Patents by Inventor Gary D. Andrew

Gary D. Andrew has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5028366
    Abstract: A method for preparing a polyurethane foam article in a mold by applying to a mold surface a water-based mold release composition which includes a release effective system which is in a solid (hardened) state at the mold pour temperature and a liquid state at the demold temperature, pouring a polyurethane foam composition into the mold, curing the foam composition and demolding the foam article. The use of such release effective system in the aqueous mold release composition provides for a reduction in surface defects of the polyurethane foam article.Also disclosed is the incorporation of a poly(siloxane-glycol) surfactant having a cloud point ranging from 25.degree.-50.degree. C. into a water-based mold release composition including an aqueous emulsion or dispersion of at least one release effective substance and desirably at least one emulsifying agent provides for improved surface quality of the foam product.
    Type: Grant
    Filed: January 12, 1988
    Date of Patent: July 2, 1991
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Mark E. Harakal, George J. Wasilczyk, Gary D. Andrew, Zdizslaw Makus, Michael Scarpati
  • Patent number: 4936917
    Abstract: The incorporation of a poly(siloxane-glycol) surfactant having a cloud point ranging from 25.degree.-50.degree. C. into a water-based mold release composition comprising an aqueous emulsion or dispersion of at least one release effective substance and desirably at least one emulsifying agent provides for improved surface quality of the foam product.Also disclosed is a method for preparing a polyurethane foam article in a mold by applying to a mold surface a water-based mold release composition which comprises a release effective system which is in a solid (hardened) state at the mold pour temperature and a liquid state at the demold temperature, pouring a polyurethane foam composition into the mold, curing the foam composition and demolding the foam article. The use of such release effective system in the aqueous mold release composition provides for a reduction in surface defects of the polyurethane foam article.
    Type: Grant
    Filed: January 12, 1988
    Date of Patent: June 26, 1990
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Mark E. Harakal, George J. Wasilczyk, Gary D. Andrew, Zdzislaw Makus, Michael Scarpati
  • Patent number: 4904629
    Abstract: A method for preparing polyurethane product by the reaction of an organic polyisocyanate with a polyester or polyether polyol in the presence of a catalytically effective amount of a catalyst system consisting essentially of a tertiary amine and 1 to 35 wt %, based on the tertiary amine, of an N-hydroxyalkyl quaternary ammonium carbonylate salt, particularly a quaternary triethylenediamine compound. The preferred quaternary composition is the reaction product of an alkylene oxide in excess of equimolar amount with triethylenediamine in the presence of an acid. The use of such catalyst system advantageously improves the cure time of the urethane reaction, when compared to a system containing solely a tertiary amine, while maintaining the same initiation of the reaction. This advantage can be transferred to a delay in the initiation time while maintaining or shortening the cure time by adjustments in the total amount of the catalyst system used.
    Type: Grant
    Filed: July 29, 1988
    Date of Patent: February 27, 1990
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Edward A. Galla, Robert L. Ricci, Gary D. Andrew
  • Patent number: 4797240
    Abstract: To prevent the staining of a nitrocellulose coated shoe upper by a polyurethane shoe sole prepared from a mixture comprising a polyisocyanate, a polyol, a chain extender, a tertiary amine catalyst, a surfactant and water, an effective amount of a reactive organic halogen compound, preferably a halogenated fire retardant, is added.
    Type: Grant
    Filed: June 8, 1987
    Date of Patent: January 10, 1989
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Gary D. Andrew, Edward A. Galla, Robert L. Ricci
  • Patent number: 4785025
    Abstract: A method for preparing polyurethane product by the reaction of an organic polyisocyanate with a polyester or polyether polyol in the presence of a catalytically effective amount of a catalyst system consisting essentially of a tertiary amine and 1 to 35 wt %, based on the tertiary amine, of an N-hydroxyalkyl quaternary ammonium carbonylate salt, particularly a quaternary triethylenediamine compound. The preferred quaternary composition is the reaction product of an alkylene oxide in excess of equimolar amount with triethylenediamine in the presence of an acid. The use of such catalyst system advantageously improves the cure time of the urethane reaction, when compared to a system containing solely a tertiary amine, while maintaining the same initiation of the reaction. This advantage can be transferred to a delay in the initiation time while maintaining or shortening the cure time by adjustments in the total amount of the catalyst system used.
    Type: Grant
    Filed: November 6, 1986
    Date of Patent: November 15, 1988
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Edward A. Galla, Robert L. Ricci, Gary D. Andrew
  • Patent number: 4582861
    Abstract: A method for preparing polyurethane product by the reaction of an organic polyisocyanate with a polyester or polyether polyol in the presence of a catalytically effective amount of a catalyst system consisting essentially of a tertiary amine and 1 to 35 wt %, based on the tertiary amine, of an N-hydroxyalkyl quaternary ammonium carbonylate salt. The use of such catalyst system advantageously improves the cure time of the urethane reaction, when compared to a system containing solely a tertiary amine, while maintaining the same initiation of the reaction. This advantage can be transferred to a delay in the initiation time while maintaining or shortening the cure time by adjustments in the total amount of the catalyst system used.
    Type: Grant
    Filed: November 13, 1984
    Date of Patent: April 15, 1986
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Edward A. Galla, Robert L. Ricci, Gary D. Andrew
  • Patent number: 4532542
    Abstract: A filter circuit for processing a composite video signal comprises a series circuit of a delay device for delaying an input composite video signal for the duration of one line of the video signal and a first bandpass filter connected to the delay device to receive the delayed video signal. A transversal bandpass filter receives the input composite video signal and provides as outputs a delayed composite video signal and a delayed chrominance component. A first summing device sums the delayed chrominance component and the output of the series circuit, while a second summing device sums the delayed composite video signal and the output of the first summing device. The series circuit can be selectively disabled so as not to apply the delayed video signal to the first summing device.
    Type: Grant
    Filed: April 1, 1983
    Date of Patent: July 30, 1985
    Assignee: Tektronix, Inc.
    Inventor: Gary D. Andrews
  • Patent number: 4501995
    Abstract: An automatic S correction circuit for a resonant scan deflection circuit comprises a plurality of S-shaping capacitors. The peak voltage and the peak-to-peak voltage across the S capacitors are detected, and the number of effective capacitors is varied to maintain the peak voltage and the peak-to-peak voltage in a predetermined relationship.
    Type: Grant
    Filed: April 6, 1982
    Date of Patent: February 26, 1985
    Assignee: Tektronix, Inc.
    Inventors: Harold W. Olmstead, Gary D. Andrews, Clayton C. Walquist