Abstract: A structure including a first layer of one or more molecular components having a first top anchor group, a first functional moiety and a first bottom anchor group. The first functional moiety connects the first top anchor group to the first bottom anchor group. The structure further includes a first conductive film of one or more nanoparticles disposed on the first layer of one or more molecular components. Each of at least a portion of the one or more nanoparticles bond with the first top anchor group of the one or more molecular components. Each of at least a portion of the one or more nanoparticles cross-link with at least one other of the nanoparticles. The first conductive film forms a first contact for the first layer of one or more molecular components.

Abstract: A structure including a first layer of one or more molecular components having a first top anchor group, a first functional moiety and a first bottom anchor group. The first functional moiety connects the first top anchor group to the first bottom anchor group. The structure further includes a first conductive film of one or more nanoparticles disposed on the first layer of one or more molecular components. Each of at least a portion of the one or more nanoparticles bond with the first top anchor group of the one or more molecular components. Each of at least a portion of the one or more nanoparticles cross-link with at least one other of the nanoparticles. The first conductive film forms a first contact for the first layer of one or more molecular components.

Abstract: A method for forming a contact to a layer of one or more molecular components that comprises depositing one or more nanoparticles on the layer of one or more molecular components. Each of at least a portion of the one or more nanoparticles bond with each of at least a portion of the one or more molecular components. When there is more than one nanoparticle, each of at least a portion of the one and more nanoparticles cross-link with at least one other of the one or more nanoparticles. The bonded and cross-linked nanoparticles form both a mechanical and electrical contact for the layer of molecular components. The contact may further act as protection and sealing layers to preserve the chemical integrity at ambient operation conditions and/or enable mass and ionic exchange.

Abstract: A method for manufacturing a gap device includes forming a template structure on a substrate, depositing an active material layer on the substrate and on the template structure, wherein the active material layer covers at least top and side surfaces of the template structure, planarizing the active material layer, and selectively removing the template structure with respect to the active material layer and the substrate.

Abstract: A method for manufacturing a gap device includes forming a template structure on a substrate, depositing an active material layer on the substrate and on the template structure, wherein the active material layer covers at least top and side surfaces of the template structure, planarizing the active material layer, and selectively removing the template structure with respect to the active material layer and the substrate.

Abstract: A method for forming a contact to a layer of one or more molecular components that comprises depositing one or more nanoparticles on the layer of one or more molecular components. Each of at least a portion of the one or more nanoparticles bond with each of at least a portion of the one or more molecular components. When there is more than one nanoparticle, each of at least a portion of the one and more nanoparticles cross-link with at least one other of the one or more nanoparticles. The bonded and cross-linked nanoparticles form both a mechanical and electrical contact for the layer of molecular components. The contact may further act as protection and sealing layers to preserve the chemical integrity at ambient operation conditions and/or enable mass and ionic exchange.