Abstract: Provided is a polyvinylidene fluoride resin adhesive film that restores the transparency of a damaged transparent base material by smoothing the surface irregularity generated by damaging and has surface-protecting properties superior in weather fastness and stain resistance. A polyvinylidene fluoride resin adhesive film, comprising a resin composition layer containing a polyvinylidene fluoride resin in an amount of 0 to 50 mass % and a polymethacrylic ester resin in an amount of 100 to 50 mass % (100% in total) and additionally an ultraviolet absorbent in an amount of 0.1 to 15 mass % with respect to the resin components therein, a resin composition layer laminated on one face thereof, containing a polyvinylidene fluoride resin in an amount of 100 to 50 mass % and a polymethacrylic ester resin in an amount of 0 to 50 mass % (100% in total) and an acrylic adhesive layer formed on the other face thereof.

Abstract: Disclosed is a fluorine-containing resin film which is formed from a fluorine-containing resin composition and has a thickness of 10 to 50 ?m, wherein the fluorine-containing resin composition is prepared by adding 10 to 30 parts by mass of titanium oxide or a composite-oxide-type inorganic pigment to 100 parts by mass of a resin component comprising 60 to 95 parts by mass of a vinylidene fluoride resin and 5 to 40 parts by mass of a methacrylic acid ester resin, and wherein the peak intensity ratio of a II-type crystal, which is expressed by (A)/((A)+(B))×100 wherein A represents the peak height at 840 cm?1 and B represents the peak height at 765 cm?1 in a measurement chart produced by an infrared absorption spectrum, is 60% or more and the total crystallinity is 30% or more as calculated from an X-ray diffraction profile.

Abstract: Disclosed is a fluorine-containing resin film which is formed from a fluorine-containing resin composition and has a thickness of 10 to 50 ?m, wherein the fluorine-containing resin composition is prepared by adding 10 to 30 parts by mass of titanium oxide or a composite-oxide-type inorganic pigment to 100 parts by mass of a resin component comprising 60 to 95 parts by mass of a vinylidene fluoride resin and 5 to 40 parts by mass of a methacrylic acid ester resin, and wherein the peak intensity ratio of a II-type crystal, which is expressed by (A)/((A)+(B))×100 wherein A represents the peak height at 840 cm?1 and B represents the peak height at 765 cm?1 in a measurement chart produced by an infrared absorption spectrum, is 60% or more and the total crystallinity is 30% or more as calculated from an X-ray diffraction profile.

Abstract: Provided is a vinylidene fluoride resin composition resistant to yellowing in the test for evaluation of durability of moist heat resistance, even when it is laminated directly on an ethylene vinyl acetate copolymer (EVA)-based sealing material, and a resin film, a back sheet for solar cells and a solar cell module comprising the same. A vinylidene fluoride resin composition at least comprising a vinylidene fluoride resin having a peak value ratio of head-to-tail bond to head-to-head bond (head-to-tail bond/head-to-head bond), as determined by 1H-NMR, of 11.5 or less and a mass-average molecular weight (Mw) of 1.30×105 or more, and an antioxidant is processed into a vinylidene fluoride resin film having a thickness of 10 to 200 ?m. The vinylidene fluoride resin film and an electric insulating resin film such as polyethylene terephthalate-based film are laminated, to give a back sheet for solar cells.

Abstract: Provided is a vinylidene fluoride resin film that has good adhesiveness to a base material, achieves good dispersivity even when a pigment is contained in large amounts, and has excellent thermal stability during a forming process. To a resin component composed of a vinylidene fluoride resin and a methacrylic acid ester resin, a predetermined amount of a titanium oxide surface treated with alumina and silica and a predetermined amount of a fatty acid ester of polyethylene glycol and/or its derivative are added to prepare a vinylidene fluoride resin film. Alternatively, at least a front side layer and a back side layer have such a composition, the front side layer has a combination amount of the vinylidene fluoride resin and the methacrylic acid ester resin of 70:30 to 95:5 in terms of mass ratio, and the back side layer has a combination amount of the vinylidene fluoride resin and the methacrylic acid ester resin of 5:95 to 45:55 in terms of mass ratio.

Abstract: Disclosed is a fluorine-containing resin film which is formed from a fluorine-containing resin composition and has a thickness of 10 to 50 wherein the fluorine-containing resin composition is prepared by adding 10 to 30 parts by mass of titanium oxide or a composite-oxide-type inorganic pigment to 100 parts by mass of a resin component comprising 60 to 95 parts by mass of a vinylidene fluoride resin and 5 to 40 parts by mass of a methacrylic acid ester resin, and wherein the peak intensity ratio of a II-type crystal, which is expressed by (A)/((A)+(B))×100 wherein A represents the peak height at 840 cm?1 and B represents the peak height at 765 cm?1 in a measurement chart produced by an infrared absorption spectrum, is 60% or more and the total crystallinity is 30% or more as calculated from an X-ray diffraction profile.

Abstract: Provided is a vinylidene fluoride resin composition resistant to yellowing in the test for evaluation of durability of moist heat resistance, even when it is laminated directly on an ethylene vinyl acetate copolymer (EVA)-based sealing material, and a resin film, a back sheet for solar cells and a solar cell module comprising the same. A vinylidene fluoride resin composition at least comprising a vinylidene fluoride resin having a peak value ratio of head-to-tail bond to head-to-head bond (head-to-tail bond/head-to-head bond), as determined by 1H-NMR, of 11.5 or less and a mass-average molecular weight (Mw) of 1.30×105 or more, and an antioxidant is processed into a vinylidene fluoride resin film having a thickness of 10 to 200 ?m. The vinylidene fluoride resin film and an electric insulating resin film such as polyethylene terephthalate-based film are laminated, to give a back sheet for solar cells.

Abstract: Provided is a polyvinylidene fluoride resin composition that has good inorganic pigment dispersivity. Based on 100 parts by mass of a resin component containing two types of polyvinylidene fluorides having different forms or different melt flow characteristics in a total amount of 50 to 95% by mass and polymethyl methacrylate in an amount of 5 to 50% by mass, 7 to 40 parts by mass of a white inorganic pigment and 0.01 to 7 parts by mass of an inorganic pigment for toning are mixed to produce the resin composition. At that time, at least one of the two types of polyvinylidene fluorides to be used has an MFR (230° C., 3.8 kg load) of 3 to 35 g/10 min and the polymethyl methacrylate to be used has an MFR (230° C., 10 kg load) of 2 to 20 g/10 min.

Abstract: Provided is a vinylidene fluoride-based resin film resistant to pinhole generation caused by dispersion insufficiency and superior in thermal stability during molding processing, even if it contains a pigment in a large amount, and a solar cell back sheet and a solar cell module comprising the same. A vinylidene fluoride-based resin film is prepared by blending a vinylidene fluoride resin, a methacrylate ester resin, a titanium oxide surface-treated with alumina, silica, and zirconia, and a polyethylene glycol fatty acid ester and/or the derivative thereof at a certain ratio. Used then was a surface-treated titanium oxide with alumina, silica, and zirconia, having a total deposited amount of alumina, silica, and zirconia of 5 to 15 mass % and a deposited amount of zirconia of 0.5 mass % or more and less than 2.0 mass %.

Abstract: Provided are a polyvinylidene fluoride resin composition that has good inorganic pigment dispersivity and that is unlikely to cause a defect due to poor dispersion and has practical mechanical strength characteristics in a film to be formed, and a film, a back sheet, and a solar cell module. Based on 100 parts by mass of a resin component containing two types of polyvinylidene fluorides having different forms or different melt flow characteristics in a total amount of 50 to 95% by mass and polymethyl methacrylate in an amount of 5 to 50% by mass, 7 to 40 parts by mass of a white inorganic pigment and 0.01 to 7 parts by mass of an inorganic pigment for toning are mixed to produce the resin composition. At that time, at least one of the two types of polyvinylidene fluorides to be used has an MFR (230° C., 3.8 kg load) of 3 to 35 g/10 min and the polymethyl methacrylate to be used has an MFR (230° C., 10 kg load) of 2 to 20 g/10 min.

Abstract: Provided is a vinylidene fluoride resin film that has good adhesiveness to a base material, achieves good dispersivity even when a pigment is contained in large amounts, and has excellent thermal stability during a forming process. To a resin component composed of a vinylidene fluoride resin and a methacrylic acid ester resin, a predetermined amount of a titanium oxide surface treated with alumina and silica and a predetermined amount of a fatty acid ester of polyethylene glycol and/or its derivative are added to prepare a vinylidene fluoride resin film. Alternatively, at least a front side layer and a back side layer have such a composition, the front side layer has a combination amount of the vinylidene fluoride resin and the methacrylic acid ester resin of 70:30 to 95:5 in terms of mass ratio, and the back side layer has a combination amount of the vinylidene fluoride resin and the methacrylic acid ester resin of 5:95 to 45:55 in terms of mass ratio.