Patents by Inventor Fritz Herren

Fritz Herren has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7740743
    Abstract: A polymer comprising i) a synthetic polymeric component that has been formed from an ethylenically unsaturated water-soluble or potentially water-soluble monomer and an ethylenically unsaturated monomer carrying a reactive group, wherein the reactive group is directly reactive with a cellulose binding domain protein; and ii) a protein component consisting of a cellulose binding domain protein, wherein the cellulose binding domain protein. The polymer is particularly suitable as a dry strength resin in a paper making process. It can also be used as a wet strength resin, internal sizing agent or surface sizing agent.
    Type: Grant
    Filed: November 4, 2005
    Date of Patent: June 22, 2010
    Assignee: Ciba Specialty Chemicals Water Treatments Ltd.
    Inventors: Michael Singh, Fritz Herren, Christina Northfleet, Robert Cockcroft, Kenneth Symes, Simon Donnelly, Andrew McCann, Valerie Reynolds
  • Publication number: 20070265407
    Abstract: A polymer comprising i) a synthetic polymeric component that has been formed from an ethylenically unsaturated water-soluble or potentially water-soluble monomer and an ethylenically unsaturated monomer carrying a reactive group, wherein the reactive group is directly reactive with a cellulose binding domain protein; and ii) a protein component consisting of a cellulose binding domain protein, wherein the cellulose binding domain protein. The polymer is particularly suitable as a dry strength resin in a paper making process. It can also be used as a wet strength resin, internal sizing agent or surface sizing agent.
    Type: Application
    Filed: November 4, 2005
    Publication date: November 15, 2007
    Inventors: Michael Singh, Fritz Herren, Christina Northfleet, Robert Cockcroft, Kenneth Symes, Simon Donnelly, Andrew McCann, Valerie Reynolds
  • Patent number: 6984682
    Abstract: A metallic effect pigment including a metallic, corrosion resistant reflective core of reflectivity from 40% to 80%; having deposited thereupon at least one dielectric coating layer formed of at least one metal oxide, the metal oxide layer having been formed by deposition on the core by hydrolysis of a hydrolyzable metal salt in an strongly acidic aqueous medium, and thereafter full transformation into the oxide by calcination.
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: January 10, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Jack Polonka, Patrice Bujard, Natacha Bonnard Pillonel, Fritz Herren
  • Patent number: 6706330
    Abstract: The invention relates to a process for coating a surface through graft polymerization, characterized in that before graft polymerization, the surface is modified, in the presence of an amine of formula: wherein R1 is hydrogen or a group R4, R2 and R3 are each independently a group R4, and R4 is [-1,2-C2-C3alkylen-T-]n-H wherein T is O or NH and n is a number from 1 to 3, by a compound having a functional group: wherein R5 to R7 are each C1-C4alkyl. The amount of amine is preferably from 5 to 500 g/m2 of surface of the substrate particle. The amount of the trialkoxysilane compound is preferably from 0.1 to 2 g/m2 of surface of the substrate particle. The process for coating a surface is particularly useful for effect pigments.
    Type: Grant
    Filed: May 17, 2002
    Date of Patent: March 16, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ryuichi Takahashi, Adrian Schulthess, Kimiya Takeshita, Fritz Herren, Patrice Bujard
  • Publication number: 20020188039
    Abstract: The invention relates to a collection of composite plateletlike particles comprising a core and at least one coating layer consisting essentially of a compound having from 60 to 95% by weight of carbon and from 5 to 25% by weight of nitrogen, the balance to 100% being selected from elements of the group consisting of hydrogen, oxygen and sulfur.
    Type: Application
    Filed: May 17, 2002
    Publication date: December 12, 2002
    Inventors: Ryuichi Takahashi, Adrian Schulthess, Kimiya Takeshita, Fritz Herren, Patrice Bujard
  • Publication number: 20020137819
    Abstract: A metallic effect pigment including a metallic, corrosion resistant reflective core of reflectivity from 40% to 80%; having deposited thereupon at least one dielectric coating layer formed of at least one metal oxide, the metal oxide layer having been formed by deposition on the core by hydrolysis of a hydrolyzable metal salt in an strongly acidic aqueous medium, and thereafter full transformation into the oxide by calcination.
    Type: Application
    Filed: March 21, 2002
    Publication date: September 26, 2002
    Inventors: Jack Polonka, Patrice Bujard, Natacha Bonnard Pillonel, Fritz Herren
  • Patent number: 6436538
    Abstract: The invention relates to a collection of composite plateletlike particles comprising a core and at least one coating layer consisting essentially of a compound having from 60 to 95% by weight of carbon and from 5 to 25% by weight of nitrogen, the balance to 100% being selected from elements of the group consisting of hydrogen, oxygen and sulfur. The invention also relates to processes for the manufacture thereof, to polymer compositions containing it, and to the use thereof as effect pigments.
    Type: Grant
    Filed: August 13, 1999
    Date of Patent: August 20, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ryuichi Takahashi, Adrian Schulthess, Kimiya Takeshita, Fritz Herren, Patrice Bujard
  • Patent number: 6369147
    Abstract: A metallic effect pigment including a metallic, corrosion resistant reflective core of reflectivity from 40% to 80%; having deposited thereupon at least one dielectric coating layer formed of at least one metal oxide, the metal oxide layer having been formed by deposition on the core by hydrolysis of a hydrolyzable metal salt in an strongly acidic aqueous medium, and thereafter full transformation into the oxide by calcination.
    Type: Grant
    Filed: January 4, 2000
    Date of Patent: April 9, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Jack Polonka, Patrice Bujard, Natacha Bonnard Pillonel, Fritz Herren
  • Patent number: 6288142
    Abstract: A process for the warp-free pigmenting of polyolefins, wherein an organic pigment is used whose particles are coated on the surface by one or more films of polar polymers.
    Type: Grant
    Filed: October 13, 2000
    Date of Patent: September 11, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Philippe Bugnon, Fritz Herren
  • Patent number: 6180694
    Abstract: The instant invention relates to a process for the warp-free pigmenting of polyolefins, which process comprises admixing coated pigment particles with a polyolefin, wherein said coated pigment particles are prepared by coating organic pigment particles with one or more films of a preformed polymer by adsorption thereon of from 1 to 10% by weight of the polymer, based on the pigment particles, at room temperature, the polymer being selected from the group consisting of polyvinylpyrrolidone homopolymers and copolymers.
    Type: Grant
    Filed: December 20, 1994
    Date of Patent: January 30, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Philippe Bugnon, Fritz Herren
  • Patent number: 6143067
    Abstract: A pigment composition, which comprises70-95% by weight of a pigment of formula ##STR1## 5-15% by weight of at least one C.sub.2 -C.sub.16 alkylenedicarboxylic acid-di-C.sub.1 -C.sub.12 alkyl ester; and0-15% by weight of at least one C.sub.12 -C.sub.24 fatty acid ester of polyhydroxy-C.sub.2 -C.sub.12 alkane;each based on the total weight of the pigment composition.Also claimed is a process for the preparation of this pigment composition and its use for mass-colouring in particular high molecular weight organic materials which can be moulded as plastics or melts.The products obtained are distinguished by an improved low shear dispersibility effect at high tinctorial strength.
    Type: Grant
    Filed: January 13, 1999
    Date of Patent: November 7, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Philippe Bugnon, Fritz Herren, Michel Fran.cedilla.ois, Alastair McAlpine Marr
  • Patent number: 6113683
    Abstract: Colored pearlescent pigment comprising a pearlescent pigment and a second pigment, characterized in using an adhesion promotor for the mutual adsorbance of the pearlescent pigment and the second pigment, whereby the adhesion promotor is a polymer containing hydroxy groups, a process for its preparation, its use and a colored high molecular weight material.
    Type: Grant
    Filed: November 10, 1998
    Date of Patent: September 5, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Fritz Herren, Kimiya Takeshita, Michel Fran.cedilla.ois
  • Patent number: 5646299
    Abstract: Diketopyrrolopyrrole of the formula ##STR1## in its .beta.-modification and in its .gamma.-modification. Both the .beta.-modification and the .gamma.-modification are suitable as pigments for coloring high-molecular weight organic material. In comparison to the .alpha.-modification, the .beta.-modification shows a shift in shade towards yellowish-red. The .gamma.-modification gives brilliant orange colorations.
    Type: Grant
    Filed: June 22, 1995
    Date of Patent: July 8, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Zhimin Hao, Abul Iqbal, Fritz Herren
  • Patent number: 5591865
    Abstract: Diketopyrrolopyrrole of the formula ##STR1## in its .beta.-modification. The new .beta.-modification is suitable as a pigment for coloring high-molecular weight organic material and shows, in comparison to the .alpha.-modification, a shift in shade towards yellowish-red.
    Type: Grant
    Filed: June 22, 1995
    Date of Patent: January 7, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Zhimin Hao, Abul Iqbal, Fritz Herren
  • Patent number: 5401780
    Abstract: An organic pigment, which has been coated by homopolymers or copolymers based on acrylic acid, methacrylic acid and/or alkyl esters thereof on top of a silane film which has itself been adsorbed onto a film of hydrolysed zirconium acetylacetonate, is useful in the warp-free pigmenting of polyolefins.
    Type: Grant
    Filed: October 15, 1993
    Date of Patent: March 28, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Philippe Bugnon, Fritz Herren
  • Patent number: 5380870
    Abstract: Mixed crystals of at least two different compounds of formula ##STR1## wherein A and B are each independently of the other a cation of formula ##EQU1## or N.sup.+ H(R.sub.1)(R.sub.2)(R.sub.3) M is a mono-, di- or trivalent metal cation, n is 1, 2 or 3, R.sub.1, R.sub.2 and R.sub.3 are each independently of one another hydrogen, C.sub.1 -C.sub.22 alkyl, C.sub.7 -C.sub.24 aralkyl, C.sub.5 -C.sub.6 cycloalkyl or C.sub.6 -C.sub.18 aryl, m is 0 or 1, and R is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, in which compounds of formula I that form the mixed crystals the cations A and B constitute a composite structure ##EQU2## wherein x is a value from 0.2 to 0.8, and the X-ray diffraction pattern of said mixed crystals differs from that of the corresponding compounds in which x is 1 or 0.These mixed crystals can be used as pigments for colouring organic material of high molecular weight and have exceptional properties, especially dispersibility, heat- and lightfastness.
    Type: Grant
    Filed: December 14, 1993
    Date of Patent: January 10, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Stefan Hari, Olof Wallquist, Fritz Herren, Thomas Eichenberger
  • Patent number: 5274010
    Abstract: A process for warp-free pigmenting of polyolefins comprising(A)(i) adsorbing a polyvinyl alcohol film onto the surface of an organic pigment particle,(ii) coating the surface of the polyvinyl alcohol coated organic pigment particle with one or more films of linear or branched homopolymers or copolymers selected from the group consisting of acrylic polymers based on acrylic acid, methacrylic acid, alkyl esters of acrylic or methacrylic acid and mixtures thereof, and(iii) admixing said pigment particles with a polyolefin; or(B)(i) adsorbing a film of hydrolysed zirconium acetylacetonate onto the surface of an organic ##STR1## in which R is methyl or ethyl and m is a number from 1 to 6, onto the surface of the hydrolysed zirconium acetylacetonate coated organic pigment particle, (ii) coating the surface of organic pigment particle coated in accordance with step (B)(i) with one or more films of linear or branched homopolymers or copolymers selected from the group consisting of acrylic polymers based on acrylic ac
    Type: Grant
    Filed: July 5, 1991
    Date of Patent: December 28, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Philippe Bugnon, Fritz Herren
  • Patent number: 5123965
    Abstract: A process for stabilizing bismuth vanadate pigments against attack by hydrochloric acid by treating said pigments with a metal phosphate, which process comprises treating an aqueous suspension of a bismuth vanadate pigment with 2-20% by weight, based on said pigment, of an orthophosphate selected from the group consisting of calcium, magnesium, aluminium, zirconium and titanium orthophosphate, of a mixture of such orthophosphates with one another or of such orthophosphates with zinc orthophosphate, with stirring, in the temperature range from 20.degree. to 100.degree. C. and in the pH range from 2 to 8, which orthophosphate is precipitated in situ from the appropriate metal salt of a strong mineral acid and orthophosphoric acid or from an alkali metal salt thereof, and isolating the resultant product by conventional methods.The pigments so obtained have excellent resistance to hydrochloric acid.
    Type: Grant
    Filed: November 21, 1990
    Date of Patent: June 23, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Fritz Herren, Leonardus J. H. Erkens
  • Patent number: 5095122
    Abstract: Organic pigments selected from the diketopyrrolopyrrole, azo, isoindolinone and isoindoline series, which pigments consist of 50% by weight of platelets which are from 5 to 50 .mu.m long, 2 to 50 .mu.m wide and 0.01 to 5 .mu.m thick, with the proviso that the ratios of length:thickness and width:thickness must be at least 3.The pigments in platelet form are excellently suited to producing effect colorations in high molecular weight organic material and in cosmetic products.
    Type: Grant
    Filed: July 13, 1990
    Date of Patent: March 10, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Philippe Bugnon, Fritz Herren, Bernhard Medinger
  • Patent number: RE35009
    Abstract: Organic pigments selected from the diketopyrrolopyrrole, azo, isoindolinone and isoindoline series, which pigments consist of .Iadd.at least .Iaddend.50% by weight of platelets which are from 5 to 50 .mu.m long, 2 to 50 .mu.m wide and 0.01 to 5 .mu.m thick, with the proviso that the ratios of length:thickness and width:thickness must be at least 3.The pigments in platelet form are excellently suited to producing effect colorations in high molecular weight organic material and in cosmetic products.
    Type: Grant
    Filed: October 28, 1993
    Date of Patent: August 1, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Philippe Bugnon, Fritz Herren, Bernhard Medinger