Abstract: A method of modifying a surface of a substrate comprises: inkjet printing a material, the material comprising a non-vaporizable component onto a surface of a substrate, wherein the non-vaporizable component comprises at least one compound having the formula

Abstract: Methods of applying adhesive to a surface of a substrate comprise: digitally applying a fixable fluid material to a portion of the substrate surface, fixing the first fluid material to form a fixed coating in contact with the substrate surface, wherein the fixed coating has at least one boundary that encloses a region of the substrate surface within the at least one boundary, and applying a second fluid material comprising at least one of an adhesive and an adhesive precursor to at least a portion of the enclosed region of the substrate surface. Various products, including laminated products, may be prepared according to such methods.

Abstract: The invention provides compounds having the formula: wherein Rf is CnF2n+1—(CH2)m—, wherein n is 1 to 22 and m is 0, or an integer from 1 to 3; X is —CO2—, —SO3—, —CONH—, —O—, —S— a covalent bond, —SO2NR—, or —NR—, wherein R is H or C1 to C5 alkylene; Y is —CH2— wherein z is 0 or 1; and R1 is H, lower alkyl or Rf—X—Yz— with the provisos that when X is —S—, or —O—, m is 0, sand z is 0, n is ≧7 and when X is a covalent bond, m or z is at least 1, and uses thereof.