.
    Type: Grant
    Filed: July 31, 1978
    Date of Patent: September 29, 1981
    Assignee: Colgate-Palmolive Company
    Inventor: Frederick W. Gray
  • Patent number: 4167487
    Abstract: N-benzoyl 2-methyl-imidazole as an activator for peroxygen compounds for bleaching.
    Type: Grant
    Filed: June 3, 1974
    Date of Patent: September 11, 1979
    Assignee: Colgate-Palmolive Company
    Inventor: Frederick W. Gray
  • Patent number: 4146496
    Abstract: There is disclosed a bleaching composition which includes an alkali metal peroxymonosulfate bleaching agent promoted by an effective amount of an alkali metal-N-bromo or N-dibromo aryl sulfonamide; the system is especially useful in conjunction with optical brighteners.
    Type: Grant
    Filed: May 18, 1977
    Date of Patent: March 27, 1979
    Assignee: Colgate-Palmolive Company
    Inventor: Frederick W. Gray
  • Patent number: 4123376
    Abstract: A bleaching composition, effective to remove stains on fabrics and safe for dyed fabrics, includes a water soluble peroxymonosulfate bleach, a water soluble inorganic bromide which promotes the bleaching activity of the peroxymonosulfate and an N-hydrogen compound of a certain type, such as para-toluene sulfonamide or 5,5-dimethylhydantoin, which inhibits destruction of dyes and overbleaching of dyed materials while stains to be bleached by the composition are effectively removed. Also within the invention are bleaching detergent compositions which also contain a normally solid, water soluble synthetic organic detergent, such as an anionic detergent which is a sodium linear higher alkylbenzene sulfonate or a nonionic detergent which is a fatty alcohol polyethylene oxide condensate, or a mixture thereof, and which may also include a builder salt. Methods of bleaching and simultaneously washing and bleaching with such compositions or their components are also disclosed.
    Type: Grant
    Filed: July 6, 1976
    Date of Patent: October 31, 1978
    Assignee: Colgate-Palmolive Company
    Inventor: Frederick W. Gray
  • Patent number: 4107065
    Abstract: An activated peroxy compound bleaching composition includes a peroxy bleaching compound, such as sodium perborate, and an activator for such bleaching compound, which improves the bleaching effect thereof, which activator is a sulfonyl halide, such as an aromatic sulfonyl halide, preferably a para-substituted benzenesulfonyl chloride, such as p-acetaminobenzenesulfonyl chloride. Preferably, the peroxy bleaching compound and activator are included in a synthetic organic detergent composition such as one based on anionic and/or nonionic normally solid detergent(s), preferably also with builder salt(s) present, and bleaching is effected during the washing of fabrics or articles made thereof, in wash waters of various temperatures, even in water which is only warm. The bleaching compound and activator may also be included in pre-soak compositions.
    Type: Grant
    Filed: November 5, 1975
    Date of Patent: August 15, 1978
    Assignee: Colgate-Palmolive Company
    Inventor: Frederick W. Gray
  • Patent number: 4088751
    Abstract: A packaged self-heating cosmetic, such as a shaving cream, hand lotion, depilatory, facial, or a shampoo, including separate exothermically reactive reductant material, such as 2-thio-4-oxypyrimidine or thiohydantoin or derivatives thereof, and an oxidant, which reacts with the reductant, generating heat. Means are provided for dispensing the packaged reductant and oxidant from separate zones and bringing them into contact with each other so that they react and heat a pressurized shaving cream or other cosmetic product whose constituents the exothermic reaction mixture contacts. The reducing agent employed is preferably 2-thio-4-oxypyrimidine or its tautomer, 2-mercapto-4-hydroxypyrimidine, or alkyl-substituted derivative thereof, and the oxidizing agent is preferably aqueous hydrogen peroxide.
    Type: Grant
    Filed: November 3, 1975
    Date of Patent: May 9, 1978
    Assignee: Colgate-Palmolive Company
    Inventors: Divaker B. Kenkare, Frederick W. Gray, Durland K. Shumway
  • Patent number: 4055505
    Abstract: An activated percompound bleaching composition comprises a bleaching percompound, such as sodium perborate tetrahydrate, an activator for such percompound, such as 2-[bis(2-hydroxyethyl)amino]-4,6-dichloro-s-triazine and a molecular sieve zeolite, such as hydrated type 4A synthetic molecular sieve zeolite. In a preferred embodiment of the invention a mixture of the described activator and diacetyl dimethylglyoxime activator is employed and inorganic builder, salts such as sodium carbonate and sodium silicate, are present, together with inorganic filler salt, such as sodium sulfate. Also within the invention are detergent compositions containing the mentioned bleaching composition components with a synthetic organic detergent, such as sodium higher linear alkylbenzene sulfonate. Methods of bleaching and washing and bleaching with the described compositions are disclosed.
    Type: Grant
    Filed: December 15, 1975
    Date of Patent: October 25, 1977
    Assignee: Colgate-Palmolive Company
    Inventor: Frederick W. Gray
  • Patent number: 3982892
    Abstract: An activated peroxy compound bleaching composition includes a peroxy bleaching compound, such as sodium perborate or sodium percarbonate and a mixture of activators for such bleaching compound, which improves the bleaching effect thereof, at least one of which is a di-lower alkanoyl di-lower alkyl glyoxime, such as diacetyldimethylglyoxime, a tetra-lower alkanoyl glycoluril, such as tetraacetylglycoluril or a mixture thereof and at least another of which is a 2-[di(2-hydroxy-lower alkyl)amino]-4,6-dihalo-s-triazine, such as 2-[bis(2-hydroxyethyl) amino]-4,6-dichloro-s-triazine, a 2,4-di-lower alkoxy-6-halo-s-triazine, such as 2,4-dimethoxy-6-chloro-s-triazine or a mixture thereof. For improved stability on storage the activators and/or the peroxy compound may be coated.
    Type: Grant
    Filed: July 12, 1974
    Date of Patent: September 28, 1976
    Assignee: Colgate-Palmolive Company
    Inventor: Frederick W. Gray
  • Patent number: 3966627
    Abstract: A cleaning composition particularly adapted for washing dishes, glasses and silverware in mechanical devices such as automatic dishwashers and capable of inhibiting overglaze attack containing as an essential ingredient aluminum silicate.
    Type: Grant
    Filed: January 17, 1975
    Date of Patent: June 29, 1976
    Assignee: Colgate-Palmolive Company
    Inventor: Frederick W. Gray