Abstract: Methods using a downhole fluid including a winterizing composition including a winterizing agents of a compound of general formula Z(R1)m, where Z is a polyol having between 5 and 30 carbon atoms, R1 is a carbyl group having between about 10 and about 40 carbon atoms, and where m is an integer having the value of 1 or 2, when m is 2, R1 can be the same or different and one or more carbon atoms of R1 can be replaced by B, N, O, Si, P, S, Ge and/or mixtures thereof and one or more of the hydrogen atoms in R1 can be replaced by F, Cl, Br, I, CONR22, COOR2, OR2, NR22 SR2, PR22 and/or mixtures thereof and where R2 can be a hydrogen atom, alkyl, aryl, alkylaryl or arylalkyl group having between 1-20 carbon atoms where one or more carbon or hydrogen atoms can be replaced as set forth for R1.

Abstract: A fluid mixture containing a high molecular weight polysaccharide composition with improved viscosity stability at high downhole temperatures and pressures encountered in common oil field applications, including hydraulic fracturing stimulation, drilling, cementing, and coil-tubing. The composition includes a salicylic acid solution, which, being a free-radical scavenger, prevents free-radical reactions within the high molecular weight polysaccharide that would otherwise adversely affect viscosity. The composition may also include an ascorbic acid solution, which reduces at least a portion of the oxidized salicylic acid to restore its function as a free-radical scavenger to prevent additional free-radical reactions with the high molecular weight polysaccharide. An alcohol solvent may also be utilized to increase the solution loading of salicylic acid.

Abstract: A new class of winterizing compositions are disclosed including a winterizing agents being a compound of general formula Z(R1)m, where Z is a polyol having between 5 and 30 carbon atoms, R1 is a carbyl group having between about 10 and about 40 carbon atoms, and where m is an integer having the value of 1 or 2, when m is 2, R1 can be the same or different and one or more carbon atoms of R1 can be replaced by B, N, O, Si, P, S, Ge and/or mixtures thereof and one or more of the hydrogen atoms in R1 can be replaced by F, Cl, Br, I, CONR22, COOR2, OR2, NR22, SR2, PR22, and/or mixtures thereof and where R2 can be a hydrogen atom, alkyl, aryl, alkylaryl or arylalkyl group having between 1-20 carbon atoms where one or more carbon or hydrogen atoms can be replaced as set forth for R1.