Patents by Inventor Fritz Fleck

Fritz Fleck has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4526976
    Abstract: Compounds of formula I ##STR1## in which X is O or S;Y is O, S or NR.sub.3 where R.sub.3 is hydrogen or C.sub.1-4 alkyl (preferably methyl or ethyl) and rings A and B may be further substituted by non-chromophoric substituents.
    Type: Grant
    Filed: March 30, 1983
    Date of Patent: July 2, 1985
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Alec V. Mercer, Malcolm Oates
  • Patent number: 4386200
    Abstract: A non-chromophoric conjugated derivative of 7-styryl coumarin for use as an optical brightener in which the lactone ring of the coumarinyl group may have a benzene ring fused to it to form a 3,4-benzocoumarinyl-7 group, the phenyl group of the styryl is substituted by a conjugated group which contains a group derived from an acid in its conjugation and which group is so located as to conjugate with the ethylene group.
    Type: Grant
    Filed: September 30, 1981
    Date of Patent: May 31, 1983
    Assignee: Sandoz Ltd.
    Inventor: Fritz Fleck
  • Patent number: 4252604
    Abstract: Bis-(triazinylamino)-stilbenesulphonic acids ##STR1## wherein X is optionally substituted NH.sub.2 ##STR2## Y is a radical of formula Z is --COOR.sub.4, --CO--C.sub.m H.sub.2m+1, --CN or ##STR3## R.sub.1 is H, halogen, alkyl or alkoxy, R.sub.2 is H or alkyl,R.sub.3 is H, optionally substituted alkyl, cycloalkyl or phenyl or ##STR4## R.sub.4 is optionally substituted alkyl, R.sub.3 and R.sub.6 are H, alkyl, hydroxyalkyl or form together with N a heterocyclem is a whole number from 1 to 5 andn is 1 or 2,are optical brighteners suitable for cellulosic fibres, polyamide and polyurethane fibres and paper.
    Type: Grant
    Filed: August 30, 1977
    Date of Patent: February 24, 1981
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Hans R. Schmid
  • Patent number: 4196229
    Abstract: Disclosed are compounds of formula I ##STR1## in which R.sub.1 and R.sub.4, independently, are hydrogen, a non-chromophoric second order substituent, or alkyl or alkenyl unsubstituted or substituted by a non-chromophoric group,R.sub.2 and R.sub.5, independently, are hydrogen or alkyl or alkenyl, unsubstituted or substituted by a non-chromophoric group,R.sub.3 and R.sub.6, independently, are hydrogen, alkyl, carboxyl or a non-chromophoric esterified carboxyl group,or R.sub.2, together with R.sub.3, and/or R.sub.5 together with R.sub.6, signify an alkylene bridge,R.sub.7 and R.sub.8, independently, signify hydrogen or a non-chromophoric substituent,or, when R.sub.7 is in the 3-position and/or R.sub.8 in the 3' position, R.sub.7 together with R.sub.2, and/or R.sub.8 together with R.sub.5 signify an alkylene bridge,with the proviso that no more than one of R.sub.1 and R.sub.2 and no more than one of R.sub.4 and R.sub.5 signify hydrogen,their production and use as optical brightening agents.
    Type: Grant
    Filed: June 12, 1978
    Date of Patent: April 1, 1980
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Juerg Heller
  • Patent number: 4182861
    Abstract: Polyester, cotton, polyamide and polyacrylonitrile fabrics and foils of polyvinylchloride are optically brightened by the addition of a compound of the formula ##STR1## in which each of R.sub.1 and R.sub.2 represents a hydrogen atom or an aliphatic, alicyclic, araliphatic, halogen- or alkyl-substituted araliphatic, aromatic, or halogen- or alkyl-substituted aromatic radical,R.sub.3 represents a hydrogen or halogen atom or a low molecular weight alkyl or alkoxy radical.
    Type: Grant
    Filed: December 30, 1976
    Date of Patent: January 8, 1980
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Hans Balzer, Horst Aebli
  • Patent number: 4179578
    Abstract: Stilbene derivatives having at least one further phenyl substituent in the para-position to a benzene ring in the stilbene are optical brighteners particularly suitable for incorporation on spinning masses.
    Type: Grant
    Filed: April 14, 1977
    Date of Patent: December 18, 1979
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Hans Kittl, Salvatore Valenti
  • Patent number: 4169702
    Abstract: Disclosed is an optical brightening process for substrates comprising or consisting of synthetic polyamide in which the optical brightener is applied to the substrate by impregnation followed by heat treatment and wherein the brightener is applied in the presence of a compound or mixture of compounds of formula I,rnh.sub.2 iwherein R is --OH, --NR.sub.1 R.sub.2 or ##STR1## X being O, S or NH, and R.sub.1 and R.sub.2 being, independently, hydrogen, C.sub.1-6 alkyl or C.sub.2-4 hydroxyalkyl,Which compounds are in free base or acid addition salt form or, when R is OH, in O-sulphonic acid form, and preparations for use in such process.
    Type: Grant
    Filed: February 7, 1977
    Date of Patent: October 2, 1979
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Emmanuel Hervot, Peter Merk, Horst Schmid, Achim Wiedemann
  • Patent number: 4167626
    Abstract: Disclosed are compounds of formula I, ##STR1## in which X signifies hydrogen, C.sub.1-4 alkyl, cyano, --COOM, --COOR.sub.1, --CONR.sub.2 R.sub.3, --SO.sub.2 NR.sub.2 R.sub.3, --SO.sub.2 R.sub.1, --SOR.sub.1, --SO.sub.3 R.sub.1 or --SO.sub.3 M,Y signifies hydrogen, C.sub.1-4 alkyl, cyano, --COOM, --COOR.sub.1, --CONR.sub.2 R.sub.3, --SO.sub.2 NR.sub.2 R.sub.3, --SO.sub.2 R.sub.1, --SOR.sub.1, --SO.sub.3 R.sub.1 or --SO.sub.3 M, with the proviso that X and Y do not simultaneously have a significance selected from hydrogen and C.sub.1-4 alkyl,R signifies an aryl radical, unsubstituted or substituted by up to two substituents selected from C.sub.1-4 alkyl, C.sub.1-4 alkoxy, chlorine, cyano, --COOM, --COOR.sub.1, --CONR.sub.4 R.sub.5, --SO.sub.2 NR.sub.4 R.sub.5, --SO.sub.2 R.sub.1 and --SO.sub.3 M,R.sub.1 signifies C.sub.1-4 alkyl or phenyl,R.sub.2 and R.sub.3, independently, signify hydrogen or C.sub.1-4 alkyl, either R.sub.4 and R.sub.5, independently, signify hydrogen or C.sub.1-4 alkyl,Or R.sub.4 and R.sub.
    Type: Grant
    Filed: July 22, 1977
    Date of Patent: September 11, 1979
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Alec V. Mercer, Roger Paver
  • Patent number: 4167629
    Abstract: This invention relates to new di-triazolylstyrene derivatives, useful as optical brighteners for organic polymeric materials, especially when applied to or incorporated in synthetic fibres.
    Type: Grant
    Filed: November 7, 1974
    Date of Patent: September 11, 1979
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Horst Schmid
  • Patent number: 4108887
    Abstract: Disclosed are compounds of formula I ##STR1## in which R.sub.1 and R.sub.4, independently, are hydrogen, a non-chromophoric second order substituent, or alkyl or alkenyl unsubstituted or substituted by a non-chromophoric group,R.sub.2 and R.sub.5, independently, are hydrogen or alkyl or alkenyl, unsubstituted or substituted by a non-chromophoric group,R.sub.3 and R.sub.6, independently, are hydrogen, alkyl, carboxyl or a non-chromophoric esterified carboxyl group, orR.sub.2, together with R.sub.3, and/or R.sub.5 together with R.sub.6, signify an alkylene bridge,R.sub.7 and R.sub.8, independently, signify hydrogen or a non-chromophoric substituent, or, whenR.sub.7 is in the 3-position and/or R.sub.8 in the 3' position, R.sub.7 together with R.sub.2, and/or R.sub.8 together with R.sub.5 signify an alkylene bridge,With the proviso that no more than one of R.sub.1 and R.sub.2 and no more than one of R.sub.4 and R.sub.5 signify hydrogen, their production and use as optical brightening agents.
    Type: Grant
    Filed: January 29, 1976
    Date of Patent: August 22, 1978
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Juerg Heller
  • Patent number: 4085101
    Abstract: Disclosed are compounds of formula I, ##STR1## in which either R.sub.1, R.sub.2 and R.sub.3, which may be the same or different, each signifies a hydrogen atom, a chlorine or fluorine atom, an alkyl radical of 1 to 4 carbon atoms, an alkoxy radical of 1 to 4 carbon atoms, a cyano group, a group --SO.sub.3 M, an unsubstituted phenyl radical or a phenyl radical substituted by up to 2 substituents selected from chlorine, fluorine, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms and the group --SO.sub.3 M, with the proviso that only one of R.sub.1, R.sub.2 and R.sub.3 signifies an unsubstituted or substituted phenyl radicalOr two of R.sub.1 , R.sub.2 and R.sub.3, together, form a methylenedioxy group, the other of R.sub.1, R.sub.2 and R.sub.3 having one of the above significances,R.sub.4 signifies a hydrogen atom, a chlorine or fluorine atom, an alkyl radical of 1 to 4 carbon atoms or an alkoxy radical of 1 to 4 carbon atoms,R.sub.
    Type: Grant
    Filed: May 5, 1976
    Date of Patent: April 18, 1978
    Assignee: Sandoz Ltd.
    Inventors: Alec Victor Mercer, Peter Stuart Littlewood, Ivan Joseph Bolton, Fritz Fleck
  • Patent number: 4032558
    Abstract: Stilbene derivatives having at least one further phenyl substituent in the para-position to a benzene ring in the stilbene are optical brighteners particularly suitable for incorporation on spinning masses.
    Type: Grant
    Filed: July 16, 1975
    Date of Patent: June 28, 1977
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Hans Kittl, Salvatore Valenti
  • Patent number: 4025507
    Abstract: Disclosed are compounds of formula I, ##STR1## in which THE R.sub.1 's are the same and signify hydrogen or methyl,The R.sub.2 's are the same and signify hydrogen; C.sub.1-6 alkyl; cyclohexyl, unsubstituted or substituted by up to three C.sub.1-6 alkyl radicals; or benzyl, unsubstituted or substituted by up to two substituents selected from halogen, C.sub.1-6 alkoxy and C.sub.1-6 alkyl, andThe M's signify hydrogen or a nonchromophoric cation,Their production and use as optical brightening agents for cellulosic substrates, particularly paper substrates.
    Type: Grant
    Filed: June 25, 1974
    Date of Patent: May 24, 1977
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Hans-Rudolf Schmid
  • Patent number: 4006158
    Abstract: Polyester, cotton, polyamide and polyacrylonitrile fabrics and foils of polyvinylchloride are optically brightened by the addition of a compound of the formula ##STR1## in which each of R.sub.1 and R.sub.2 represents a hydrogen atom or an aliphatic, alicyclic, araliphatic, halogen- or alkyl-substituted araliphatic, aromatic, or halogen- or alkyl-substituted aromatic radical,OrR.sub.1 and R.sub.2 together with the two carbon atoms of the triazole ring form a five or six membered cycloalkyl ring or such a cycloalkyl ring having condensed on it a benzene ring,R.sub.3 represents a hydrogen or halogen atom or a low molecular weight alkyl or alkoxy radical.
    Type: Grant
    Filed: April 28, 1975
    Date of Patent: February 1, 1977
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Hans Balzer, Horst Aebli
  • Patent number: 4003889
    Abstract: Disclosed are compounds of formula I, ##STR1## in which either R.sub.1, R.sub.2 and R.sub.3, which may be the same or different, each signifies a hydrogen atom, a chlorine or fluorine atom, an alkyl radical of 1 to 4 carbon atoms, an alkoxy radical of 1 to 4 carbon atoms, a cyano group, a group --SO.sub.3 M, an unsubstituted phenyl radical or a phenyl radical substituted by up to 2 substituents selected from chlorine, fluorine, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms and the group --SO.sub.3 M, with the proviso that only one of R.sub.1, R.sub.2 and R.sub.3 signifies an unsubstituted or substituted phenyl radical,Or two ofR.sub.1, r.sub.2 and R.sub.3 together form a methylenedioxy group, the other of R.sub.1, R.sub.2 and R.sub.3 having one of the above significances,R.sub.4 signifies a hydrogen atom, a chlorine or fluorine atom, an alkyl radical of 1 to 4 carbon atoms or an alkoxy radical of 1 to 4 carbon atoms,R.sub.
    Type: Grant
    Filed: June 17, 1974
    Date of Patent: January 18, 1977
    Assignee: Sandoz Ltd.
    Inventors: Ivan Joseph Bolton, Alec Victor Mercer, Fritz Fleck
  • Patent number: 3996210
    Abstract: Monobenzoxazolylstilbenes of formula ##STR1## wherein R--O is lower alkoxy and stands in one of the positions 5 or 6,R.sub.1 is hydrogen or lower alkyl andR.sub.2 is hydrogen, chlorine or lower alkyl.
    Type: Grant
    Filed: June 8, 1970
    Date of Patent: December 7, 1976
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Salvatore Valenti
  • Patent number: 3970647
    Abstract: Disclosed are stilbene compounds of formula I, ##SPC1##in whichR.sub.1 signifies hydrogen, halogen or C.sub.1-6 alkyl,R.sub.2 signifies hydrogen or methyl,R.sub.3 signifies cyano or a radical --CONR.sub.7 R.sub.8 in which either R.sub.7 and R.sub.8, independently, each signifies hydrogen, C.sub.1-6 alkyl or C.sub.2-6 hydroxyalkyl, or R.sub.7 and R.sub.8, together with the nitrogen atom, signify a pyrrolidine, piperidine or morpholine radical,Either R.sub.4 and R.sub.5, independently, each signifiesC.sub.1-6 alkyl or C.sub. 2-6 hydroxyalkyl, or R.sub.4 and R.sub.5, together with the nitrogen atom, form a radical (a) ##EQU1## in which --X-- signifies --CH.sub.2 --, --O--, --S--, a direct bond, or --NR.sub.9 --, in which R.sub.9 signifies C.sub. 1-6 alkyl or C.sub.2-6 hydroxy-alkyl,R.sub.6 signifies hydrogen or C.sub.1-6 alkyl, unsubstituted or substituted by hydroxy, cyano or aminocarbonyl,M signifies hydrogen or a non-chromophoric cation,A.sup.
    Type: Grant
    Filed: February 11, 1974
    Date of Patent: July 20, 1976
    Assignee: Sandoz Ltd.
    Inventors: Hans Balzer, Fritz Fleck, Hans-Rudolf Schmid
  • Patent number: 3956283
    Abstract: Disclosed are compounds of formula I, ##SPC1##in which R.sub.1 signifies hydrogen, fluorine, bromine, chlorine, C.sub.1-6 alkyl, C.sub.1-6 alkoxy or --SO.sub.3 M,R.sub.2 signifies cyano or --CONR.sub.3 R.sub.4,in which either R.sub.3 and R.sub.4, independently, each signify hydrogen, C.sub.1-6 alkyl or C.sub.2-6 hydroxyalkyl,Or R.sub.3 and R.sub.4, together with the nitrogen atom to which they are attached, signify a pyrrolidino, piperidino or morpholino ring, andM signifies hydrogen or a non-chromophoric cation,Their production and use as optical brightening agents, particularly for cellulosic substrates such as paper and cotton.
    Type: Grant
    Filed: May 16, 1974
    Date of Patent: May 11, 1976
    Assignee: Sandoz Ltd.
    Inventor: Fritz Fleck
  • Patent number: 3956280
    Abstract: The invention provides novel pyrazoline derivatives which are useful as optical brighteners.
    Type: Grant
    Filed: December 20, 1974
    Date of Patent: May 11, 1976
    Assignee: Sandoz Ltd.
    Inventors: Fritz Fleck, Peter Stuart Littlewood, Alec Victor Mercer
  • Patent number: 3940388
    Abstract: The present invention provides novel compounds of the formula: ##SPC1##In whichR.sub.1 signifies hydrogen, fluorine or chlorine atom, a carboxylic or sulphonic acid group or an amide or ester thereof, a cyano group or an alkylsulphonyl or arylsulphonyl group,R.sub.2 signifies a hydrogen, fluorine or chlorine atom, a cyano group, a phenyl or alkyl radical which may be substituted, a carboxylic or sulphonic acid group or an amide or ester thereof, an alkylsulphonyl or arylsulphonyl group or a benzoxazole group which may be substituted,R.sub.3 and R.sub.4 independently signify a hydrogen, fluorine or chlorine atom, an alkyl radical of 1 to 6 carbon atoms which may be substituted, a cyano or carboxy group, a carboxylic acid amide or ester group, and R.sub.
    Type: Grant
    Filed: December 3, 1973
    Date of Patent: February 24, 1976
    Assignee: Sandoz Ltd., (Sandoz AG)
    Inventors: Horst Aebli, Fritz Fleck, Horst Schmid