Patents by Inventor Fritz Pierre, JR.

Fritz Pierre, JR. has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11892233
    Abstract: A method and system for liquefying a methane-rich high-pressure feed gas stream using a first heat exchanger zone and a second heat exchanger zone. The feed gas stream is mixed with a refrigerant stream to form a second gas stream, which is compressed, cooled, and directed to a second heat exchanger zone to be additionally cooled below ambient temperature. It is then expanded to a pressure less than 2,000 psia and no greater than the pressure to which the second gas stream was compressed, and then separated into a first expanded refrigerant stream and a chilled gas stream. The first expanded refrigerant stream is expanded and then passed through the first heat exchanger zone such that it has a temperature that is cooler, by at least 5° F., than the highest fluid temperature within the first heat exchanger zone.
    Type: Grant
    Filed: November 4, 2021
    Date of Patent: February 6, 2024
    Assignee: ExxonMobil Technology and Engineering Company
    Inventor: Fritz Pierre, Jr.
  • Patent number: 11815308
    Abstract: A method and apparatus for producing liquefied natural gas. A portion of a natural gas stream is cooled in a first heat exchanger and re-combined with the natural gas stream, and heavy hydrocarbons are removed therefrom to generate a separated natural gas stream and a separator bottom stream. Liquids are separated from the separator bottom stream to form an overhead stream, which is cooled and separated to form a recycle gas stream. The recycle gas stream is compressed. A first portion of the compressed recycle gas stream is directed through the first heat exchanger and directed to the separator as a column reflux stream. The separated to natural gas stream is used as a coolant in the first heat exchanger to thereby generate a pretreated natural gas stream, which is compressed and liquefied.
    Type: Grant
    Filed: April 17, 2020
    Date of Patent: November 14, 2023
    Assignee: ExxonMobil Technology and Engineering Company
    Inventors: Yijun Liu, Fritz Pierre, Jr.
  • Patent number: 11806639
    Abstract: A method and apparatus for producing liquefied natural gas. A portion of a natural gas stream is cooled in a heat exchanger and combined with the natural gas stream. Heavy hydrocarbons are removed from the combined natural gas stream, and the resulting separated natural gas stream is partially condensed in the first heat exchanger, with a liquid stream separated therefrom. The natural gas stream is warmed in the first heat exchanger and then is compressed and cooled. The resultant cooled compressed natural gas stream is expanded, thereby forming a chilled natural gas stream that is separated into a refrigerant stream and a non-refrigerant stream. The refrigerant stream recycled to the heat exchanger to be warmed through heat exchange with one or more process streams associated with pretreating the natural gas stream, thereby generating a warmed refrigerant stream. The warmed refrigerant stream and the non-refrigerant stream are liquefied.
    Type: Grant
    Filed: April 17, 2020
    Date of Patent: November 7, 2023
    Assignee: ExxonMobil Technology and Engineering Company
    Inventors: Yijun Liu, Fritz Pierre, Jr.
  • Publication number: 20230136307
    Abstract: A method for liquefying a feed gas stream. A refrigerant stream is cooled and expanded to produce an expanded, cooled refrigerant stream. Part or all of the expanded, cooled refrigerant stream is mixed with a make-up refrigerant stream in a separator, thereby condensing heavy hydrocarbon components from the make-up refrigerant stream and forming a gaseous expanded, cooled refrigerant stream. The gaseous expanded, cooled refrigerant stream passes through a heat exchanger zone to form a warm refrigerant stream. The feed gas stream is passed through the heat exchanger zone to cool at least part of the feed gas stream by indirect heat exchange with the expanded, cooled refrigerant stream, thereby forming a liquefied gas stream. The warm refrigerant stream is compressed to produce the compressed refrigerant stream.
    Type: Application
    Filed: December 15, 2022
    Publication date: May 4, 2023
    Inventors: Yijun LIU, Fritz PIERRE, Jr.
  • Patent number: 11635252
    Abstract: A method is disclosed for start-up of a system for liquefying a feed gas stream comprising natural gas. The system has a feed gas compression and expansion loop, and a refrigerant system comprising a primary cooling loop and a sub-cooling loop. The feed gas compression and expansion loop is started up. The refrigerant system is pressurized. Circulation in the primary cooling loop is started and established. Circulation in the sub-cooling loop is started and established. A flow rate of the feed gas stream and circulation rates of the primary cooling loop and the sub-cooling loop are ramped up.
    Type: Grant
    Filed: July 30, 2019
    Date of Patent: April 25, 2023
    Assignee: ExxonMobil Technology and Engineering Company
    Inventors: Yijun Liu, Fritz Pierre, Jr., Ananda K. Nagavarapu, Xiaoli Y. Wright
  • Patent number: 11555651
    Abstract: A method for liquefying a feed gas stream. A refrigerant stream is cooled and expanded to produce an expanded, cooled refrigerant stream. Part or all of the expanded, cooled refrigerant stream is mixed with a make-up refrigerant stream in a separator, thereby condensing heavy hydrocarbon components from the make-up refrigerant stream and forming a gaseous expanded, cooled refrigerant stream. The gaseous expanded, cooled refrigerant stream passes through a heat exchanger zone to form a warm refrigerant stream. The feed gas stream is passed through the heat exchanger zone to cool at least part of the feed gas stream by indirect heat exchange with the expanded, cooled refrigerant stream, thereby forming a liquefied gas stream. The warm refrigerant stream is compressed to produce the compressed refrigerant stream.
    Type: Grant
    Filed: July 30, 2019
    Date of Patent: January 17, 2023
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Yijun Liu, Fritz Pierre, Jr.
  • Patent number: 11536510
    Abstract: A method and apparatus for producing liquefied natural gas. A pretreated natural gas stream is compressed in at least two serially arranged compressors to a pressure of at least 1,500 psia and cooled. The resultant cooled compressed natural gas stream is expanded in at least one work producing natural gas expander to a pressure less than 2,000 psia and no greater than the pressure to which natural gas stream has been compressed, thereby forming a chilled natural gas stream that is separated into a refrigerant stream and a non-refrigerant stream. The refrigerant stream is warmed in a heat exchanger through heat exchange with one or more process streams associated with pretreating the natural gas stream, thereby generating a warmed refrigerant stream. The warmed refrigerant stream and the non-refrigerant stream are then liquefied.
    Type: Grant
    Filed: May 13, 2019
    Date of Patent: December 27, 2022
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Yijun Liu, Fritz Pierre, Jr.
  • Patent number: 11506454
    Abstract: A method for liquefying a feed gas stream. A compressed first refrigerant stream is cooled and expanded to produce an expanded first refrigerant stream. The feed gas stream is cooled to within a first temperature range by exchanging heat only with the expanded first refrigerant stream to form a liquefied feed gas stream and a warmed first refrigerant stream. A compressed second refrigerant stream is provided is cooled to produce a cooled second refrigerant stream. At least a portion of the cooled second refrigerant stream is further cooled by exchanging heat with the expanded first refrigerant stream, and then is expanded to form an expanded second refrigerant stream. The liquefied feed gas stream is cooled to within a second temperature range by exchanging heat with the expanded second refrigerant stream to form a sub-cooled LNG stream and a first warmed, second refrigerant stream.
    Type: Grant
    Filed: July 30, 2019
    Date of Patent: November 22, 2022
    Assignee: ExxonMobile Upstream Research Company
    Inventor: Fritz Pierre, Jr.
  • Publication number: 20220074652
    Abstract: A method and system for liquefying a methane-rich high-pressure feed gas stream using a first heat exchanger zone and a second heat exchanger zone. The feed gas stream is mixed with a refrigerant stream to form a second gas stream, which is compressed, cooled, and directed to a second heat exchanger zone to be additionally cooled below ambient temperature. It is then expanded to a pressure less than 2,000 psia and no greater than the pressure to which the second gas stream was compressed, and then separated into a first expanded refrigerant stream and a chilled gas stream. The first expanded refrigerant stream is expanded and then passed through the first heat exchanger zone such that it has a temperature that is cooler, by at least 5° F., than the highest fluid temperature within the first heat exchanger zone.
    Type: Application
    Filed: November 4, 2021
    Publication date: March 10, 2022
    Inventor: Fritz Pierre, JR.
  • Publication number: 20210364229
    Abstract: Described herein are systems and processes of removing contaminants in a liquid nitrogen (LIN) stream used to produce liquefied natural gas (LNG). Greenhouse gas contaminants are removed from the LIN using a greenhouse gas removal unit. The LNG is compressed prior to being cooled by the LIN.
    Type: Application
    Filed: August 6, 2021
    Publication date: November 25, 2021
    Inventor: Fritz Pierre, JR.
  • Patent number: 11079176
    Abstract: A method for producing liquefied natural gas (LNG) from a natural gas stream having a nitrogen concentration of greater than 1 mol %. At least one liquid nitrogen (LIN) stream is received at an LNG liquefaction facility. The LIN streams may be produced at a different geographic location from the LNG liquefaction facility. A natural gas stream is liquefied by indirect heat exchange with a nitrogen vent stream to form a pressurized LNG stream. The pressurized LNG stream has a nitrogen concentration of greater than 1 mol %. The pressurized LNG stream is directed to one or more stages of a column to produce an LNG stream and the nitrogen vent stream. The column has upper stages and lower stages. The LIN streams are directed to one or more upper stages of the column.
    Type: Grant
    Filed: January 30, 2019
    Date of Patent: August 3, 2021
    Assignee: ExxonMobil Upstream Research Company
    Inventor: Fritz Pierre, Jr.
  • Patent number: 11060791
    Abstract: Described herein are systems and processes to produce liquefied natural gas (LNG) using liquefied nitrogen (LIN) as the refrigerant. Greenhouse gas contaminants are removed from the LIN using a greenhouse gas removal unit. The LNG is compressed prior to being cooled by the LIN.
    Type: Grant
    Filed: June 14, 2016
    Date of Patent: July 13, 2021
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Fritz Pierre, Jr., Parag A. Gupte, Richard A. Huntington, Robert D. Denton
  • Patent number: 10989358
    Abstract: A method for loading liquefied nitrogen (LIN) into a cryogenic storage tank initially containing liquid natural gas (LNG) and a vapor space above the LNG. First and second nitrogen gas streams are provided. The first nitrogen stream has a lower temperature than the second nitrogen gas stream. While the LNG is offloaded from the storage tank, the first nitrogen gas stream is injected into the vapor space. The storage tank is then purged by injecting the second nitrogen gas stream into the storage tank to thereby reduce a natural gas content of the vapor space to less than 5 mol %. After purging the storage tank, the storage tank is loaded with LIN.
    Type: Grant
    Filed: April 21, 2020
    Date of Patent: April 27, 2021
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Robert D. Kaminsky, Fritz Pierre, Jr.
  • Publication number: 20210086099
    Abstract: A method and apparatus for producing liquefied natural gas. A portion of a natural gas stream is cooled in a heat exchanger and combined with the natural gas stream. Heavy hydrocarbons are removed from the combined natural gas stream, and the resulting separated natural gas stream is partially condensed in the first heat exchanger, with a liquid stream separated therefrom. The natural gas stream is warmed in the first heat exchanger and then is compressed and cooled. The resultant cooled compressed natural gas stream is expanded, thereby forming a chilled natural gas stream that is separated into a refrigerant stream and a non-refrigerant stream. The refrigerant stream recycled to the heat exchanger to be warmed through heat exchange with one or more process streams associated with pretreating the natural gas stream, thereby generating a warmed refrigerant stream. The warmed refrigerant stream and the non-refrigerant stream are liquefied.
    Type: Application
    Filed: April 17, 2020
    Publication date: March 25, 2021
    Inventors: Yijun LIU, Fritz Pierre, JR.
  • Publication number: 20210088275
    Abstract: A method and apparatus for producing liquefied natural gas. A portion of a natural gas stream is cooled in a first heat exchanger and re-combined with the natural gas stream, and heavy hydrocarbons are removed therefrom to generate a separated natural gas stream and a separator bottom stream. Liquids are separated from the separator bottom stream to form an overhead stream, which is cooled and separated to form a recycle gas stream. The recycle gas stream is compressed. A first portion of the compressed recycle gas stream is directed through the first heat exchanger and directed to the separator as a column reflux stream. The separated to natural gas stream is used as a coolant in the first heat exchanger to thereby generate a pretreated natural gas stream, which is compressed and liquefied.
    Type: Application
    Filed: April 17, 2020
    Publication date: March 25, 2021
    Inventors: Yijun LIU, Fritz PIERRE, JR.
  • Patent number: 10663115
    Abstract: A method for loading liquefied nitrogen (LIN) into a cryogenic storage tank initially containing liquid natural gas (LNG) and a vapor space above the LNG. First and second nitrogen gas streams are provided. The first nitrogen stream has a lower temperature than the second nitrogen gas stream. While the LNG is offloaded from the storage tank, the first nitrogen gas stream is injected into the vapor space. The storage tank is then purged by injecting the second nitrogen gas stream into the storage tank to thereby reduce a natural gas content of the vapor space to less than 5 mol %. After purging the storage tank, the storage tank is loaded with LIN.
    Type: Grant
    Filed: January 17, 2018
    Date of Patent: May 26, 2020
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Robert D. Kaminsky, Fritz Pierre, Jr.
  • Patent number: 10578354
    Abstract: Described herein are systems and processes to produce liquefied nitrogen (LIN) using liquefied natural gas (LNG) as the refrigerant. The LIN may be produced by indirect heat exchange of at least one nitrogen gas stream with at least two LNG streams within at least one heat exchanger where the LNG streams are at different pressures.
    Type: Grant
    Filed: June 14, 2016
    Date of Patent: March 3, 2020
    Assignee: ExxonMobil Upstream Reseach Company
    Inventors: Fritz Pierre, Jr., Parag A. Gupte, Richard A. Huntington
  • Publication number: 20200064062
    Abstract: A method is disclosed for start-up of a system for liquefying a feed gas stream comprising natural gas. The system has a feed gas compression and expansion loop, and a refrigerant system comprising a primary cooling loop and a sub-cooling loop. The feed gas compression and expansion loop is started up. The refrigerant system is pressurized. Circulation in the primary cooling loop is started and established. Circulation in the sub-cooling loop is started and established. A flow rate of the feed gas stream and circulation rates of the primary cooling loop and the sub-cooling loop are ramped up.
    Type: Application
    Filed: July 30, 2019
    Publication date: February 27, 2020
    Inventors: Yijun LIU, Fritz PIERRE, JR., Ananda K. NAGAVARAPU, Xiaoli Y. WRIGHT
  • Publication number: 20200064061
    Abstract: A method for liquefying a feed gas stream. A refrigerant stream is cooled and expanded to produce an expanded, cooled refrigerant stream. Part or all of the expanded, cooled refrigerant stream is mixed with a make-up refrigerant stream in a separator, thereby condensing heavy hydrocarbon components from the make-up refrigerant stream and forming a gaseous expanded, cooled refrigerant stream. The gaseous expanded, cooled refrigerant stream passes through a heat exchanger zone to form a warm refrigerant stream. The feed gas stream is passed through the heat exchanger zone to cool at least part of the feed gas stream by indirect heat exchange with the expanded, cooled refrigerant stream, thereby forming a liquefied gas stream. The warm refrigerant stream is compressed to produce the compressed refrigerant stream.
    Type: Application
    Filed: July 30, 2019
    Publication date: February 27, 2020
    Inventors: Yijun LIU, Fritz PIERRE, JR.
  • Publication number: 20200064060
    Abstract: A method for liquefying a feed gas stream. A compressed first refrigerant stream is cooled and expanded to produce an expanded first refrigerant stream. The feed gas stream is cooled to within a first temperature range by exchanging heat only with the expanded first refrigerant stream to form a liquefied feed gas stream and a warmed first refrigerant stream. A compressed second refrigerant stream is provided is cooled to produce a cooled second refrigerant stream. At least a portion of the cooled second refrigerant stream is further cooled by exchanging heat with the expanded first refrigerant stream, and then is expanded to form an expanded second refrigerant stream. The liquefied feed gas stream is cooled to within a second temperature range by exchanging heat with the expanded second refrigerant stream to form a sub-cooled LNG stream and a first warmed, second refrigerant stream.
    Type: Application
    Filed: July 30, 2019
    Publication date: February 27, 2020
    Inventor: Fritz PIERRE, JR.