Patents by Inventor Friedrich W. Krock

Friedrich W. Krock has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5621027
    Abstract: Dyestuffs of the formula ##STR1## wherein Z denotes a radical to complete a 3,4- or 2,3-pyridinylene, a 4,5-pyrimidinylene, a 3,4- or 4,5-pyridazinylene or a 2,3-pyrazinylene system andX, Y, m and n have the meanings given in the description,which are particularly suitable for bulk dyeing plastics, in particular thermoplastics, have been found.
    Type: Grant
    Filed: May 12, 1995
    Date of Patent: April 15, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Roschger, Volker Hederich, Stephan Michaelis, Friedrich W. Krock
  • Patent number: 5272259
    Abstract: Dyestuffs which in the form of the free acid conform to the formula ##STR1## in which X and Y independently represent --N.dbd.N--R, --CF.sub.3, --CONH.sub.2, --CONHR.sup.1, --CONR.sup.1 R.sup.2, --COOH, --COOR.sup.1, --CN, --NO.sub.2, --NH.sub.2, --NHR.sup.1, --NR.sup.1 R.sup.2, --OH, --OR.sup.1, --R.sup.1 CONH--, --O--CO--R.sup.1, halogen or a substituted or unsubstituted heterocyclic radical, provided that at least one of the radicals X or Y represents --N.dbd.N--R, in whichR represents an aryl or heterocyclic radical, andR.sup.1 and R.sup.2 independently represent alkyl, cycloalkyl, aryl or aralkyl, which are uninterrupted or interrupted by O, S or both O and S,and in which furthermore the radicals mentioned for R, R.sup.1 and R.sup.
    Type: Grant
    Filed: May 26, 1992
    Date of Patent: December 21, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Uwe Claussen, Friedrich W. Krock
  • Patent number: 5213582
    Abstract: Light-polarizing films or foils, preferably based on a vinyl alcohol homopolymer or copolymer, contain dyes corresponding to the following formula ##STR1## in which R, R.sup.1, T.sup.1, T.sup.2, n, X and Z are as defined in the specification.
    Type: Grant
    Filed: March 11, 1992
    Date of Patent: May 25, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Wild, Uwe Claussen, Friedrich W. Krock
  • Patent number: 5175336
    Abstract: The invention relates to new fluoromethylated polycyanobenzenes of the formula ##STR1## in which X represents hydrogen, fluorine or chlorine,m is 1 or 2 andn is (6-m),to a process for their preparation and to the salt-like alkali metal cyanide adducts of the fluoromethylated polycyanobenzenes formed as intermediates in this preparation process and to the use of the fluoromethylated polycyanobenzenes for the detection of anions.
    Type: Grant
    Filed: May 16, 1991
    Date of Patent: December 29, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gunther Beck, Wolfgang von der Emden, Helmut Heitzer, Friedrich W. Krock, Ernst Kysela, Albrecht Marhold
  • Patent number: 5122557
    Abstract: The present invention relates to light polarizing films containing water-soluble, transparent organic polymers and dichroic dyes capable of fluorescence and to new dichroic dyes.
    Type: Grant
    Filed: June 3, 1991
    Date of Patent: June 16, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Uwe Claussen, Friedrich W. Krock
  • Patent number: 5093401
    Abstract: Casting solutions for the production of light-polarizing films or sheets contain, relative to the sum of weights (A)+(B)+(C)+(D)=100% by weight, (A) 30-95% by weight, preferably 40-75% by weight, of water, (B) 1-40% by weight, preferably 4-30% by weight, of vinyl, alcohol polymer, (C) 0.01-5% by weight, preferably 0.02-2% by weight, of the dichroic dyestuff, (D) 0.1-75% by weight, preferably 0.5-50% by weight, of one or several organic compounds from the group consisting of aliphatic polyols having 2-6 C atoms, aliphatic ether polyols having 2-6 C atoms, C.sub.1 -C.sub.4 -alkyl ethers of aliphatic polyols having 2-6 C atoms, aliphatic aminoalcohols having 2-4 C atoms, amides of aliphatic C.sub.1 -C.sub.4 -carboxylic acids, and, if desired, a C.sub.1 -C.sub.4 -monoalcohol, and, if desired (E) further additives customary for casting solutions, for example stabilizers, and wherein if using glycerol solely, the weight ratio of glycerol: vinylalcohol polymer is about 0.2-1:1, preferably 0.3-0.5:1.
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: March 3, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Uwe Claussen, Friedrich W. Krock
  • Patent number: 5007942
    Abstract: Light-polarizing films or sheets, preferably based on vinyl alcohol homopolymers or copolymers contain dyestuffs of the formula ##STR1## in which X and Y have the meanings given in the description.
    Type: Grant
    Filed: December 14, 1989
    Date of Patent: April 16, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Uwe Claussen, Friedrich W. Krock
  • Patent number: 4863634
    Abstract: Dyestuffs of the formula ##STR1## in which X designates OR.sub.2 or a group NHR.sub.2,Y designates H or a group NHR.sub.2 or OR.sub.2,Y' designates H or NHR.sub.1,R.sub.1 and R.sub.2 designate H, alkyl, cycloalkyl, aryl or aralkyl and if Y or Y' represents H,Q designates aryl, a thienyl radical or a group --OR.sub.2, --NHR.sub.3, --SO.sub.2 R.sub.3, --S--CO--R.sub.3, --CO--SR.sub.3, --SR.sub.3, --CH.dbd.NR.sub.3, --COOR.sub.3, --OCOR.sub.3, --OCOOR.sub.3, --NHCO--OR.sub.3, --O--SO.sub.2 --R.sub.3, --NH--CO--NHR.sub.3, --O--CO--NHR.sub.3, --CHO, --O--CH.sub.2 CH.sub.2 --OR.sub.3 or --SO.sub.3 R.sub.3,M designates H, halogen or Q,R.sub.3 designates alkyl, aralkyl, cycloalkyl or a heterocyclic radical or a radical Z of the formula ##STR2## wherein R.sub.4 and R.sub.8 denote H, halogen, CF.sub.3, alkyl or alkoxy andR.sub.5 and R.sub.6 denote R.sub.4, --SR.sub.3, --NO.sub.2, --OR.sub.3, --CO.sub.2 R.sub.3, --COR.sub.3, --SCOR.sub.3, --SO.sub.3 R.sub.3, --NHCONHR.sub.3, --OCONHR.sub.3, --OSO.sub.2 R.sub.
    Type: Grant
    Filed: June 1, 1984
    Date of Patent: September 5, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Uwe Claussen, Rutger Neeff, Friedrich W. Krock
  • Patent number: 4689171
    Abstract: Dyestuffs of the formula ##STR1## in which Y.sub.1, Y.sub.2, Y.sub.3, Y.sub.4 designate hydrogen, halogen, nitro, amino, alkylamino, arylamino, cycloalkylamino, aralkylamino, alkylthio, arylthio, cycloalkylthio, aralkylthio or hydroxyl, it being possible for the hydrocarbon radicals to be sustituted, with the proviso that(a) at least one of the substituents Y.sub.1, Y.sub.2, Y.sub.3 or Y.sub.4 does not denote hydrogen,(b) a maximum of two of the substituents Y.sub.1, Y.sub.2, Y.sub.3 and Y.sub.4 designate halogen and either(c.sub.1) X.sub.1, X.sub.3 represent halogen, --R.sub.1, --OR.sub.1 or --SR.sub.1, R.sub.1 denoting optionally substituted alkyl, it being possible for the alkyl chain to be substituted by an oxygen atom or several non-adjacent oxygen atoms, optionally substituted aryl, optionally substituted cycloalkyl, optionally substituted aralkyl or an optionally substituted heterocyclic radical and X.sub.2 designating hydrogen, or(c.sub.2) X.sub.1, X.sub.
    Type: Grant
    Filed: September 9, 1985
    Date of Patent: August 25, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Martin Blunck, Uwe Claussen, Friedrich W. Krock, Rutger Neeff
  • Patent number: 4596666
    Abstract: Anthraquinone dyestuffs of the formula ##STR1## in which R.sub.1 represents alkyl, aralkyl, --CO--X-alkyl, --CO-- X-aralkyl, --CO--X-aryl, --O-alkyl, --O-aralkyl, --O-- aryl, --CN, --NO.sub.2, --CF.sub.3, halogen or a heterocyclic radical andR.sub.2 represents H or R.sub.1,X representing O, S, NH or a direct bond andY.sub.1, Y.sub.2, Y.sub.3 and Y.sub.4 denoting hydrogen, --NH.sub.2, --OH, halogen, --NO.sub.2 or an arylmercapto group and at least one of the substituents Y.sub.1 -Y.sub.4 representing an arylmercapto group,it being also possible for the alkyl, aryl, aralkyl and heterocyclic radicals mentioned for R.sub.1 and Y.sub.1 -Y.sub.4 to be substituted, the preparation and use thereof, and dichroic material containing these anthraquinone dyestuffs.
    Type: Grant
    Filed: December 2, 1983
    Date of Patent: June 24, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Martin Blunck, Uwe Claussen, Friedrich W. Krock, Rutger Neeff
  • Patent number: 4521341
    Abstract: 1,4-Diamino-anthraquinone-2-sulphonic acid is obtained in a simple manner, in good yield and good purity, by reacting 1-amino-4-bromo-anthraquinone-2-sulphonic acid with ammonia in water in the presence of copper catalysts at an elevated temperature, under a partial pressure of ammonia of at least 5 bar.
    Type: Grant
    Filed: March 16, 1984
    Date of Patent: June 4, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Friedrich W. Krock, Rutger Neoff
  • Patent number: 4422973
    Abstract: 1,4-Diamino-2,3-dicyano-anthraquinone is obtained in good yields and in high purity by reacting 1-amino-4-bromo-anthraquinone-2-sulphonic acid with ammonia and then reacting the 1,4-diamino-anthraquinone-2-sulphonic acid, which is not isolated as an intermediate, with cyanide ions, in formamide or N-methylformamide.
    Type: Grant
    Filed: January 15, 1981
    Date of Patent: December 27, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Friedrich W. Krock, Rutger Neeff
  • Patent number: 4294578
    Abstract: Use of compounds which, in the form of the free acid, correspond to the formula ##STR1## in which Z represents halogen or alkylcarbonylamino with 1-4 C atoms in the alkyl radical,m is 0, 1 or 2 andn, r and s represent the numbers 0 or 1 with the proviso that the sum of n, r and s has a value of 1 or 2 and s can be 1 only if r at the same time is 0,for dyeing polymeric materials containing amide groups, material dyed in this way and colorants containing the compounds of the indicated formula.
    Type: Grant
    Filed: March 15, 1979
    Date of Patent: October 13, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Friedrich W. Krock, Rutger Neeff
  • Patent number: 4294769
    Abstract: 2,3-Dicyano-anthraquinones of the formula ##STR1## wherein R denotes hydrogen, alkyl or cycloalkyl, are obtained in good yields and high purity by reacting compounds of the formula ##STR2## wherein X denoted hydrogen or the sulphonic acid group, with cyanides in formamide or N-methylformamide as solvents, and if appropriate oxidizing agents and heavy metal catalysts.
    Type: Grant
    Filed: July 24, 1980
    Date of Patent: October 13, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Friedrich W. Krock, Rutger Neeff, Heinz Scheiter
  • Patent number: 4278434
    Abstract: Dyestuffs of the formula ##STR1## wherein R represents C.sub.1 -C.sub.5 -alkyl which is optionally substituted by fluorine, chlorine, hydroxyl or methoxy,are outstandingly suitable for printing polymeric materials in accordance with the transfer printing principle in that they produce intensely colored prints on these materials, especially on polyester and polyamide fibre materials.
    Type: Grant
    Filed: February 11, 1980
    Date of Patent: July 14, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Friedrich W. Krock, Rutger Neeff, Robert Kuth
  • Patent number: 4264511
    Abstract: New anthraquinone compounds of the formula ##STR1## in which Y denotes chlorine, bromine, --O--R or ##STR2## R denotes aryl, R.sub.1 and R.sub.2 denote hydrogen, alkyl, cycloalkyl or aryl andX.sub.1 and X.sub.2 denote hydrogen, halogen or nitro,are obtained when the corresponding 2-sulphonic acids are treated with inorganic acid halides and the products are then optionally treated with alcohols or amines. The compounds I are valuable dyestuffs for dyeing polyester fibres and starting materials for the preparation of such dyestuffs.
    Type: Grant
    Filed: May 11, 1979
    Date of Patent: April 28, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventors: Friedrich W. Krock, Rutger Neeff