Abstract: An index value is calculated for rating an eyeglass with respect to protection against UV hazard. The index value is based on an integrated UV transmission value through the eyeglass and an integrated UV reflection value related to a back face of the eyeglass. Thus, the index value takes into account actual wearing conditions where UV eye exposure is due either to transmission through the eyeglass or reflection on the eyeglass back face. Respective index values obtained for a set of eyeglasses allow easy sorting of the eyeglasses with respect to UV protection efficiency.

Abstract: An index value is calculated for rating an eyeglass with respect to protection against UV hazard. The index value is based on an integrated UV transmission value through the eyeglass and an integrated UV reflection value related to a back face of the eyeglass. Thus, the index value takes into account actual wearing conditions where UV eye exposure is due either to transmission through the eyeglass or reflection on the eyeglass back face. Respective index values obtained for a set of eyeglasses allow easy sorting of the eyeglasses with respect to UV protection efficiency.

Abstract: A method that includes providing a cavity defined by at least a portion of a mold and a closure member attached to the portion of the mold, the portion of the mold being oriented vertically and having a top and a bottom, and a sealing material being positioned near the bottom and attached to the closure member; puncturing the sealing material and the closure member with an instrument near the bottom, the puncturing creating an opening in the sealing material; and introducing a polymerizable composition into the cavity through the instrument. A method useful in testing sealing materials. Other methods are also disclosed.

Abstract: A method that includes providing a cavity defined by at least a portion of a mold and a closure member attached to the portion of the mold, the portion of the mold being oriented vertically and having a top and a bottom, and a sealing material being positioned near the bottom and attached to the closure member; puncturing the sealing material and the closure member with an instrument near the bottom, the puncturing creating an opening in the sealing material; and introducing a polymerizable composition into the cavity through the instrument. A method useful in testing sealing materials. Other methods are also disclosed.

Abstract: The invention relates to a process for polymerising a monomer, polymerizing and/or crosslinking an oligomer, or crosslinking a polymer or copolymer, said monomer, oligomer, polymer and copolymer being selected among precursor monomers, urethane, thiourethane and episulfide oligomers, and urethane, thiourethane and episulfide polymers and copolymers, which comprises: (a) adding to precursor monomers or oligomers or polymers or copolymers an effective amount of at least one complex of Co, Mo or W which under irradiation conditions photochemically reacts to release at least one anionically charged nucleophile or uncharged Lewis base; and (b) irradiating the mixture of (a) to release the at least one anionically charged nucleophile or uncharged Lewis base to initiate polymerisation and/or crosslinking of the monomer, oligomer, polymer or copolymer.

Abstract: The invention relates to a process for polymerising a monomer, polymerizing and/or crosslinking an oligomer, or crosslinking a polymer or copolymer, said monomer, oligomer, polymer and copolymer being selected among precursor monomers, urethane, thiourethane and episulfide oligomers, and urethane, thiourethane and episulfide polymers and copolymers, which comprises: (a) adding to precursor monomers or oligomers or polymers or copolymers an effective amount of at least one complex of Co, Mo or W which under irradiation conditions photochemically reacts to release at least one anionically charged nucleophile or uncharged Lewis base; and (b) irradiating the mixture of (a) to release the at least one anionically charged nucleophile or uncharged Lewis base to initiate polymerisation and/or crosslinking of the monomer, oligomer, polymer or copolymer.

Abstract: The invention relates to a process for polymerising a monomer, polymerizing and/or crosslinking a oligomer, or crosslinking a polymer or copolymer, said monomer, oligomer, polymer and copolymer being selected among precursor monomers, urethane, thiourethane and episulfide oligomers, and urethane, thiourethane and episulfide polymers and copolymers, which comprises: (a) adding to precursor monomers or oligomers or polymers or copolymers an effective amount of at least one complex of Co, Mo or W which under irradiation conditions photochemically reacts to release at least one anionically charged nucleophile or uncharged Lewis base; and (b) irridiating the mixture of (a) to release the at least one anionically charged nucleophile or uncharged Lewis base to initiate polymerisation and/or crosslinking of the monomer, oligomer, polymer or copolymer.

Abstract: A method that includes providing a cavity defined by at least a portion of a mold and a closure member attached to the portion of the mold, the portion of the mold being oriented vertically and having a top and a bottom, and a sealing material being positioned near the bottom and attached to the closure member; puncturing the sealing material and the closure member with an instrument near the bottom, the puncturing creating an opening in the sealing material; and introducing a polymerizable composition into the cavity through the instrument. A method useful in testing sealing materials. Other methods are also disclosed.

Abstract: A method of fast curing polythiourethane transparent casted substrate, usable for making optical articles such as ophthalmic lenses, which comprises the steps of: 1) Providing a first component A comprising a polythiourethane prepolymer having isocyanate or isothiocyanate end groups and a viscosity at 25° C. ranging from 0.02 to 0.4 Pa.s; 2) Providing a second component B comprising a polythiourethane prepolymer having thiol (SH) end groups and a viscosity at 25° C. ranging from 0.2 to 2.0 Pa.s; 3) Mixing together first and second components A and B and filling a moulding cavity of a casting mould assembly with the resulting mixture; 4) Curing said mixture to obtain a transparent solid substrate, said curing step comprising: a) a first step for polymerizing said mixture to obtain a gel within 1 to 10 minutes; and b) a second step of post-curing the gel to obtain the transparent solid substrate; and 5) Recovering the transparent solid substrate from the mould.

Abstract: The polymerizable compositions comprise: A) at least one polyiso(thio)cyanate monomer, and at least one polythiol monomer; or at least one episulfide compound and optionally one or more compounds having two or more functional groups capable of reacting with episulfide groups; and B) as polymerization catalyst, an effective amount of a salt of formula MmP+Yn? Y? is an anion such as the corresponding acid YH has a pKa fulfilling the condition 0.5?pKa?14 with the proviso that when the polymerizable compositions comprise an episulfide compound and MP+ is an ammonium group, the polymerizable composition also comprises an electro-donor compound. Application to the fabrication of optical articles, such as lenses.

Abstract: A method of fast curing polythiourethane transparent casted substrate, usable for making optical articles such as ophthalmic lenses, which comprises the steps of:

Abstract: A method for molding a plastic ophthalmic lens which comprises introducing a liquid polymerizable composition in a molding cavity of a two-piece mold through a filling nozzle in flow communication with the upper half of the molding cavity and spaced apart from the central vertical axis of the molding cavity up to the time the lower half of the molding cavity is filled. Then, tilting the mold to bring the filling in register with the central axis of the molding cavity and achieving full filling of the molding cavity. Thereafter, polymerizing the composition and recovering the lens.

Abstract: A method for molding a plastic ophthalmic lens which comprises introducing a liquid polymerizable composition in a molding cavity of a two-piece mold through a filling nozzle in flow communication with the upper half of the molding cavity and spaced apart from the central vertical axis of the molding cavity up to the time the lower half of the molding cavity is filled. Then, tilting the mold to bring the filling in register with the central axis of the molding cavity and achieving full filling of the molding cavity. Thereafter, polymerizing the composition and recovering the lens.

Abstract: The room temperature polymerizable composition comprises at least one polymerizable monomer having at least one episulfide functionality and an effective amount of at least one (alkoxyphenyl)phosphine polymerization catalyst.

Abstract: The method for making an optical lens which includes: filling a molding cavity vertically oriented and defined by two mold pieces at the periphery of which is disposed an annular closure member with a polymerizable synthetic composition through a disposable check valve provided in the closure member; polymerizing the composition to form the lens; and recovering the lens with the disposable check valve imprisoned within the polymerized composition at the periphery thereof.

Abstract: The polymerizable compositions compriseA) at least one polyiso(thio)cyanate monomer, and at least one polythiol monomer; or at least one episulfide compound and optionally one or more compounds having two or more functional groups capable of reacting with episulfide groups; andB) an effective amount of a thiocyanate salt as a polymerization catalyst.Application to the fabrication of optical articles, such as lenses.

Abstract: Transparent polymer composition comprising:a component A comprising:at least 10% by weight of a monomer or of a mixture of monomers (I), containing at least one thioacrylate or thiomethacrylate function;0 to 90% by weight of one or more monomers (II) which are copolymerizable by a radical route, preferably mono- or polyfunctional vinyl, acrylic or methacrylic; anda component B comprising, relative to the weight of the component A:0.1 to 15% by weight of one or more monomers (III) containing an ethylenic unsaturation which does not contribute to an aromatic system and having a carbon bearing a free hydroxyl group in an .alpha. position relative to the ethylenic unsaturation.Application to the manufacture of ophthalmic lenses.

Abstract: The present invention relates to a new polymer compositions for use in the manufacture of ophthalmic lenses, to their use in ophthalmology and to apparatus using these lenses, such as eyepieces and film/video camera optics.

Abstract: The present invention relates to new polymer compositions for use in the manufacture of opthalmic lenses which result from the copolymerization of a component (A) comprising at least 50% by weight of a monomer or mixture having formula ##STR1## wherein R.sub.1 and R.sub.2 are selected from H and C.sub.1 -C.sub.6 alkyl radical,X is --O--, --S--, --SO.sub.2, --CO--, --CH.sub.2 --, --CH.dbd.CH--, or C(CH.sub.3).sub.2,m and n are integers and m+n ranging from 0 to 10 and 0,5 to 15% by weight of a component (B) comprising a monomer having an ethylenic unsaturation which does not contribute to an aromatic system and having a free hydroxy group in position .alpha. of the unsaturation, as well as to their use in opthalmology and to apparatus using these lenses, such as eyepieces and film/video camera optics.

Abstract: A polymer composition obtained by polymerisation of a polymerisable composition comprising: at least 50% by weight of a monomer or mixture of monomers having formula I ##STR1## wherein R.sub.1 and R.sub.2, which may be identical or different, represent hydrogen or C.sub.1 -C.sub.6 alkyl, X represents ##STR2## and wherein m+n is between 0 and 10, 0 to 50% by weight of one or more mono- or polyfunctional vinyl, acrylic or methacrylic comonomers (II); 0.5 to 15% by weight with respect to the weight of components (I) and (II) of a compound having formula (III) ##STR3## where R.sub.3 and R.sub.4 represent hydrogen or one of radicals R.sub.3 and R.sub.4 represents a hydrogen atom while the other forms a ring with R.sub.7 ; R.sub.5, R.sub.6 and R.sub.7 are hydrogen or an alkyl group which may be substituted by OH and/or interrupted.