Patents by Inventor Friedrich Garzarolli
Friedrich Garzarolli has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7127024Abstract: A fuel element for a pressurized water reactor is described. The fuel element contains a laterally open skeleton having control-rod guide tubes each with a first end and a second end, spacers fastened to the control-rod guide tubes, a fuel element head disposed at the first end of the control-rod guide tubes, and a fuel element foot disposed at the second end of the control-rod guide tubes. Gastight cladding tubes are inserted into the skeleton and each is filled with a column of fuel pellets. At least some of the gastight cladding tubes have a multilayer wall. The multilayer wall is formed of a mechanically stable matrix containing a first zirconium alloy disposed in a middle of the multiplayer wall; and a thinner protective layer of a second zirconium alloy alloyed to a lesser extent than the first zirconium alloy. The thinner protective layer is bound metallurgically to the matrix and is disposed on an inside of the matrix facing the fuel pellets.Type: GrantFiled: October 29, 2004Date of Patent: October 24, 2006Assignee: Framatome ANP GmbHInventors: Friedrich Garzarolli, Angelika Seibold, Heinrich Ruhmann
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Publication number: 20060225815Abstract: A zirconium alloy has the following composition in percent by mass: Sn: 0.2-0.5%; Nb: 0.2-0.8%; Fe: 0.05-0.40%; V: 0-0.20%; 0:0.12-0.20%; Si: 80-120 ppm; C:=120 ppm; and a remainder of reactor-pure zirconium and acceptable impurities. The alloy is particularly suitable for components for the core of light water reactors, in particular, for pressurized water reactors.Type: ApplicationFiled: January 17, 2006Publication date: October 12, 2006Inventors: Friedrich Garzarolli, Angelika Seibold, Heinrich Ruhmann
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Publication number: 20060203953Abstract: A fuel element for a pressurized water reactor is described. The fuel element contains a laterally open skeleton having control-rod guide tubes each with a first end and a second end, spacers fastened to the control-rod guide tubes, a fuel element head disposed at the first end of the control-rod guide tubes, and a fuel element foot disposed at the second end of the control-rod guide tubes. Gastight cladding tubes are inserted into the skeleton and each is filled with a column of fuel pellets. At least some of the gastight cladding tubes have a multilayer wall. The multilayer wall is formed of a mechanically stable matrix containing a first zirconium alloy disposed in a middle of the multiplayer wall; and a thinner protective layer of a second zirconium alloy alloyed to a lesser extent than the first zirconium alloy. The thinner protective layer is bound metallurgically to the matrix and is disposed on an inside of the matrix facing the fuel pellets.Type: ApplicationFiled: October 29, 2004Publication date: September 14, 2006Inventors: Friedrich Garzarolli, Angelika Seibold, Heinrich Ruhmann
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Patent number: 6898260Abstract: A fuel element for a pressurized water reactor is described. The fuel element contains a laterally open skeleton having control-rod guide tubes each with a first end and a second end, spacers fastened to the control-rod guide tubes, a fuel element head disposed at the first end of the control-rod guide tubes, and a fuel element foot disposed at the second end of the control-rod guide tubes. Gastight cladding tubes are inserted into the skeleton and each is filled with a column of fuel pellets. At least some of the gastight cladding tubes have a multilayer wall. The multilayer wall is formed of a mechanically stable matrix containing a first zirconium alloy disposed in a middle of the multiplayer wall; and a thinner protective layer of a second zirconium alloy alloyed to a lesser extent than the first zirconium alloy. The thinner protective layer is bound metallurgically to the matrix and is disposed on an inside of the matrix facing the fuel pellets.Type: GrantFiled: October 1, 2001Date of Patent: May 24, 2005Assignee: Framatome ANP GmbHInventors: Friedrich Garzarolli, Angelika Seibold, Heinrich Ruhmann
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Publication number: 20020061089Abstract: A fuel element for a pressurized water reactor is described. The fuel element contains a laterally open skeleton having control-rod guide tubes each with a first end and a second end, spacers fastened to the control-rod guide tubes, a fuel element head disposed at the first end of the control-rod guide tubes, and a fuel element foot disposed at the second end of the control-rod guide tubes. Gastight cladding tubes are inserted into the skeleton and each is filled with a column of fuel pellets. At least some of the gastight cladding tubes have a multilayer wall. The multilayer wall is formed of a mechanically stable matrix containing a first zirconium alloy disposed in a middle of the multiplayer wall; and a thinner protective layer of a second zirconium alloy alloyed to a lesser extent than the first zirconium alloy. The thinner protective layer is bound metallurgically to the matrix and is disposed on an inside of the matrix facing the fuel pellets.Type: ApplicationFiled: October 1, 2001Publication date: May 23, 2002Inventors: Friedrich Garzarolli, Angelika Seibold, Heinrich Ruhmann
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Patent number: 6320925Abstract: A spacer of a fuel assembly having intersecting webs undergoes reduced longitudinal expansion as a result of corrosion during an operating period. The webs have intersection locations at which assembly gaps are provided. The assembly gaps have widths which correspond essentially, at most over a fraction of their total length, to the wall thickness of an intersecting web, but are wider in a remaining region. Since corrosion layers growing from an edge of an assembly gap toward the intersecting web cannot touch the web, no solid pressure, which could lead to longitudinal expansion, builds up.Type: GrantFiled: January 27, 1999Date of Patent: November 20, 2001Assignee: Siemens AktiengesellschaftInventors: Reiner Manzel, Werner Jahreiss, Norbert Schmidt, Josef Steven, Peter Dewes, Friedrich Garzarolli, Erhard Ortlieb, Franz-Josef Bökers, Matthias Rudolph
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Patent number: 6167104Abstract: A pressurized water reactor fuel assembly with a guide tube and a method for producing a guide tube for control elements are provided. Such guide tubes in pressurized water nuclear reactors which are composed of zirconium alloys (zircaloy-2 and zircaloy-4) show sharp radiation-induced growth in the axial direction at the commencement of their use in the reactor core. The sharp initial growth of the tubes is compensated by an inherent contraction of the tubes. For this purpose, the guide tubes are given internal stresses which are reduced by tube contraction as a result of a radiation-induced supply of energy. During production, guide tubes which are too short are first produced and subsequently lengthened by at least 0.3% to a final dimension in a last production step. In order to lengthen the tube, it may be stretched on a straightening bench.Type: GrantFiled: March 4, 1999Date of Patent: December 26, 2000Assignee: Siemens AktiengesellschaftInventors: Friedrich Garzarolli, Ingo Pohlmeyer, Theo Grimmelsmann, Alwin Schaa
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Patent number: 6132525Abstract: Austenitic steel intended for use in radiation areas of nuclear reactors is largely resistant to irradiation-induced stress corrosion cracking if its silicon, phosphorus and sulfur contents are reduced in relation to standard commercial steel quantities and its grain structure has finely dispersed carbide precipitation, particularly of niobium carbide. The finely dispersed distribution can be induced in that larger niobium precipitation takes place at annealing temperatures between 1100 and 1150.degree. C., and carbide is precipitated through the corresponding annealing at temperatures of approximately 750.degree. C.Type: GrantFiled: March 7, 1997Date of Patent: October 17, 2000Assignee: Electric Power Research Institute, Inc.Inventors: Dietrich Alter, Peter Dewes, Friedrich Garzarolli, Roland Hahn, J. Lawrence Nelson
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Patent number: 5949838Abstract: A method of producing austenite steel for use in the radiation zone of a nuclear reactor. The method comprising the steps of forming the austenite steel with about 17% by weight chromium, about 9 to 11.5% by weight nickel, about 0.04% by weight carbon, and iron impurities whose content of silicon is about 0.1% by weight and whose total content of sulfur and phosphorous is less than 0.03% by weight; and exposing the austenite steel to a temperature treatment at a temperature less than 1150 .degree. C. to produce a fine grain lattice with grain diameter features under approximately 20 .mu.m.Type: GrantFiled: February 27, 1998Date of Patent: September 7, 1999Assignee: Electric Power Research Institute, Inc.Inventors: Dietrich Alter, Peter Dewes, Friedrich Garzarolli, Roland Hahn, J. Lawrence Nelson
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Patent number: 5854818Abstract: Zirconium alloys for use in an aqueous environment subject to high fluence of a water reactor and characterized by improved corrosion resistance, consisting essentially of 0.3 to 1.8 weight percent tin, 0.1 to 0.65 weight percent iron, the balance of alloys being essentially nuclear grade zirconium with incidental impurities and having a microstructure of Zr.sub.3 Fe second phase precipitates distributed uniformly intragranularly and intergranularly to form radiation resistant second phase precipitates in the alloy matrix.Type: GrantFiled: August 28, 1997Date of Patent: December 29, 1998Assignee: Siemens Power CorporationInventors: Leonard F. P. Van Swam, Friedrich Garzarolli, Heinrich Ruhmann
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Patent number: 5844959Abstract: Zirconium alloys for use in an aqueous environment subject to high fluence of a water reactor and characterized by improved corrosion resistance, consisting essentially of from 0.5 to 3.25 weight percent niobium, from 0.3 to 1.8 weight percent tin, the balance of alloys being essentially nuclear grade zirconium with incidental impurities and having a microstructure of beta niobium second phase precipitates distributed uniformly intragranularly and intergranularly to form radiation resistant second phase precipitates in the alloy matrix.Type: GrantFiled: August 1, 1997Date of Patent: December 1, 1998Assignee: Siemens Power CorporationInventors: Leonard F. P. Van Swam, Friedrich Garzarolli, Heinrich Ruhmann
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Patent number: 5838753Abstract: A process for fabricating nuclear fuel rod cladding tube comprising beta quenching a zirconium alloy billet consisting essentially of from 0.5 to 3.25 weight percent niobium, from 0.3 to 1.8 weight percent tin, the balance of the alloy being essentially nuclear grade zirconium with incidental impurities by heating to a temperature in the beta range above 950.degree. C. and rapidly quenching the billet to a temperature below the .alpha. plus .beta. to .alpha. transformation temperature to form a martensitic structure; extruding the beta-quenched billet at a temperature below 600.degree. C. to form a hollow; annealing the hollow by heating at a temperature up to 590.degree. C.; pilgering the annealed hollow; and final annealing the pilgered annealed hollow to a temperature up to 590.degree. C.Type: GrantFiled: August 1, 1997Date of Patent: November 17, 1998Assignee: Siemens Power CorporationInventors: Leonard F. P. Van Swam, Friedrich Garzarolli, Heinrich Ruhmann
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Patent number: 5835550Abstract: A process for fabricating nuclear fuel rod cladding tube comprising beta quenching a zirconium alloy billet consisting essentially of 0.3 to 1.8 weight percent tin, 0.1 to 0.65 weight percent iron, the balance of the alloy being essentially nuclear grade zirconium with incidental impurities by heating to a temperature in the beta range greater than about 1000.degree. C. and rapidly quenching the billet to a temperature below the .alpha. plus .beta. to a transformation temperature to form a martensitic structure; extruding the beta-quenched billet at a temperature between 600.degree. and 750.degree. C. to form a hollow; annealing the hollow by heating at a temperature up to about 700.degree. C.; pilgering the annealed hollow; and final annealing the pilgered annealed hollow to a temperature up to about 700.degree. C. to form the nuclear fuel rod cladding tube comprising the alloy having a microstructure of Zr.sub.Type: GrantFiled: August 28, 1997Date of Patent: November 10, 1998Assignee: Siemens Power CorporationInventors: Leonard F. P. Van Swam, Friedrich Garzarolli, Heinrich Ruhmann
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Patent number: 5539791Abstract: Zircaloy 2 and zircaloy 4 are zirconium alloys which are permitted and tried and tested in nuclear engineering and which have constituents with fixed concentration ranges. The properties, especially corrosion resistance, mechanical stability and sensitivity to pellet-cladding interaction of those alloys are subject to pronounced spreads of unknown origin. According to the invention, the tin content is between 1.4 and 1.8% by weight, the Fe content between 0.1 and 0.25% by weight, the Cr content between 0.1 and 0.3% by weight, the Si content between 0.05 and 0.02% by weight, the O content between 0.05 and 0.11% by weight, the C content below 0.02% by weight and the Ni content below 0.08% by weight. This restriction of the permissible concentration ranges ensures that the material properties are spread only within a narrow favorable range. A liner made from zirconium with an iron constituent of between 0.2 and 0.8% by weight is proposed for the inner lining of a fuel-rod sheathing tube.Type: GrantFiled: August 26, 1994Date of Patent: July 23, 1996Assignee: Siemens AktiengesellschaftInventors: Friedrich Garzarolli, Eckard Steinberg
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Patent number: 5493592Abstract: A fuel rod has a cladding including a thicker inner layer and a thin outer layer being metallurgically bound thereto. In view of the conditions prevailing on the inside of the cladding tube and the mechanical properties of the entire cladding tube, the inner layer is formed of zircaloy having a comparatively high Sn content and a low Fe and Fe+Cr content. The outer layer also contains virtually only zircaloy constituents, but in view of corrosion, H2 take-up and sensitivity to Li dissolved in the cooling water, the Fe and Fe+Cr content is greater than or at most equal to that of the inner layer, the chosen Sn content is less than 1.3% and the chosen Sn+Fe+Cr content is more than 1.0%. Low failure rates of the cladding tube are thereby achieved even for long service lives.Type: GrantFiled: September 13, 1994Date of Patent: February 20, 1996Assignee: Siemens AktiengesellschaftInventors: Friedrich Garzarolli, Eckard Steinberg
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Patent number: 4963316Abstract: A fuel rod for a nuclear reactor fuel assembly includes a cladding tube having an outer surface and a given total wall thickness. Nuclear fuel is disposed in the cladding tube. The cladding tube is formed of a first zirconium alloy which may have alloy components of from 1.2 to 2% by weight of tin, 0.07 to 0.2% by weight of iron, 0.05 to 0.15% by weight of chromium, 0.03 to 0.08% by weight of nickel, 0.07 to 0.15% by weight of oxygen, and a total percent by weight for the alloy components of iron, chromium and nickel in a range of from 0.18 to 0.38% by weight. The first zirconium alloy may also have alloy components of from 1.2 to 2% by weight of tin, 0.18 to 0.24% by weight of iron, 0.07 to 0.13% by weight of chromium, 0.10 to 0.16% by weight of oxygen, and a total percentage by weight for the components of iron and chromium in a range of from 0.28 to 0.37% by weight.Type: GrantFiled: July 21, 1988Date of Patent: October 16, 1990Assignee: Siemens AktiengesellschaftInventors: Heinz Stehle, Hans Weidinger, Eckard Steinberg, Friedrich Garzarolli
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Patent number: 4938920Abstract: A nuclear reactor fuel assembly includes a fuel rod containing nuclear fuel in a cladding tube formed of an iron-containing zirconium alloy. A fuel assembly skeleton to which the fuel rod is attached has a structural part formed of the iron-containing zirconium alloy. The iron-containing zirconium alloy has an oxygen content of from 0.1 to 0.16% by weight and contains alloy components of from 0 to 1% by weight of niobium, 0 to 0.8% by weight of tin, at least two metals from the group consisting of iron, chromium and vanadium having from 0.2 to 0.8% by weight of iron, 0 to 0.4% by weight of chromium and 0 to 0.3% by weight of vanadium, a total percent by weight of iron, chromium and vanadium of from 0.25 to 1% by weight, and a total percent by weight for niobium and tin in the range from 0 to 1% by weight.Type: GrantFiled: July 8, 1988Date of Patent: July 3, 1990Assignee: Siemens AktiengesellschaftInventors: Friedrich Garzarolli, Erhard Ortlieb, Eckard Steinberg, Hans Weidinger