Abstract: A method of forming a film of photonic crystal material. A first process is performed upon a material capable of having a photonic crystal structure, this process causing deformation of the material so as to form a film in which incident light received by the material is selectively reflected or transmitted to generate a first optical effect in the film. A second process is performed upon substantially all of the film which applies a shear stress to the film. This causes a change in the material structure so as to generate a second optical effect in the film, different from the first optical effect, in response to incident light. Security films, devices, articles and documents formed using the method are also discussed.

Abstract: A composite optical device has a layer of a composite optical material mounted on a substrate. The layer of composite optical material has substantially uniform thickness. The composite optical material is a polymer opal, in that it has a three dimensional arrangement of core particles distributed in a matrix, the refractive index of the material of the core particles being different to the refractive index of the material of the matrix and the three dimensional arrangement being capable of having a periodicity such that, when a surface of the material is illuminated with white light, the composite material exhibits structural colour. The local stiffness of the substrate is different at different positions of the substrate.

Abstract: A method of forming a film of photonic crystal material. A first process is performed upon a material capable of having a photonic crystal structure, this process causing deformation of the material so as to form a film in which incident light received by the material is selectively reflected or transmitted to generate a first optical effect in the film. A second process is performed upon substantially all of the film which applies a shear stress to the film. This causes a change in the material structure so as to generate a second optical effect in the film, different from the first optical effect, in response to incident light. Security films, devices, articles and documents formed using the method are also discussed.

Abstract: The invention relates to a process for the preparation of inverse opals having adjustable channel diameters. This is achieved by partial fusing of solid organic or inorganic spheres.

Abstract: The invention relates to the use of core/shell particles whose shell forms a matrix and whose core is essentially solid, is built up essentially from an inorganic material and has an essentially monodisperse size distribution and is connected to the shell via an interlayer, for the production of mouldings having homogeneous, regularly arranged cavities and particles in the cavities, to a process for the production of mouldings having homogeneous, regularly arranged cavities, and to the corresponding mouldings.