Patents by Inventor Fujito Ehara

Fujito Ehara has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7300998
    Abstract: The object of the present invention is to provide a high quality polyester resin having high productivity, stability and safety, a catalyst for polyester production with high catalytic activity, a method for producing the polyester resin with the catalyst, a polyester resin obtained with the catalyst, and a hollow molded container having the polyester resin. The polyester resin of the present invention satisfies specific parameters regarding polymerizability, stability, and metal content. The catalyst for polyester production satisfies specific parameters. The catalyst particularly preferably has: (a) a solid titanium-containing compound which has a maximum solubility in ethylene glycol of 1,000 ppm or more in terms of converted titanium amount when dissolved in ethylene glycol with heating at 150° C.
    Type: Grant
    Filed: February 13, 2003
    Date of Patent: November 27, 2007
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hideshi Hori, Fujito Ehara, Shouji Hiraoka, Ken Maeda, Tomohiro Suzuki, Nobumasa Mukai
  • Publication number: 20050107576
    Abstract: The object of the present invention is to provide a high quality polyester resin having high productivity, stability and safety, a catalyst for polyester production with high catalytic activity, a method for producing the polyester resin with the catalyst, a polyester resin obtained with the catalyst, and a hollow molded container comprising the polyester resin. The polyester resin of the present invention satisfies specific parameters regarding polymerizability, stability, and metal content. The catalyst for polyester production satisfies specific parameters. The catalyst particularly preferably comprises: (a) a solid titanium-containing compound which has a maximum solubility in ethylene glycol of 1,000 ppm or more in terms of converted titanium amount when dissolved in ethylene glycol with heating at 150° C.
    Type: Application
    Filed: February 13, 2003
    Publication date: May 19, 2005
    Inventors: Hideshi Hori, Fujito Ehara, Shouji Hiraoka, Ken Maeda, Tomohiro Suzuki, Nobumasa Mukai
  • Patent number: 6649731
    Abstract: By the present invention, there are provided a catalyst for polyester preparation, which comprises a solid titanium compound containing titanium, oxygen, carbon and hydrogen and having a Ti—O bond and which has a maximum solubility in ethylene glycol, as measured when the catalyst is dissolved in ethylene glycol under heating at 150° C., of not less than 3,000 ppm in terms of a titanium atom, a catalyst for polyester preparation, which comprises a titanium-containing solution wherein a contact product of a hydrolyzate of a titanium halide or a hydrolyzate of a titanium alkoxide with a polyhydric alcohol is dissolved in ethylene glycol in an amount of 3,000 to 100,000 ppm in terms of a titanium atom, a process for preparing a polyester using the catalyst, and a polyester prepared by the process.
    Type: Grant
    Filed: April 18, 2002
    Date of Patent: November 18, 2003
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hideshi Hori, Fujito Ehara, Akiyoshi Shimizu, Nobumasa Mukai, Shoji Hiraoka
  • Publication number: 20020193555
    Abstract: By the present invention, there are provided a catalyst for polyester preparation, which comprises a solid titanium compound containing titanium, oxygen, carbon and hydrogen and having a Ti—O bond and which has a maximum solubility in ethylene glycol, as measured when the catalyst is dissolved in ethylene glycol under heating at 150° C., of not less than 3,000 ppm in terms of a titanium atom, a catalyst for polyester preparation, which comprises a titanium-containing solution wherein a contact product of a hydrolyzate of a titanium halide or a hydrolyzate of a titanium alkoxide with a polyhydric alcohol is dissolved in ethylene glycol in an amount of 3,000 to 100,000 ppm in terms of a titanium atom, a process for preparing a polyester using the catalyst, and a polyester prepared by the process.
    Type: Application
    Filed: April 18, 2002
    Publication date: December 19, 2002
    Inventors: Hideshi Hori, Fujito Ehara, Akiyoshi Shimizu, Nobumasa Mukai, Shoji Hiraoka
  • Publication number: 20020137879
    Abstract: The present invention provides a catalyst or polyester production capable of producing a polyester with high catalytic activity and a process For producing a polyester using the catalyst. The catalyst for polyester production comprises a solid titanium compound which is obtained by dehydro-drying a hydrolyzate obtained by hydrolysis of a titanium halide and which has a molar ratio (OH/Ti) of a hydroxyl group (OH) to titanium (Ti) exceeding 0.09 and less than 4. The present invention also provides a method to obtain a polyester having a small increase of the acetaldehyde content during the molding. This method comprises bringing a polyester, which is obtained by the use of a titanium compound catalyst and in which the reaction has been completed, into contact with a phosphoric ester aqueous solution or the like having a concentration of not less than 10 ppm in terms of phosphorus atom.
    Type: Application
    Filed: December 21, 2001
    Publication date: September 26, 2002
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Takeshi Ohmatsuzawa, Fujito Ehara, Hideshi Hori, Kazuo Toyota, Kenzaburou Fukutani, Junichi Imuta, Akivoshi Shimizu, Takayuki Onogi, Seiji Noda, Sayuki Sakai, Shoji Hiraoka, Koji Nakamachi, Michio Tsugawa, Satoru Miyazoe
  • Patent number: 6451959
    Abstract: The present invention provides a catalyst for polyester production capable of producing a polyester with high catalytic activity, a process for producing a polyester using the catalyst and a polyester produced thereby. The catalyst comprises a solid titanium compound obtained by dehydro-drying a hydrolyzate obtained by hydrolysis of a titanium halide and which has a molar ratio (OH/Ti) of a hydroxyl group (OH) to titanium (Ti) exceeding 0.09 and less than 4. In the process, the polyester is obtained by polycondensing an aromatic dicarboxylic acid, or an ester-forming derivative thereof, and an aliphatic diol, or ester-forming derivative thereof, in the presence of the catalyst. The resulting polyester has excellent transparency and tint, a titanium content of 1 to 100 ppm, a magnesium content of 1 to 200 ppm and a magnesium to titanium weight ratio of not less than 0.01.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: September 17, 2002
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Takeshi Ohmatsuzawa, Fujito Ehara, Hideshi Hori, Kazuo Toyota, Kenzaburou Fukutani, Junichi Imuta, Akivoshi Shimizu, Takayuki Onogi, Seiji Noda, Masayuki Sakai, Shoji Hiraoka, Koji Nakamachi, Michio Tsugawa, Satoru Miyazoe
  • Patent number: 6346070
    Abstract: The present invention provides a catalyst for polyester production capable of producing a polyester with high catalytic activity and a process for producing a polyester using the catalyst. The catalyst for polyester production comprises a solid titanium compound which is obtained by dehydro-drying a hydrolyzate obtained by hydrolysis of a titanium halide and which has a molar ratio (OH/Ti) of a hydroxyl group (OH) to titanium (Ti) exceeding 0.09 and less than 4. The present invention also provides a method to obtain a polyester having a small increase of the acetaldehyde content during the molding. This method comprises bringing a polyester, which is obtained by the use of a titanium compound catalyst and in which the reaction has been completed, into contact with a phosphoric ester aqueous solution or the like having a concentration of not less than 10 ppm in terms of phosphorus atom.
    Type: Grant
    Filed: December 22, 1999
    Date of Patent: February 12, 2002
    Assignee: Mitsui Chemicals Inc
    Inventors: Takeshi Ohmatsuzawa, Fujito Ehara, Hideshi Hori, Kazuo Toyota, Kenzaburou Fukutani, Junichi Imuta, Akiyoshi Shimizu, Takayuki Onogi, Seiji Noda, Masayuki Sakai, Shoji Hiraoka, Koji Nakamachi, Michio Tsugawa, Satoru Miyazoe
  • Patent number: 5368739
    Abstract: An activated carbon oxidized by air or oxygen at near ambient temperatures having a contact pH between 7.6 and 8.5 for use in water treatment systems to prevent pH excursions during operation of the system.
    Type: Grant
    Filed: September 1, 1993
    Date of Patent: November 29, 1994
    Assignee: Calgon Carbon Corporation
    Inventors: Bertrand W. Dussert, Richard A. Hayden, John R. Lutchko, Kishio Yoshino, Satoru Hisaki, Fujito Ehara
  • Patent number: RE40571
    Abstract: The present invention provides a catalyst for polyester production capable of producing a polyester with high catalytic activity, a process for producing a polyester using the catalyst and a polyester produced thereby. The catalyst comprises a solid titanium compound obtained by dehydro-drying a hydrolyzate obtained by hydrolysis of a titanium halide and which has a molar ratio (OH/Ti) of a hydroxyl group (OH) to titanium (Ti) exceeding 0.09 and less than 4. In the process, the polyester is obtained by polycondensing an aromatic dicarboxylic acid, or an ester-forming derivative thereof, and an aliphatic diol, or ester-forming derivative thereof, in the presence of the catalyst. The resulting polyester has excellent transparency and tint, a titanium content of 1 to 100 ppm, a magnesium content of 1 to 200 ppm and a magnesium to titanium weight ratio of not less than 0.01.
    Type: Grant
    Filed: September 16, 2004
    Date of Patent: November 11, 2008
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Takeshi Ohmatsuzawa, Fujito Ehara, Hideshi Hori, Kazuo Toyota, Kenzaburou Fukutani, Junichi Imuta, Akiyoshi Shimizu, Takayuki Onogi, Seiji Noda, Masayuki Sakai, Shoji Hiraoka, Koji Nakamachi, Michio Tsugawa, Satoru Miyazoe