Abstract: Reaction of a phenol with a metal salt of an alcohol produces a metal phenolate salt of a phenol. When a hindered phenol is used a hindered metal phenolate is produced. Such hindered metal phenolate salts are useful in driving the synthesis reaction of hindered phenol esters and phosphite esters to completion.

Abstract: Reaction of a phenol with a metal salt of an alcohol produces a metal phenolate salt of a phenol. When a hindered phenol is used a hindered metal phenolate is produced. Such hindered metal phenolate salts are useful in driving the synthesis reaction of hindered phenol esters and phosphite esters to completion.

Abstract: A process to produce organic phosphites from the group consisting of: 1

Abstract: A process to produce organic phosphites from the group consisting of: wherein each R1 , R2, and R3 is independently selected from the group consisting of hydrogen, methyl, ethyl, n-propyl, iso-propyl, n-butyl, t-butyl, t-amyl, t-hexyl, cyclohexyl, cumyl, t-pentyl, and t-octyl; and wherein each R1, R2, and R3 is independently selected from the group consisting of hydrogen, methyl, ethyl, n-propyl, iso-propyl, n-butyl, t-butyl, t-amyl, t-hexyl, cyclohexyl, cumyl, t-pentyl, and t-octyl and each R4 and R5 is independently selected from the group consisting of hydrogen, methyl, ethyl, n-propyl, iso-propyl, n-butyl, t-butyl, t-amyl, t-hexyl, cyclohexyl, cumyl, t-pentyl, and t-octyl using a metal phenolate where each R1, R2, and R3 is independently selected from the group consisting of hydrogen, methyl, ethyl, n-propyl, iso-propyl, n-butyl, t-butyl, t-amyl, t-hexyl, cyclohexyl, cumyl, t-pentyl, and t-octyl, and Q is a metal cation having a valence x, i.e.

Abstract: There is disclosed a bit sync search and frame sync search system operative with a digital data signal as transmitted by a digital radio transmitter. The bit search is implemented by detecting a predetermined phasing signal which is incorporated in the digital signal and which has a repetitive bit pattern of ones and zeroes. The phasing signal is first detected by providing an in-phase and quadrature component signal and correlating those signals to provide an output signal indicative of the bit pattern in the phasing signal. After the phasing signal has been provided and an oscillator associated with a receiving apparatus is compensated according to the detected phasing signal, a tracking mode is entered, whereby a frame signal is captured and the system generates histograms of data bit transitions for producing an error signal indicative of the difference of the transmitted clock rate and the sampling portion of a received bit.

Abstract: There is disclosed a bit sync search and frame sync search system operative with a digital data signal as transmitted by a digital radio transmitter. The bit search is implemented by detecting a predetermined phasing signal which is incorporated in the digital signal and which has a repetitive bit pattern of ones and zeroes. The phasing signal is first detected by providing an in-phase and quadrature component signal and correlating those signals to provide an output signal indicative of the bit pattern in the phasing signal. After the phasing signal has been provided and an oscillator associated with a receiving apparatus is compensated according to the detected phasing signal, a tracking mode is entered, whereby a frame signal is captured and the system generates histograms of data bit transitions for producing an error signal indicative of the difference of the transmitted clock rate and the sampling portion of a received bit.

Abstract: There is disclosed a bit sync search and frame sync search system operative with a digital data signal as transmitted by a digital radio transmitter. The bit search is implemented by detecting a predetermined phasing signal which is incorporated in the digital signal and which has a repetitive bit pattern of ones and zeroes. The phasing signal is first detected by providing 94 in-phase and quadrature component signals and correlating those signals to provide an output signal indicative of the bit pattern in the phasing signal. After the phasing signal has been provided and an oscillator associated with a receiving apparatus is compensated according to the detected phasing signal, a tracking mode is entered, whereby a frame signal is captured and the system generates histograms of data bit transitions for producing an error signal indicative of the difference of the transmitted clock rate and the sampling portion of a received bit.

Abstract: Disclosed are coating compositions which include hydrogen silsesquioxane resin dissolved in saturated alkyl hydrocarbons. The compositions are useful for forming coatings which are thick and/or have good coating quality.

Abstract: Curable adhesive compositions comprise combinations of organosiloxane MQ resins and liquid polyorganosiloxanes of specified viscosity and functionality. The compositions are substantially free of unreactive materials and are applied in the molten state. Depending upon the concentration of reactive groups on the resin and polyorganosiloxane, the compositions may also include a silane containing an average of more than two hydrolyzable groups per molecule. Preferred compositions develop excellent adhesion to a variety of organic and metallic substrates during curing under ambient conditions.

Abstract: A method for enhancing the dielectric properties of a new or in-service electrical cable is disclosed, the method comprising supplying the interstitial void space of the cable's conductor with a water-reative antitreeing agent having a diffusion coefficient of at least 1.times.10.sup.-7 cm.sup.2 /second at 50.degree. C. in the insulation of the cable and having an initial viscosity of .ltoreq.100 cP at 25.degree. C. The instant method provides a more symmetrical distribution of dielectric enhancing fluid in the insulation than prior art fluids and results in a significant reduction in cable treatment time.

Abstract: A method for enhancing the dielectric properties of a new or in-service electrical cable is disclosed, the method comprising supplying the interstitial void space of the cable's conductor with a fluid mixture comprising(A) an antitreeing agent; and(B) a water-reactive compound,wherein (B) has a diffusion coefficient of at least 1.times.10.sup.-7 cm.sup.2 /second at 50.degree. C. in the insulation of the cable and the mixture has an initial viscosity of .ltoreq.100 cP at 25.degree. C. The instant method provides a more symmetrical distribution of dielectric enhancing fluid in the insulation than prior art fluids and results in a significant reduction in cable treatment time.

Abstract: A silicone pressure-sensitive adhesive composition having high adhesion and tack while having a high percentage of adhesive failure when peeled from substrates is disclosed, said composition consisting essentially of(A) 50 to 80 parts by weight of an MQ organopolysiloxane resin;(B) 20 to 50 parts by weight of a polydiorganosiloxane having at least 3 alkenyl groups in its molecule, with the proviso that the alkenyl group content of said polydiorganosiloxane is 0.1 to 4 mole percent, the total amount of components (A) and (B) being 100 parts by weight;(C) an organohydrogenpolysiloxane crosslinking agent having, on average, at least 3 SiH groups per molecule, the amount of said organohydrogenpolysiloxane being sufficient to provide a molar ratio of said SiH groups of component (C) to said alkenyl groups of component (B) in the range of 0.1 to <1.0; and(D) a curing amount of a hydrosilation catalyst.

Abstract: A moisture-curable silicone hot-melt adhesive composition is disclosed, which composition comprises(i) a solid hydroxyl-functional organopolysiloxane resin comprising R.sub.3 SiO.sub.1/2 siloxane units and SiO.sub.4/2 siloxane units in a molar ratio of 0.5/1 to 1.2/1, wherein R is selected from hydrocarbon or halogenated hydrocarbon radicals;(ii) a diorganopolysiloxane polymer having silicon-bonded hydroxyl terminal groups and having a viscosity at 25.degree. C. of 100 to 500,000 centipoise, the weight ratio of said resin (i) to said polymer being (ii) in the range 40:60 to 75:25;(iii) a ketoximosilane, the amount of said ketoximosilane being sufficient to provide a molar ratio of X groups to total hydroxyl groups on said resin (i) and said diorganopolysiloxane (ii) of 0.9 to 3; and(iv) optionally, sufficient catalyst to accelerate the cure of said composition, said composition being an essentially solvent-free non-slump solid at room temperature, being extrudable at .ltoreq.150.degree. C.

Abstract: There is disclosed a silicone pressure-sensitive adhesive composition based on a siloxane resin component, a polydiorganosiloxane polymer component having unsaturated groups in its molecule, a silicon hydride-functional crosslinking agent and a hydrosilation catalyst, wherein the crosslinking agent is a reaction product of a cyclic or linear organohydrogenpolysiloxane and an unsaturated organic compound selected from alpha-alkenes having 6 to 28 carbon atoms or aromatic compounds having the formula Ph-R.sup.4, wherein Ph represents a phenyl radical and R.sup.4 is a terminally unsaturated monovalent hydrocarbon group having 2 to 6 carbon atoms.

Abstract: There is disclosed a pressure-sensitive adhesive composition based on a silicone resin and a polydiorganosiloxane polymer wherein the resin component has a number average molecular weight of about 950 to 1,600 and consists essentially of triorganosiloxy (M) units and silicate (Q) units wherein the molar ratio M/Q is in the range 1.1/1 to 1.4/1, inclusive. The adhesives of the invention exhibit improved adhesion to low energy substrates such as polyethylene and polytetrafluoroethylene.

Abstract: There is provided a method of extending the serviceable life of a stranded conductor electrical distribution cable wherein the interstices of the conductor are filled with a curable silicone water block composition which is subsequently cured to a non-flowing state. The composition has a low viscosity and comprises (A) an Si-H endblocked polydiorganosiloxane fluid, (B) a polydiorganosiloxane fluid endblocked with an unsaturated organic radical, (C) a siloxane crosslinker, (D) a hydrosilation catalyst and (E) a polymerization inhibitor. Proper selection of catalyst and inhibitor concentrations imparts a controllable viscosity-time profile to the composition and allows cables of various sizes and lengths to be filled before the water block composition cures.

Abstract: There is provided a method for restoring in-service electrical distribution cable having a stranded conductor and polyolefin insulation, comprising(i) drying the interstices of said conductor,(ii) exposing the interior of said cable to an anti-treeing additive till said additive is absorbed by the insulation,(iii) filling the interstices of said stranded conductor with a water block composition comprising (A) an Si-H endblocked polydiorganosiloxane fluid; (B) a polydiorganosiloxane fluid; (C) a siloxane crosslinker; (D) a hydrosilation catalyst; and (E) a polymerization inhibitor, and(iv) curing said water block composition to a non-flowing state. Proper selection of catalyst and inhibitor concentrations imparts a controllable viscosity-time profile to the composition and allows cables of various sizes and lengths to be filled before the water block composition cures.

Abstract: There is disclosed the use of a quaternary ammonium salt of an alkoxysilane as a dispersant for magnetic pigment particles in the preparation of magnetic recording media. The dispersant of the present invention can bind to the pigment particles and may be substituted for conventional phosphate ester dispersants which are incapable of binding to the pigment and tend to migrate to the surface of such media, thereby adversely affecting recording media performance.

Abstract: There is disclosed the use of a quaternary ammonium salt of an alkoxysilane as a dispersant for magnetic pigment particles in the preparation of magnetic recording media. The dispersant of the present invention can bind to the pigment particles and may be substituted for conventional phosphate ester dispersants which are incapable of binding to the pigment and tend to migrate to the surface of such media, thereby adversely affecting recording media performance.

Abstract: There is provided a method of extending the serviceable life of a stranded conductor electrical distribution cable wherein the interstices of the conductor are filled with a curable silicone water block composition which is subsequently cured to a non-flowing state. The composition has a low viscosity and comprises (A) an Si-H endblocked polydiorganosiloxane fluid, (B) a polydiorganosiloxane fluid endblocked with an unsaturated organic radical, (C) a siloxane crosslinker, (D) a hydrosilation catalyst and (E) a polymerization inhibitor. Proper selection of catalyst and inhibitor concentrations imparts a controllable viscosity-time profile to the composition and allows cables of various sizes and lengths to be filled before the water block composition cures.