Patents by Inventor Fritz Sadowski

Fritz Sadowski has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5731382
    Abstract: Coating agents are described, that are suitable for the production of pigmented or transparent top coatings, based on hydroxy-functional (meth)acrylic copolymers, aliphatic and/or cycloaliphatic polyisocyanates, solvents, and customary lacquer additives and pigments. They are free from epoxy resins and nitrocellulose and contain as binderA) one or more (meth)acrylic copolymers, containing hydroxyl groups, froma1) 47-53 wt % of one or more aromatic vinyl compounds,a2) 28-33 wt % of one or more hydroxyalkyl methacrylates,a3) 14-19 wt % of one or more alkyl (meth)acrylates, anda4) 0.5-2 wt % acrylic acid and/or methacrylic acid,with a hydroxyl number of 120-160 mg KOH/g, an acid number of 5 to 15 mg KOH/g, a weight-average molecular weight of 10,000 to 20,000 and a glass transition temperature of +40.degree. C. to +60.degree. C., andB) an aliphatic and/or cycloaliphatic polyisocyanate or a mixture of such polyisocyanates in such an amount that 0.5 to 2.
    Type: Grant
    Filed: September 24, 1996
    Date of Patent: March 24, 1998
    Assignee: Herberts GmbH
    Inventors: Klaus Bederke, Gerhard Bremer, Hermann Kerber, Manfred Krumme, Fritz Sadowski, Werner Stephan, Olaf Ley
  • Patent number: 5708117
    Abstract: The description relates to coating agents for use as primers and fillers in the manufacture of multilayer lacquer coatings, more particularly in the motor-vehicle sector.The coating agent contains a binder mixture ofA) 60-75 wt. % of a hydroxy-functional copolymer with an OH number of 110 to 170 mg KOH/g, obtainable froma) 5-60 wt. %, preferably 10-30 wt. % of at least one diester of an alpha, beta-olefinically unsaturated dicarboxylic acid with saturated monohydric alcohols containing 1-8 carbon atoms,b) 10-70 wt. %, preferably 35-60 wt. % of one or more vinyl aromatic hydrocarbons,c) 0-30 wt. %, preferably 0-15 wt. % of one or more glycidyl esters of aliphatic saturated monocarboxylic acids branched in the alpha position,d) 25-50 wt. % of at least one hydroxy alkyl ester or a mixture of at least one alkyl ester and one hydroxyl alkyl ester of an alpha, beta-olefinically unsaturated monocarboxylic acid, ande) 0-10 wt. % of one or more alpha, beta-unsaturated monocarboxylic acids,B) 1-6 wt.
    Type: Grant
    Filed: March 11, 1996
    Date of Patent: January 13, 1998
    Assignee: Herberts Gesellschaft mit Beschrankter Haftung
    Inventors: Heinz Dietholf Becker, Gerhard Bremer, Fritz Sadowski, Werner Stephan
  • Patent number: 5635559
    Abstract: The description relates to physically drying water-based coating agents. They contain water, metallic pigments, optional other pigments, neutralizing agents, conventional additives, small proportions of solvents and a binder mixture consisting ofA) 50 to 90 wt. % polyurethanes with carbonate groupings and a number average molecular weight of 70000 to 500000 based on reaction products of polyisocyanates with polyhydroxyl compounds, with a content of polyhydroxy polycarbonates andB) 10 to 50 wt. % of carboxylic acid ester groups containing polyurethanes with a number average molecular weight of 20000 to 100000.They are particularly suitable for manufacturing metallic lacquers for repairs in the motor vehicle sector.
    Type: Grant
    Filed: October 18, 1995
    Date of Patent: June 3, 1997
    Assignee: Herberts Gesellschaft mit Beschrankter Haftung
    Inventors: Thomas Brock, Hans-Peter Patzschke, Fritz Sadowski
  • Patent number: 5480936
    Abstract: Oligoester acrylate resins having a high content of solids and comparatively low viscosity, and aqueous coating agents with a low content of organic solvents for obtaining coatings with high resistance to chemicals, more particularly high resistance to acids and oily soot, and very low tendency to yellowing.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: January 2, 1996
    Assignee: Herberts Gesellschaft mit beschranker Haftung
    Inventors: Volker Duecoffre, Carmen Flosbach, Walter Schubert, Manfred Krumme, Werner Stephan, Fritz Sadowski
  • Patent number: 5426156
    Abstract: Previous two-component coatings with enamine components cured very slowly at low temperatures and led to yellowed products. A binder composition is prepared which cures rapidly at low temperatures and leads to non-yellowing products. It contains as CH-acid component a polymer with at least two enamine functions in the molecule, obtained byA) transesterification of a .beta.-keto-ester with hydroxyl-group-containing compounds or polymers which contain at least two hydroxyl groups in the molecule, with an OH value of at least 50 and a number-average molecular weight of 500 to 10,000, followed by reaction with ammonia or primary and/or secondary amines, andB) as .alpha.,.beta.-unsaturated component a compound with at least two groups of the general formula R.sub.1 R.sub.2 C.dbd.CR.sub.3 --X; in which X signifies --CO-- which is bonded via the residue of a di- or polyhydric alcohol, a di- or polyamine or an aminoalcohol to a further R.sub.1 R.sub.2 C.dbd.CR.sub.3 --X group, where R.sub.1, R.sub.2 and R.sub.
    Type: Grant
    Filed: November 16, 1994
    Date of Patent: June 20, 1995
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Klaus Bederke, Hermann Kerber, Walter Schubert, Gerhard Bremer, Thomas Brock, Fritz Sadowski
  • Patent number: 5426138
    Abstract: A binding-agent composition for solvent-based or aqueous coating agents can be cured at low temperature to produce coatings which are non-yellowing and resistant to solvents. The binding-agent composition contains binding-agent components based on polyethers, polyesters, polyether polyesters and/or (meth)acrylic copolymers with, in each case, at least one acryloyl group and at least one epoxide group in the molecule, whereby the acryloyl groups and epoxide groups are present in the ratio 2:8 to 8:2. Also included are several polyamines as curing agents in a proportion of equivalent weights ranging from 2:0.5 to 1:1.5. The binding agents are used in pigmented and pigment-free lacquers, for use particularly in multi-layer lacquering.
    Type: Grant
    Filed: April 29, 1994
    Date of Patent: June 20, 1995
    Assignee: Herberts GmbH
    Inventors: Klaus Bederke, Hermann Kerber, Walter Schubert, Thomas Brock, Fritz Sadowski, Helmut Loffler
  • Patent number: 5420205
    Abstract: A binder composition suitable for coating agents is described, that contains one or more unsaturated polyesters with an acid number of 5-60 mg KOH/g, a hydroxyl number of 50-200 mg KOH/g and a weight-average molecular weight (Mw) of 500-3000 g/mol, that are obtainable by reaction ofA) one or more alpha,beta-ethylenically unsaturated dicarboxylic acids or their anhydrides,B) one or more hydroxy-functional allyl ethers andC) one or more ethylenically unsaturated compounds with an oxirane group in the molecule,in the molar ratio of A):B):C)=(2 to 4):(2 to 4):(0.5 to 1.8). The composition is suitable in particular for filling putties and filling compounds that dry rapidly, even at low temperatures.
    Type: Grant
    Filed: June 20, 1994
    Date of Patent: May 30, 1995
    Assignee: Herberts Gesellschaft mis beschrankter Haftung
    Inventors: Heinz D. Becker, Klaus Bederke, Gerhard Bremer, Herrmann Kerber, Birgit Precht, Fritz Sadowski, Werner Stephan
  • Patent number: 5412000
    Abstract: A coating and primer composition suitable as a primer for plastics such as a polyolefin which comprises: a) from about 1 to 5% by weight of ethylene/vinyl acetate copolymers, b) from about 0.5 to 5% by weight of chlorinated polyolefins, c) from about 0.01 to 5% by weight of an epoxy resin; and d) from about 85 to 98.49% by weight of an organic solvent, and optionally paint auxiliaries, pigments and/or fillers.A method of priming plastic surfaces of an object, especially polyolefins, and particularly polypropylene, is also provided which comprises applying the aforesaid composition to a plastic surface and drying the same prior to applying paint or finish coating.
    Type: Grant
    Filed: March 17, 1994
    Date of Patent: May 2, 1995
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Udo Hellmann, Werner Stephan, Fritz Sadowski
  • Patent number: 5401795
    Abstract: The description relates to a physically drying water-based coating agent. It contains water, pigments, neutralizing agents, conventional additives, small proportions of solvents and a binder mixture consisting ofA) 10 to 90 wt. % polyurethanes with carbonate groupings and a glass transition temperature of <0.degree. C. based on reaction products of polyisocyanates with polyhydroxyl compounds, with a content of polyhydroxy polycarbonates andB) 90 to 10 wt. % of reaction products of carboxy-functional polycondensates and .alpha.,.beta.-olefinically unsaturated monomers with a glass transition temperature of >0.degree. C. in the form of an aqueous dispersion.The coating agent is particularly suitable for manufacturing lacquers for repairs in the motor vehicle sector.
    Type: Grant
    Filed: April 19, 1993
    Date of Patent: March 28, 1995
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Thomas Brock, Hans-Peter Patzschke, Fritz Sadowski
  • Patent number: 5136004
    Abstract: The invention concerns a binder suitable for clear or pigmented coating agents. Binders based on copolymers containing hydroxyl groups have hitherto a high solvent content. The solids content of the new binders is improved without affecting the viscosity; gloss, body, flow and processing properties of coatings containing the new binders are improved. The binders consist essentially of a copolymer containing hydroxyl groups, made from specific quantities of styrol, tertbutacrylate, isobutyl methacrylate, 2-ethylhexyl methacrylate, 2-hydroxypropyl methacrylate, butanediol-1, 4-monoacrylate, acrylic acid and glycidyl esters of .alpha.-alkylalkane monocarboxylic acids and/or .alpha.,.alpha.-dialkylalkane monocarboxylic acids.
    Type: Grant
    Filed: November 13, 1990
    Date of Patent: August 4, 1992
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Klaus Bederke, Hermann Kerber, Manfred Krumme, Fritz Sadowski, Werner Stephan
  • Patent number: 4855342
    Abstract: Previous coating materials lead to the formation of bubbles at high layer thickness and when drying by heating. The new coating materials are intended to be bubble-free when dried at higher layer thicknesses.Aside from pigments and/or extenders, the coating material contains solvents and, if necessary, conventional paint auxiliaries in a vehicle mixture, comprising essentially 60-75% by weight of a hydroxy-functional copolymer, 1-5% by weight of an ester-soluble nitrocellulose and 25-35% by weight of difunctional or multifunctional polyisocyanate. It can be cured without forming bubbles even when applied in thick layers.Use as primer and filler.
    Type: Grant
    Filed: November 19, 1987
    Date of Patent: August 8, 1989
    Assignee: Herberts Gesellschaft
    Inventors: Heinz D. Becker, Klaus Bederke, Ralf Dahm, Hermann Kerber, Fritz Sadowski, Werner Stephan